Template:Nuclear physics In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in what is called positron emission. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability.<ref name="konya74"> Template:Cite book</ref> For either electron or positron emission to be energetically possible, the energy release (see below) or Q value must be positive.
Beta decay is a consequence of the weak force, which is characterized by relatively long decay times. Nucleons are composed of up quarks and down quarks,<ref>Template:Cite journal</ref> and the weak force allows a quark to change its flavour by means of a virtual W boson leading to creation of an electron/antineutrino or positron/neutrino pair. For example, a neutron, composed of two down quarks and an up quark, decays to a proton composed of a down quark and two up quarks.
Electron capture is sometimes included as a type of beta decay,<ref>Template:Cite book</ref> because the basic nuclear process, mediated by the weak force, is the same. In electron capture, an inner atomic electron is captured by a proton in the nucleus, transforming it into a neutron, and an electron neutrino is released.
DescriptionEdit
The two types of beta decay are known as beta minus and beta plus. In beta minus (β−) decay, a neutron is converted to a proton, and the process creates an electron and an electron antineutrino; while in beta plus (β+) decay, a proton is converted to a neutron and the process creates a positron and an electron neutrino. β+ decay is also known as positron emission.<ref>Template:Cite book</ref>
Beta decay conserves a quantum number known as the lepton number, or the number of electrons and their associated neutrinos (other leptons are the muon and tau particles). These particles have lepton number +1, while their antiparticles have lepton number −1. Since a proton or neutron has lepton number zero, β+ decay (a positron, or antielectron) must be accompanied with an electron neutrino, while β− decay (an electron) must be accompanied by an electron antineutrino.
An example of electron emission (β− decay) is the decay of carbon-14 into nitrogen-14 with a half-life of about 5,700 years:
In this form of decay, the original element becomes a new chemical element in a process known as nuclear transmutation. This new element has an unchanged mass number Template:Mvar, but an atomic number Template:Mvar that is increased by one. As in all nuclear decays, the decaying element (in this case Template:Nuclide) is known as the parent nuclide while the resulting element (in this case Template:Nuclide) is known as the daughter nuclide.
Another example is the decay of hydrogen-3 (tritium) into helium-3 with a half-life of about 12.3 years:
An example of positron emission (β+ decay) is the decay of magnesium-23 into sodium-23 with a half-life of about 11.3 s:
β+ decay also results in nuclear transmutation, with the daughter element having an atomic number that is decreased by one.
The beta spectrum, or distribution of energy values for the beta particles, is continuous. The total energy of the decay process is divided between the electron, the antineutrino, and the recoiling nuclide. In the figure to the right, an example of an electron with 0.40 MeV energy from the beta decay of 210Bi is shown. In this example, the total decay energy is 1.16 MeV, so the antineutrino has the remaining energy: Template:Nowrap. An electron at the far right of the curve would have the maximum possible kinetic energy, leaving the energy of the neutrino to be only its small rest mass.
HistoryEdit
Discovery and initial characterizationEdit
Radioactivity was discovered in 1896 by Henri Becquerel in uranium, and subsequently observed by Marie and Pierre Curie in thorium and in the newly discovered elements polonium and radium. In 1899, Ernest Rutherford separated radioactive emissions into two types: alpha and beta (now beta minus), based on penetration of objects and ability to cause ionization. Alpha rays could be stopped by thin sheets of paper or aluminium, whereas beta rays could penetrate several millimetres of aluminium. In 1900, Paul Villard identified a still more penetrating type of radiation, which Rutherford identified as a fundamentally new type in 1903 and termed gamma rays. Alpha, beta, and gamma are the first three letters of the Greek alphabet.
In 1900, Becquerel measured the mass-to-charge ratio (Template:Math) for beta particles by the method of J.J. Thomson used to study cathode rays and identify the electron. He found that Template:Math for a beta particle is the same as for Thomson's electron, and therefore suggested that the beta particle is in fact an electron.<ref name="Handbook">Template:Cite book</ref>
In 1901, Rutherford and Frederick Soddy showed that alpha and beta radioactivity involves the transmutation of atoms into atoms of other chemical elements. In 1913, after the products of more radioactive decays were known, Soddy and Kazimierz Fajans independently proposed their radioactive displacement law, which states that beta (i.e., Template:SubatomicParticle) emission from one element produces another element one place to the right in the periodic table, while alpha emission produces an element two places to the left.
