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Barium oxide
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{{Short description|Chemical compound used in cathode-ray tubes}} {{redirect|BaO||BAO (disambiguation)|and|Bao (disambiguation)}} {{Chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 443645196 | Name = Barium oxide | ImageFile = Barium-oxide-3D-vdW.png | ImageFile1 = Barium oxide.JPG | OtherNames = {{unbulleted list | Neutral barium oxide (1:1) | Barium protoxide | Calcined baryta | Baria }} | IUPACName = | SystematicName = | Section1 = {{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 56180 | InChI = 1/Ba.O/rBaO/c1-2 | SMILES = [Ba]=O | InChIKey = QVQLCTNNEUAWMS-FXUTYLCTAB | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Ba.O | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = QVQLCTNNEUAWMS-UHFFFAOYSA-N | CASNo = 1304-28-5 | CASNo_Ref = {{cascite|correct|CAS}} | UNII_Ref = {{fdacite|correct|FDA}} | UNII = 77603K202B | RTECS = CQ9800000 | PubChem = 62392 | EC_number = 215-127-9 | UNNumber = 1884 }} | Section2 = {{Chembox Properties | Formula = | Ba=1 | O = 1 | MolarMass = 153.326 g/mol | Appearance = white solid | Density = 5.72 g/cm<sup>3</sup>, solid | Solubility = {{unbulleted list | 3.48 g/100 mL (20 °C) | 90.8 g/100 mL (100 °C) | Reacts to form [[Barium hydroxide|Ba(OH)<sub>2</sub>]] }} | SolubleOther = soluble in [[ethanol]], dilute mineral acids and alkalies; insoluble in [[acetone]] and liquid [[ammonia]] | MeltingPtC = 1923 | MeltingPt_notes = | BoilingPt = ~ | BoilingPtC = 2000 | MagSus = −29.1·10<sup>−6</sup> cm<sup>3</sup>/mol }} | Section3 = {{Chembox Structure | Coordination = [[octahedron|Octahedral]] | CrystalStruct = [[Cubic crystal system|cubic]], [[Pearson symbol|cF8]] | SpaceGroup = Fm<u style="text-decoration:overline">3</u>m, No. 225 }} | Section4 = {{Chembox Thermochemistry | DeltaHf = −582 kJ·mol<sup>−1</sup><ref name="Zumdahl">{{cite book| author = Zumdahl, Steven S.|title =Chemical Principles 6th Ed.| publisher = Houghton Mifflin Company| year = 2009| isbn = 978-0-618-94690-7}}</ref> | Entropy = 70 J·mol<sup>−1</sup>·K<sup>−1</sup><ref name="Zumdahl"/> | HeatCapacity = 47.7 J/K mol }} | Section5 = | Section6 = | Section7 = {{Chembox Hazards | GHSPictograms = {{GHS05}}{{GHS06}}{{GHS07}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|301|302|314|315|332|412}} | PPhrases = {{P-phrases|210|220|221|260|261|264|270|271|273|280|283|301+310|301+312|301+330+331|302+352|303+361+353|304+312|304+340|305+351+338|306+360|310|312|321|330|332+313|362|363|370+378|371+380+375|405|501}} | NFPA-H = 3 | NFPA-F = 0 | NFPA-R = 0 | FlashPt = Non-flammable }} | Section8 = {{Chembox Related | OtherAnions = {{unbulleted list | [[Barium hydroxide]] | [[Barium peroxide]] }} | OtherCations = {{unbulleted list | [[Beryllium oxide]] | [[Magnesium oxide]] | [[Calcium oxide]] | [[Strontium oxide]] }} }} }} '''Barium oxide''', also known as '''baria''', is a white [[hygroscopic]] non-flammable [[chemical compound|compound]] with the formula BaO. It has a [[Cubic crystal system|cubic]] structure and is used in [[cathode-ray tube]]s, crown glass, and [[Catalysis|catalysts]]. It is harmful to human skin and if swallowed in large quantity causes irritation. Excessive quantities of barium oxide may lead to death. It is prepared by heating [[barium carbonate]] with [[coke (fuel)|coke]], [[carbon black]] or [[tar]] or by [[thermal decomposition]] of [[barium nitrate]].{{Citation needed|date=September 2014}}
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