Lyman-alpha, typically denoted by Ly-α or Lyα, is a spectral line of hydrogen (or, more generally, of any one-electron atom) in the Lyman series. It is emitted when the atomic electron transitions from an n = 2 orbital to the ground state (n = 1), where n is the principal quantum number. In hydrogen, its wavelength of 1215.67 angstroms (Template:Val or Template:Val), corresponding to a frequency of about Template:Val, places Lyman-alpha in the ultraviolet (UV) part of the electromagnetic spectrum. More specifically, Ly-α lies in vacuum UV (VUV), characterized by a strong absorption in the air.
Fine structureEdit
Because of the spin–orbit interaction, the Lyman-alpha line splits into a fine-structure doublet with the wavelengths of 1215.668 and 1215.674 angstroms.<ref>Template:Citation</ref> These components are called Ly-α3/2 and Ly-α1/2, respectively.
The eigenstates of the perturbed Hamiltonian are labeled by the total angular momentum j of the electron, not just the orbital angular momentum l. In the n = 2, l = 1 orbital, there are two possible states, with j = Template:Sfrac and j = Template:Sfrac, resulting in a spectral doublet. The j = Template:Sfrac state has a higher energy and so is energetically farther from the n = 1 state to which it is transitioning. Thus, the j = Template:Sfrac state is associated with the more energetic (having a shorter wavelength) spectral line in the doublet.<ref>Template:Cite book</ref>
ObservationEdit
Since the hydrogen Lyman-alpha radiation is strongly absorbed by the air, its observation in laboratory requires use of vacuumed spectroscopic systems. For the same reason, Lyman-alpha astronomy is ordinarily carried out by satellite-borne instruments, except for observing extremely distant sources whose redshifts allow the line to penetrate the Earth atmosphere.
The line was also observed in antihydrogen.<ref>Template:Cite journal</ref> Within the experimental uncertainties, the measured frequency is equal to that of hydrogen, in agreement with predictions of quantum electrodynamics.