NeutrinosEdit
The study of beta decay provided the first physical evidence for the existence of the neutrino. In both alpha and gamma decay, the resulting alpha or gamma particle has a narrow energy distribution, since the particle carries the energy from the difference between the initial and final nuclear states. However, the kinetic energy distribution, or spectrum, of beta particles measured by Lise Meitner and Otto Hahn in 1911 and by Jean Danysz in 1913 showed multiple lines on a diffuse background. These measurements offered the first hint that beta particles have a continuous spectrum.<ref name="Jensen">Template:Cite book</ref> In 1914, James Chadwick used a magnetic spectrometer with one of Hans Geiger's new counters to make more accurate measurements which showed that the spectrum was continuous.<ref name="Jensen" /><ref>Template:Cite journal</ref> The results, which appeared to be in contradiction to the law of conservation of energy, were validated by means of calorimetric measurements in 1929 by Lise Meitner and Wilhelm Orthmann.<ref>Template:Cite journal</ref> If beta decay were simply electron emission as assumed at the time, then the energy of the emitted electron should have a particular, well-defined value.<ref name=Brown>Template:Cite journal</ref> For beta decay, however, the observed broad distribution of energies suggested that energy is lost in the beta decay process. This spectrum was puzzling for many years.
A second problem is related to the conservation of angular momentum. Molecular band spectra showed that the nuclear spin of nitrogen-14 is 1 (i.e., equal to the reduced Planck constant) and more generally that the spin is integral for nuclei of even mass number and half-integral for nuclei of odd mass number. This was later explained by the proton-neutron model of the nucleus.<ref name=Brown/> Beta decay leaves the mass number unchanged, so the change of nuclear spin must be an integer. However, the electron spin is 1/2, hence angular momentum would not be conserved if beta decay were simply electron emission.
From 1920 to 1927, Charles Drummond Ellis (along with Chadwick and colleagues) further established that the beta decay spectrum is continuous. In 1933, Ellis and Nevill Mott obtained strong evidence that the beta spectrum has an effective upper bound in energy. Niels Bohr had suggested that the beta spectrum could be explained if conservation of energy was true only in a statistical sense, thus this principle might be violated in any given decay.<ref name=Brown/>Template:Rp However, the upper bound in beta energies determined by Ellis and Mott ruled out that notion. Now, the problem of how to account for the variability of energy in known beta decay products, as well as for conservation of momentum and angular momentum in the process, became acute.
In a famous letter written in 1930, Wolfgang Pauli attempted to resolve the beta-particle energy conundrum by suggesting that, in addition to electrons and protons, atomic nuclei also contained an extremely light neutral particle, which he called the neutron. He suggested that this "neutron" was also emitted during beta decay (thus accounting for the known missing energy, momentum, and angular momentum), but it had simply not yet been observed. In 1931, Enrico Fermi renamed Pauli's "neutron" the "neutrino" ('little neutral one' in Italian). In 1933, Fermi published his landmark theory for beta decay, where he applied the principles of quantum mechanics to matter particles, supposing that they can be created and annihilated, just as the light quanta in atomic transitions. Thus, according to Fermi, neutrinos are created in the beta-decay process, rather than contained in the nucleus; the same happens to electrons. The neutrino interaction with matter was so weak that detecting it proved a severe experimental challenge. Further indirect evidence of the existence of the neutrino was obtained by observing the recoil of nuclei that emitted such a particle after absorbing an electron. Neutrinos were finally detected directly in 1956 by the American physicists Clyde Cowan and Frederick Reines in the Cowan–Reines neutrino experiment.<ref>Template:Cite journal</ref> The properties of neutrinos were (with a few minor modifications) as predicted by Pauli and Fermi.
