Polyene

In organic chemistry, polyenes are polyunsaturated organic compounds that contain multiple carbon–carbon double bonds (Template:Chem2).<ref name=Penguin2ed>Template:Cite book</ref><ref name=OED2rev>Template:Cite book</ref> Some sources consider dienes to be polyenes,<ref>Template:Cite book</ref> whereas others require polyenes to contain at least three carbon–carbon double bonds.<ref name=StructChem>Template:Cite book</ref>

Conjugated polyenes contain a conjugated system of alternating single and double carbon–carbon bonds, with characteristic optical properties.

The following polyenes are used as antimycotics for humans: amphotericin B, nystatin, candicidin, pimaricin, methyl partricin, and trichomycin.<ref>Template:Cite journal</ref>

Optical properties

Some polyenes are brightly colored, an otherwise rare property for a hydrocarbon. Normally alkenes absorb in the ultraviolet region of a spectrum, but the absorption energy state of polyenes with numerous conjugated double bonds can be lowered such that they enter the visible region of the spectrum, resulting in compounds which are coloured (because they contain a chromophore). Thus many natural dyes contain linear polyenes.

Chemical and electrical properties

Polyenes tend to be more reactive than simpler alkenes. For example, polyene-containing triglycerides are reactive towards atmospheric oxygen. Polyacetylene, which partially oxidized or reduced, exhibits high electrical conductivity. Most conductive polymers are polyenes, and many have conjugated structures. Poly(aza)acetylenes are readily prepared from pyridine precursors without the necessity of a controlled atmosphere, simply by ultraviolet irradiation of a mixture of pyridine and poly(4-vinyl) pyridine.Template:Citation needed Recent research at the Weizmann Institute and Aix-Marseille University showed a clear transition between ionic and electronic conductivity with increasing UV dose over 30 hours.<ref>Template:Cite journal</ref>

Occurrence

A few fatty acids are polyenes. Another class of important polyenes are polyene antimycotics.<ref name="ncbi">{{#invoke:citation/CS1|citation |CitationClass=web }}</ref>

• Representative polyenes
• Amphotericin B new.svg

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• Leukotriene A4.svg

  Leukotriene A4 is a regulator of the immune response.

• Trans-Polyacetylene.svg

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