Template:SubatomicParticle decay and electron captureEdit
In 1934, Frédéric and Irène Joliot-Curie bombarded aluminium with alpha particles to effect the nuclear reaction Template:Nuclide + Template:Nuclide → Template:Nuclide + Template:Nuclide, and observed that the product isotope Template:Nuclide emits a positron identical to those found in cosmic rays (discovered by Carl David Anderson in 1932). This was the first example of Template:SubatomicParticle decay (positron emission), which they termed artificial radioactivity since Template:Nuclide is a short-lived nuclide which does not exist in nature. In recognition of their discovery, the couple were awarded the Nobel Prize in Chemistry in 1935.<ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref>
The theory of electron capture was first discussed by Gian-Carlo Wick in a 1934 paper, and then developed by Hideki Yukawa and others. K-electron capture was first observed in 1937 by Luis Alvarez, in the nuclide 48V.<ref name=k>Template:Cite book</ref><ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref><ref>Template:Cite journal</ref> Alvarez went on to study electron capture in 67Ga and other nuclides.<ref name=k /><ref>Template:Cite journal</ref><ref>Template:Cite journal</ref>
Non-conservation of parityEdit
In 1956, Tsung-Dao Lee and Chen Ning Yang noticed that there was no evidence that parity was conserved in weak interactions, and so they postulated that this symmetry may not be preserved by the weak force. They sketched the design for an experiment for testing conservation of parity in the laboratory.<ref>Template:Cite journal</ref> Later that year, Chien-Shiung Wu and coworkers conducted the Wu experiment showing an asymmetrical beta decay of [[cobalt-60|Template:SimpleNuclide]] at cold temperatures that proved that parity is not conserved in beta decay.<ref name="Wu1957" >Template:Cite journal</ref><ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref> This surprising result overturned long-held assumptions about parity and the weak force. In recognition of their theoretical work, Lee and Yang were awarded the Nobel Prize for Physics in 1957.<ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref> However Wu, who was female, was not awarded the Nobel prize.<ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref>
β− decay Edit
[[Image:Beta Negative Decay.svg|thumb|right|The leading-order Feynman diagram for Template:SubatomicParticle decay of a neutron into a proton, electron, and electron antineutrino via a virtual [[W boson|Template:SubatomicParticle boson]]. For higher-order diagrams see <ref>Template:Cite journal</ref><ref>Template:Cite journal</ref>]] In Template:SubatomicParticle decay, the weak interaction converts an atomic nucleus into a nucleus with atomic number increased by one, while emitting an electron (Template:SubatomicParticle) and an electron antineutrino (Template:SubatomicParticle). Template:SubatomicParticle decay generally occurs in neutron-rich nuclei.<ref name=Loveland>Template:Cite book</ref> The generic equation is:
- Template:Physics particle → Template:Physics particle + Template:SubatomicParticle + Template:Math<ref name="konya74"/>
where Template:Mvar and Template:Mvar are the mass number and atomic number of the decaying nucleus, and X and X′ are the initial and final elements, respectively.
Another example is when the free neutron (Template:Nuclide) decays by Template:SubatomicParticle decay into a proton (Template:SubatomicParticle):
- Template:SubatomicParticle → Template:SubatomicParticle + Template:SubatomicParticle + Template:Math.
At the fundamental level (as depicted in the Feynman diagram on the right), this is caused by the conversion of the negatively charged (Template:Math) down quark to the positively charged (Template:Math) up quark, which is promoted by a virtual [[W boson|Template:SubatomicParticle boson]]; the Template:SubatomicParticle boson subsequently decays into an electron and an electron antineutrino:
- Template:Subatomic particle → Template:Subatomic particle + Template:SubatomicParticle + Template:Math.
β+ decay Edit
{{#invoke:Labelled list hatnote|labelledList|Main article|Main articles|Main page|Main pages}} [[File:Electron Capture Decay.svg|thumb|The leading-order Feynman diagram for Template:SubatomicParticle decay of a proton into a neutron, positron, and electron neutrino via an intermediate virtual [[W boson|Template:SubatomicParticle boson]]]]
In Template:SubatomicParticle decay, or positron emission, the weak interaction converts an atomic nucleus into a nucleus with atomic number decreased by one, while emitting a positron (Template:SubatomicParticle) and an electron neutrino (Template:SubatomicParticle). Template:SubatomicParticle decay generally occurs in proton-rich nuclei. The generic equation is:
- Template:Physics particle → Template:Physics particle + Template:SubatomicParticle + Template:Math<ref name="konya74"/>
This may be considered as the decay of a proton inside the nucleus to a neutron:
- p → n + Template:SubatomicParticle + Template:Math<ref name="konya74"/>
However, Template:SubatomicParticle decay cannot occur in an isolated proton because it requires energy, due to the mass of the neutron being greater than the mass of the proton. Template:SubatomicParticle decay can only happen inside nuclei when the daughter nucleus has a greater binding energy (and therefore a lower total energy) than the mother nucleus. The difference between these energies goes into the reaction of converting a proton into a neutron, a positron, and a neutrino and into the kinetic energy of these particles. This process is opposite to negative beta decay, in that the weak interaction converts a proton into a neutron by converting an up quark into a down quark resulting in the emission of a Template:SubatomicParticle or the absorption of a Template:SubatomicParticle. When a Template:SubatomicParticle boson is emitted, it decays into a positron and an electron neutrino:
- Template:Subatomic particle → Template:Subatomic particle + Template:SubatomicParticle + Template:Math.
Electron capture (K-capture/L-capture)Edit
{{#invoke:Labelled list hatnote|labelledList|Main article|Main articles|Main page|Main pages}}
In all cases where Template:SubatomicParticle decay (positron emission) of a nucleus is allowed energetically, so too is electron capture allowed. This is a process during which a nucleus captures one of its atomic electrons, resulting in the emission of a neutrino:
An example of electron capture is one of the decay modes of krypton-81 into bromine-81:
All emitted neutrinos are of the same energy. In proton-rich nuclei where the energy difference between the initial and final states is less than 2Template:Math, Template:SubatomicParticle decay is not energetically possible, and electron capture is the sole decay mode.<ref name="Zuber" />
If the captured electron comes from the innermost shell of the atom, the K-shell, which has the highest probability to interact with the nucleus, the process is called K-capture.<ref name="Jevremovic2009">Template:Cite book</ref> If it comes from the L-shell, the process is called L-capture, etc.
Electron capture is a competing (simultaneous) decay process for all nuclei that can undergo β+ decay. The converse, however, is not true: electron capture is the only type of decay that is allowed in proton-rich nuclides that do not have sufficient energy to emit a positron and neutrino.<ref name="Zuber">Template:Cite book</ref>
Nuclear transmutationEdit
Template:See also If the proton and neutron are part of an atomic nucleus, the above described decay processes transmute one chemical element into another. For example:
Template:Nuclide → Template:Nuclide + Template:SubatomicParticle + Template:Math (beta minus decay) Template:Nuclide → Template:Nuclide + Template:Math + Template:Math (beta plus decay) Template:Nuclide + Template:SubatomicParticle → Template:Nuclide + Template:Math (electron capture)
Beta decay does not change the number (Template:Mvar) of nucleons in the nucleus, but changes only its charge Template:Mvar. Thus the set of all nuclides with the same Template:Mvar can be introduced; these isobaric nuclides may turn into each other via beta decay. For a given Template:Mvar there is one that is most stable. It is said to be beta stable, because it presents a local minimum of the mass excess: if such a nucleus has Template:Math numbers, the neighbour nuclei Template:Math and Template:Math have higher mass excess and can beta decay into Template:Math, but not vice versa. For all odd mass numbers Template:Mvar, there is only one known beta-stable isobar. For even Template:Mvar, there are up to three different beta-stable isobars experimentally known; for example, Template:Nuclide, Template:Nuclide, and Template:Nuclide are all beta-stable. There are about 350 known beta-decay stable nuclides.<ref name="nndc_Inte">{{#invoke:citation/CS1|citation |CitationClass=web }}</ref>
Competition of beta decay typesEdit
Usually unstable nuclides are clearly either "neutron rich" or "proton rich", with the former undergoing beta decay and the latter undergoing electron capture (or more rarely, due to the higher energy requirements, positron decay). However, in a few cases of odd-proton, odd-neutron radionuclides, it may be energetically favorable for the radionuclide to decay to an even-proton, even-neutron isobar either by undergoing beta-positive or beta-negative decay.
Three types of beta decay in competition are illustrated by the single isotope Template:Nuclide (29 protons, 35 neutrons), which has a half-life of about 12.7 hours.<ref name="Cu-64">Atomic and Nuclear Data: Chapter 12 Cu-64 Template:Webarchive Laboratoire National Henri Becquerel, 2011. Retrieved on 2024-05-01.</ref> This isotope has one unpaired proton and one unpaired neutron, so either the proton or the neutron can decay.<ref name="Copper-64">{{#invoke:citation/CS1|citation |CitationClass=web }}</ref> This particular nuclide is almost equally likely to undergo proton decay (by positron emission, 18% or by electron capture, 43%; both forming [[Isotopes of nickel|Template:SimpleNuclide]]) or neutron decay (by electron emission, 39%; forming [[Isotopes of zinc|Template:SimpleNuclide]]).<ref name="Cu-64"/><ref name="Copper-64"/>
Stability of naturally occurring nuclidesEdit
Most naturally occurring nuclides on earth are beta stable. Nuclides that are not beta stable have half-lives ranging from under a second to periods of time significantly greater than the age of the universe. One common example of a long-lived isotope is the odd-proton odd-neutron nuclide Template:Nuclide, which undergoes all three types of beta decay (Template:SubatomicParticle, Template:SubatomicParticle and electron capture) with a half-life of Template:Val.<ref> {{#invoke:citation/CS1|citation |CitationClass=web }}</ref>
Conservation rules for beta decayEdit
Baryon number is conservedEdit
<math display="block">B=\frac{n_q - n_{\bar{q}}}{3}</math> where
- <math>n_q</math> is the number of constituent quarks, and
- <math>n_{\overline{q}}</math> is the number of constituent antiquarks.
Beta decay just changes neutron to proton or, in the case of positive beta decay (electron capture) proton to neutron so the number of individual quarks doesn't change. It is only the baryon flavor that changes, here labelled as the isospin.
Up and down quarks have total isospin <math display="inline">I=\frac{1}{2}</math> and isospin projections <math display="block">I_\text{z}=\begin{cases} \frac{1}{2} & \text{up quark} \\ -\frac{1}{2} & \text{down quark} \end{cases}</math>
All other quarks have Template:Math.
In general <math display="block">I_\text{z}=\frac{1}{2} (n_\text{u} - n_\text{d})</math>
Lepton number is conservedEdit
<math display="block">L \equiv n_{\ell} - n_{\bar{\ell}}</math>
so all leptons have assigned a value of +1, antileptons −1, and non-leptonic particles 0. <math display="block">\begin{matrix}
& \text{n} & \rightarrow & \text{p} & + & \text{e}^- & + & \bar{\nu}_\text{e} \\
L: & 0 &=& 0 & + & 1 & - & 1 \end{matrix}</math>
Angular momentumEdit
For allowed decays, the net orbital angular momentum is zero, hence only spin quantum numbers are considered.
The electron and antineutrino are fermions, spin-1/2 objects, therefore they may couple to total <math>S=1</math> (parallel) or <math>S=0</math> (anti-parallel).
For forbidden decays, orbital angular momentum must also be taken into consideration.
Energy releaseEdit
The [[Q value (nuclear science)|Template:Mvar value]] is defined as the total energy released in a given nuclear decay. In beta decay, Template:Mvar is therefore also the sum of the kinetic energies of the emitted beta particle, neutrino, and recoiling nucleus. (Because of the large mass of the nucleus compared to that of the beta particle and neutrino, the kinetic energy of the recoiling nucleus can generally be neglected.) Beta particles can therefore be emitted with any kinetic energy ranging from 0 to Template:Mvar.<ref name="konya74"/> A typical Template:Mvar is around 1 MeV, but can range from a few keV to a few tens of MeV.
Since the rest mass of the electron is 511 keV, the most energetic beta particles are ultrarelativistic, with speeds very close to the speed of light. In the case of 187Re, the maximum speed of the beta particle is only 9.8% of the speed of light.
The following table gives some examples:
| Isotope | Energy (keV) |
Decay mode |
|---|---|---|
| free neutron |
Template:0782.33 | β− |
| Template:03H (tritium) |
Template:018.59 | β− |
| [[carbon-11|Template:011C]] | Template:0960.4 1982.4 |
β+ εTemplate:0 |
| [[Carbon-14|Template:014C]] | Template:0156.475 | β− |
| [[fluorine-20|Template:020F]] | 5390.86 | β− |
| [[Potassium-37|Template:037K]] | 5125.48 6147.48 |
β+ εTemplate:0 |
| 163Ho | Template:02.555 | εTemplate:0 |
| 187Re | Template:02.467 | β− |
| 210Bi | 1162.2 | β− |
Tritium β− decay being used in the KATRIN experimental search for sterile neutrinos.<ref>Template:Cite journal</ref>
β− decayEdit
Consider the generic equation for beta decay
The Template:Mvar value for this decay is
- <math chem>Q=\left[m_N\left(\ce{^\mathit{A}_\mathit{Z}X}\right) - m_N\left(\ce{^\mathit{A}_{\mathit{Z}+1}X'}\right)-m_e-m_{\overline\nu_e}\right]c^2</math>,
where <math chem>m_N\left(\ce{^\mathit{A}_\mathit{Z}X}\right)</math> is the mass of the nucleus of the Template:Physics particle atom, <math chem>m_e</math> is the mass of the electron, and <math chem>m_{\overline\nu_e}</math> is the mass of the electron antineutrino. In other words, the total energy released is the mass energy of the initial nucleus, minus the mass energy of the final nucleus, electron, and antineutrino. The mass of the nucleus Template:Mvar is related to the standard atomic mass Template:Mvar by <math chem display="block">m\left(\ce{^\mathit{A}_\mathit{Z}X}\right)c^2=m_N\left(\ce{^\mathit{A}_\mathit{Z}X}\right)c^2 + Z m_e c^2-\sum_{i=1}^Z B_i.</math> That is, the total atomic mass is the mass of the nucleus, plus the mass of the electrons, minus the sum of all electron binding energies Template:Mvar for the atom. This equation is rearranged to find <math chem>m_N\left(\ce{^\mathit{A}_\mathit{Z}X}\right)</math>, and <math chem>m_N\left(\ce{^\mathit{A}_{\mathit{Z}+1}X'}\right)</math> is found similarly. Substituting these nuclear masses into the Template:Math-value equation, while neglecting the nearly-zero antineutrino mass and the difference in electron binding energies, which is very small for high-Template:Mvar atoms, we have <math chem display="block">Q=\left[m\left(\ce{^\mathit{A}_\mathit{Z}X}\right)-m\left(\ce{^\mathit{A}_{\mathit{Z}+1}X'}\right)\right]c^2</math> This energy is carried away as kinetic energy by the electron and antineutrino.
Because the reaction will proceed only when the Template:Mvar value is positive, β− decay can occur when the mass of atom Template:Physics particle is greater than the mass of atom Template:Physics particle.<ref name="Krane1987">Template:Cite book</ref>
β+ decayEdit
The equations for β+ decay are similar, with the generic equation
giving <math chem display="block">Q=\left[m_N\left(\ce{^\mathit{A}_\mathit{Z}X}\right) - m_N\left(\ce{^\mathit{A}_{\mathit{Z}-1}X'}\right)-m_e-m_{\nu_e}\right]c^2.</math> However, in this equation, the electron masses do not cancel, and we are left with <math chem display="block">Q=\left[m\left(\ce{^\mathit{A}_\mathit{Z}X}\right)-m\left(\ce{^\mathit{A}_{\mathit{Z}-1}X'}\right)-2m_e\right]c^2.</math>
Because the reaction will proceed only when the Template:Mvar value is positive, β+ decay can occur when the mass of atom Template:Physics particle exceeds that of Template:Physics particle by at least twice the mass of the electron.<ref name="Krane1987" />
Electron captureEdit
The analogous calculation for electron capture must take into account the binding energy of the electrons. This is because the atom will be left in an excited state after capturing the electron, and the binding energy of the captured innermost electron is significant. Using the generic equation for electron capture
we have <math chem display="block">Q=\left[m_N\left(\ce{^\mathit{A}_\mathit{Z}X}\right) + m_e - m_N\left(\ce{^\mathit{A}_{\mathit{Z}-1}X'}\right)-m_{\nu_e}\right]c^2,</math> which simplifies to <math chem display="block">Q=\left[m\left(\ce{^\mathit{A}_\mathit{Z}X}\right) - m\left(\ce{^\mathit{A}_{\mathit{Z}-1}X'}\right)\right]c^2-B_n,</math> where Template:Mvar is the binding energy of the captured electron.
Because the binding energy of the electron is much less than the mass of the electron, nuclei that can undergo β+ decay can always also undergo electron capture, but the reverse is not true.<ref name="Krane1987" />
Beta emission spectrumEdit
Beta decay can be considered as a perturbation as described in quantum mechanics, and thus Fermi's Golden Rule can be applied. This leads to an expression for the kinetic energy spectrum Template:Math of emitted betas as follows:<ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref>
<math display="block">N(T) = C_L(T) F(Z,T) p E (Q-T)^2</math>
where Template:Mvar is the kinetic energy, Template:Mvar is a shape function that depends on the forbiddenness of the decay (it is constant for allowed decays), Template:Math is the Fermi Function (see below) with Z the charge of the final-state nucleus, Template:Math is the total energy, <math> p = \sqrt{(E/c)^2 - (mc)^2}</math> is the momentum, and Template:Mvar is the Q value of the decay. The kinetic energy of the emitted neutrino is given approximately by Template:Mvar minus the kinetic energy of the beta.
As an example, the beta decay spectrum of 210Bi (originally called RaE) is shown to the right.
Fermi functionEdit
The Fermi function that appears in the beta spectrum formula accounts for the Coulomb attraction / repulsion between the emitted beta and the final state nucleus. Approximating the associated wavefunctions to be spherically symmetric, the Fermi function can be analytically calculated to be:<ref>Template:Cite journal</ref>
<math display="block">F(Z,T)=\frac{2 (1+S)}{\Gamma(1+2S)^2} (2 p \rho)^{2S-2} e^{\pi \eta} |\Gamma(S+i \eta)|^2,</math>
where Template:Mvar is the final momentum, Γ the Gamma function, and (if Template:Mvar is the fine-structure constant and Template:Mvar the radius of the final state nucleus) <math>S = \sqrt{1 - \alpha^2 Z^2}</math>, <math>\eta = \pm Ze^2E/(\hbar cp)</math> (+ for electrons, − for positrons), and <math>\rho = r_N/\hbar </math>.
For non-relativistic betas (Template:Math), this expression can be approximated by:<ref>Template:Cite book</ref>
<math display="block">F(Z,T) \approx \frac{2 \pi \eta}{1 - e^{- 2 \pi \eta}}.</math>
Other approximations can be found in the literature.<ref>Template:Cite journal</ref><ref>Template:Cite journal</ref>
Kurie plotEdit
A Kurie plot (also known as a Fermi–Kurie plot) is a graph used in studying beta decay developed by Franz N. D. Kurie, in which the square root of the number of beta particles whose momentum (or energy) lies within a certain narrow range, divided by the Fermi function, is plotted against beta-particle energy.<ref>Template:Cite journal</ref><ref>Template:Cite journal</ref> It is a straight line for allowed transitions and some forbidden transitions, in accord with the Fermi beta-decay theory. The energy-axis (x-axis) intercept of a Kurie plot corresponds to the maximum energy imparted to the electron/positron (the decay's Template:Mvar value). With a Kurie plot one can find the limit on the effective mass of a neutrino.<ref>Template:Cite journal</ref>
Helicity (polarization) of neutrinos, electrons and positrons emitted in beta decayEdit
After the discovery of parity non-conservation (see History), it was found that, in beta decay, electrons are emitted mostly with negative helicity, i.e., they move, naively speaking, like left-handed screws driven into a material (they have negative longitudinal polarization).<ref>Template:Cite journal</ref> Conversely, positrons have mostly positive helicity, i.e., they move like right-handed screws. Neutrinos (emitted in positron decay) have negative helicity, while antineutrinos (emitted in electron decay) have positive helicity.<ref>Template:Cite book</ref>
The higher the energy of the particles, the higher their polarization.
Types of beta decay transitionsEdit
{{#invoke:Labelled list hatnote|labelledList|Main article|Main articles|Main page|Main pages}} Beta decays can be classified according to the angular momentum ([[Angular momentum operator|Template:Mvar value]]) and total spin ([[Spin (physics)|Template:Mvar value]]) of the emitted radiation. Since total angular momentum must be conserved, including orbital and spin angular momentum, beta decay occurs by a variety of quantum state transitions to various nuclear angular momentum or spin states, known as "Fermi" or "Gamow–Teller" transitions. When beta decay particles carry no angular momentum (Template:Math), the decay is referred to as "allowed", otherwise it is "forbidden".
Other decay modes, which are rare, are known as bound state decay and double beta decay.
Fermi transitionsEdit
A Fermi transition is a beta decay in which the spins of the emitted electron (positron) and anti-neutrino (neutrino) couple to total spin <math>S=0</math>, leading to an angular momentum change <math>\Delta J=0</math> between the initial and final states of the nucleus (assuming an allowed transition). In the non-relativistic limit, the nuclear part of the operator for a Fermi transition is given by <math display="block"> \mathcal{O}_{F}=G_{V}\sum_{a} \hat{\tau}_{a\pm} </math> with <math>G_V</math> the weak vector coupling constant, <math>\tau_{\pm}</math> the isospin raising and lowering operators, and <math>a</math> running over all protons and neutrons in the nucleus.
Gamow–Teller transitionsEdit
A Gamow–Teller transition is a beta decay in which the spins of the emitted electron (positron) and anti-neutrino (neutrino) couple to total spin <math>S=1</math>, leading to an angular momentum change <math>\Delta J=0,\pm 1</math> between the initial and final states of the nucleus (assuming an allowed transition). In this case, the nuclear part of the operator is given by <math display="block"> \mathcal{O}_{GT}=G_{A}\sum_{a} \hat{\sigma}_{a}\hat{\tau}_{a\pm} </math> with <math>G_{A}</math> the weak axial-vector coupling constant, and <math>\sigma</math> the spin Pauli matrices, which can produce a spin-flip in the decaying nucleon.
Forbidden transitionsEdit
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When Template:Math, the decay is referred to as "forbidden". Nuclear selection rules require high Template:Mvar values to be accompanied by changes in nuclear spin (Template:Mvar) and parity (Template:Mvar). The selection rules for the Template:Mvarth forbidden transitions are: <math display="block">\Delta J=L-1, L, L+1; \Delta \pi=(-1)^L, </math> where Template:Math corresponds to no parity change or parity change, respectively. The special case of a transition between isobaric analogue states, where the structure of the final state is very similar to the structure of the initial state, is referred to as "superallowed" for beta decay, and proceeds very quickly. The following table lists the ΔTemplate:Var and ΔTemplate:Var values for the first few values of Template:Mvar:
| Forbiddenness | ΔTemplate:Var | ΔTemplate:Var |
|---|---|---|
| Superallowed | 0 | Template:No |
| Allowed | 0, 1 | Template:No |
| First forbidden | 0, 1, 2 | Template:Yes |
| Second forbidden | 1, 2, 3 | Template:No |
| Third forbidden | 2, 3, 4 | Template:Yes |
Rare decay modesEdit
Bound-state β− decayEdit
A very small minority of free neutron decays (about four per million) are "two-body decays": the proton, electron and antineutrino are produced, but the electron fails to gain the 13.6 eV energy necessary to escape the proton, and therefore simply remains bound to it, as a neutral hydrogen atom.<ref>An Overview Of Neutron Decay Template:Webarchive J. Byrne in Quark-Mixing, CKM Unitarity (H. Abele and D. Mund, 2002), see p.XV</ref> In this type of beta decay, in essence all of the neutron decay energy is carried off by the antineutrino.
For fully ionized atoms (bare nuclei), it is possible in likewise manner for electrons to fail to escape the atom, and to be emitted from the nucleus into low-lying atomic bound states (orbitals). This cannot occur for neutral atoms with low-lying bound states which are already filled by electrons.
Bound-state β− decays were predicted by Daudel, Jean, and Lecoin in 1947,<ref>Template:Cite journal</ref> and the phenomenon in fully ionized atoms was first observed for 163Dy66+ in 1992 by Jung et al. of the Darmstadt Heavy-Ion Research Center. Though neutral 163Dy is stable, fully ionized 163Dy66+ undergoes β− decay into the K and L shells with a half-life of 47 days.<ref>Template:Cite journal</ref> The resulting nucleus – 163Ho66+ – is stable only in this almost fully ionized state and will decay via electron capture into 163Dy in the neutral state. Likewise, while being stable in the neutral state, the fully ionized 205Tl81+ undergoes bound-state β− decay to 205Pb81+ with a half-life of Template:Val days.<ref>{{#invoke:citation/CS1|citation |CitationClass=web }}</ref><ref>Template:Cite journal</ref> The half-lives of neutral 163Ho and 205Pb are respectively 4570 years and Template:Val years. In addition, it is estimated that β− decay is energetically impossible for natural atoms but theoretically possible when fully ionized also for 193Ir, 194Au, 202Tl, 215At, 243Am, and 246Bk.<ref name="bs-prediction">Template:Cite journal</ref>
Another possibility is that a fully ionized atom undergoes greatly accelerated β decay, as observed for 187Re by Bosch et al., also at Darmstadt. Neutral 187Re does undergo β− decay, with half-life Template:Val years,Template:NUBASE2020 but for fully ionized 187Re75+ this is shortened to only 32.9 years. This is because 187Re75+ is energetically allowed to undergo β− decay to the first-excited state in 187Os75+, a process energetically disallowed for natural 187Re.<ref>Template:Cite journal
"Note also, that the decay of bare 187Re is dominated by the nonunique transition to the first excited state of 187Os, since the decay to the ground state has a much smaller matrix element."</ref> Similarly, neutral 241Pu undergoes β− decay with a half-life of 14.3 years, but in its fully ionized state the beta-decay half-life of 241Pu94+ decreases to 4.2 days.<ref>Template:Cite journal</ref> For comparison, the variation of decay rates of other nuclear processes due to chemical environment is less than 1%. Moreover, current mass determinations cannot decisively determine whether 222Rn is energetically possible to undergo β− decay (the decay energy given in AME2020 is (−6 ± 8) keV),Template:AME2020 II<ref>Template:Cite journal</ref> but in either case it is predicted that β− will be greatly accelerated for fully ionized 222Rn86+.<ref name="bs-prediction" />
Double beta decayEdit
{{#invoke:Labelled list hatnote|labelledList|Main article|Main articles|Main page|Main pages}} Some nuclei can undergo double beta decay (2β) where the charge of the nucleus changes by two units. Double beta decay is difficult to study, as it has an extremely long half-life. In nuclei for which both β decay and 2β are possible, the rarer 2β process is effectively impossible to observe. However, in nuclei where β decay is forbidden but 2β is allowed, the process can be seen and a half-life measured.<ref name="Bilenky">Template:Cite journal</ref> Thus, 2β is usually studied only for beta stable nuclei. Like single beta decay, double beta decay does not change Template:Mvar; thus, at least one of the nuclides with some given Template:Mvar has to be stable with regard to both single and double beta decay.
"Ordinary" 2β results in the emission of two electrons and two antineutrinos. If neutrinos are Majorana particles (i.e., they are their own antiparticles), then a decay known as neutrinoless double beta decay will occur. Most neutrino physicists believe that neutrinoless 2β has never been observed.<ref name="Bilenky" />
See alsoEdit
- Common beta emitters
- Neutrino
- Betavoltaics
- Particle radiation
- Radionuclide
- Tritium illumination, a form of fluorescent lighting powered by beta decay
- Pandemonium effect
- Total absorption spectroscopy
ReferencesEdit
BibliographyEdit
External linksEdit
- File:Ndslivechart.png The Live Chart of Nuclides - IAEA with filter on decay type
- Beta decay simulation [1]
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