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CNO cycle
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{{short description|Catalysed fusion reactions by which stars convert hydrogen to helium}} {{Use dmy dates|date=August 2021}} [[File:Nuclear energy generation.svg|right|upright=1.5|thumb|300px|[[Logarithm]] of the relative energy output (ε) of [[Proton–proton chain reaction|proton–proton]] (p–p), CNO, and [[Triple-alpha process|triple-α]] fusion processes at different temperatures (T). The dashed line shows the combined energy generation of the p–p and CNO processes within a star.]] In [[astrophysics]], the '''carbon–nitrogen–oxygen''' ('''CNO''') '''cycle''', sometimes called '''Bethe–Weizsäcker cycle''', after [[Hans Albrecht Bethe]] and [[Carl Friedrich von Weizsäcker]], is one of the two known sets of [[nuclear fusion|fusion]] [[nuclear reaction|reactions]] by which [[star]]s convert [[hydrogen]] to [[helium]], the other being the [[proton–proton chain reaction]] (p–p cycle), which is more efficient at the [[Sun]]'s core temperature. The CNO cycle is hypothesized to be dominant in stars that are more than 1.3 times as [[Solar mass|massive as the Sun]].<ref name=salaris_cassini2005/> Unlike the proton-proton reaction, which consumes all its constituents, the CNO cycle is a [[catalytic cycle]]. In the CNO cycle, four [[proton]]s fuse, using [[carbon]], [[nitrogen]], and [[oxygen]] isotopes as catalysts, each of which is consumed at one step of the CNO cycle, but re-generated in a later step. The end product is one [[alpha particle]] (a [[stable nuclide|stable]] [[helium]] nucleus), two [[positron]]s, and two [[electron neutrino]]s. There are various alternative paths and catalysts involved in the CNO cycles, but all these cycles have the same net result: :4 {{nuclide|Hydrogen|1}} + 2 {{SubatomicParticle|Electron}} :: → {{nuclide|Helium|4}} + {{math|2 {{SubatomicParticle|Positron}} + 2 {{SubatomicParticle|Electron}} + 2 {{SubatomicParticle|Electron neutrino}} + 3 {{SubatomicParticle|Gamma}}}} + {{val|24.7|ul=MeV}} :: → {{nuclide|Helium|4}} + {{math|2 {{SubatomicParticle|Electron neutrino}} + 7 {{SubatomicParticle|Gamma}}}} + {{val|26.7|u=MeV}} The positrons will almost instantly [[Electron–positron annihilation|annihilate with electrons]], releasing energy in the form of [[gamma ray]]s. The neutrinos escape from the star carrying away some energy.<ref name="BOREXINO">{{cite journal |collaboration=The BOREXINO collaboration |date=25 June 2020 |title=Experimental evidence of neutrinos produced in the CNO fusion cycle in the Sun |arxiv=2006.15115 |language=en|last1=Agostini |first1=M. |last2=Altenmüller |first2=K. |last3=Appel |first3=S. |last4=Atroshchenko |first4=V. |last5=Bagdasarian |first5=Z. |last6=Basilico |first6=D. |last7=Bellini |first7=G. |last8=Benziger |first8=J. |last9=Biondi |first9=R. |last10=Bravo |first10=D. |last11=Caccianiga |first11=B. |last12=Calaprice |first12=F. |last13=Caminata |first13=A. |last14=Cavalcante |first14=P. |last15=Chepurnov |first15=A. |last16=D'Angelo |first16=D. |last17=Davini |first17=S. |last18=Derbin |first18=A. |last19=Di Giacinto |first19=A. |last20=Di Marcello |first20=V. |last21=Ding |first21=X. F. |last22=Di Ludovico |first22=A. |last23=Di Noto |first23=L. |last24=Drachnev |first24=I. |last25=Formozov |first25=A. |last26=Franco |first26=D. |last27=Galbiati |first27=C. |last28=Ghiano |first28=C. |last29=Giammarchi |first29=M. |last30=Goretti |first30=A. |journal=Nature |volume=587 |issue=7835 |pages=577–582 |doi=10.1038/s41586-020-2934-0 |pmid=33239797 |bibcode=2020Natur.587..577B |s2cid=227174644 |display-authors=2 }}</ref> One nucleus goes on to become carbon, nitrogen, and oxygen isotopes through a number of transformations in a repeating cycle. [[Image:CNO Cycle.svg|300px|right|thumbnail|Overview of the CNO-I Cycle]] The proton–proton chain is more prominent in stars the mass of the Sun or less. This difference stems from temperature dependency differences between the two reactions; pp-chain reaction starts at temperatures around {{val|4|e=6|ul=K}}<ref>{{cite book | last1=Reid | first1=I. Neill | last2=Hawley | first2=Suzanne L. | year=2005 | chapter=The structure, formation, and evolution of low-mass stars and brown dwarfs – Energy generation | title=New Light on Dark Stars: Red dwarfs, low-mass stars, brown dwarfs | edition=2nd | pages=108–111 | series=Springer-Praxis Books in Astrophysics and Astronomy | publisher=[[Springer Science & Business Media]] | isbn=3-540-25124-3 | chapter-url=https://books.google.com/books?id=o7pe7Fp4JaAC&pg=PA108 }}</ref> (4 megakelvin), making it the dominant energy source in smaller stars. A self-maintaining CNO chain starts at approximately {{val|15|e=6|ul=K}}, but its energy output rises much more rapidly with increasing temperatures<ref name=salaris_cassini2005>{{cite book | first1=Maurizio | last1=Salaris | first2=Santi | last2=Cassisi | year=2005 | title=Evolution of Stars and Stellar Populations | pages=[https://archive.org/details/evolutionofstars0000sala/page/119 119]–121 | publisher=[[John Wiley and Sons]] | isbn=0-470-09220-3 | url=https://archive.org/details/evolutionofstars0000sala | url-access=registration }}</ref> so that it becomes the dominant source of energy at approximately {{val|17|e=6|ul=K}}.<ref> {{cite journal | last1=Schuler |first1=S.C. | last2=King |first2=J.R. | last3=The |first3=L.-S. | year=2009 | title=Stellar Nucleosynthesis in the Hyades open cluster | journal=[[The Astrophysical Journal]] | volume=701 | issue=1 | pages=837–849 | arxiv=0906.4812 | bibcode=2009ApJ...701..837S | doi=10.1088/0004-637X/701/1/837 |s2cid=10626836 }}</ref> The Sun has a [[solar core|core]] temperature of around {{val|15.7|e=6|ul=K}}, and only {{val|1.7|s=%}} of {{SimpleNuclide|Helium|4|link=yes}} nuclei produced in the Sun are born in the CNO cycle. The [[#CNO-I|CNO-I]] process was independently proposed by [[Carl Friedrich von Weizsäcker|Carl von Weizsäcker]]<ref name = vonWeizsäcker-1> {{cite journal |last=von Weizsäcker |first=Carl F. |author-link=Carl Friedrich von Weizsäcker |title=Über Elementumwandlungen in Innern der Sterne I |trans-title= On transformations of elements in the interiors of stars I |journal=[[Physikalische Zeitschrift]] |volume=38 |year=1937 |pages=176–191 }}</ref><ref name = vonWeizsäcker-2> {{cite journal |last=von Weizsäcker |first=Carl F. |author-link=Carl Friedrich von Weizsäcker |title=Über Elementumwandlungen in Innern der Sterne II |trans-title= On transformations of elements in the interiors of stars II |journal=[[Physikalische Zeitschrift]] |volume=39 |year=1938 |pages=633–646 }}</ref> and [[Hans Bethe]]<ref name = Bethe-1939-a> {{cite journal |last = Bethe |first = Hans A. |author-link = Hans Bethe |year = 1939 |title = Energy Production in Stars |journal = [[Physical Review]] |volume = 55 |issue = 1 |pages = 541–7 |doi = 10.1103/PhysRev.55.103 |pmid = 17835673 |doi-access = free |bibcode = 1939PhRv...55..103B }}</ref><ref name = Bethe-1939-b/> in the late 1930s. The first reports of the experimental detection of the neutrinos produced by the CNO cycle in the Sun were published in 2020 by the [[Borexino|BOREXINO]] collaboration. This was also the first experimental confirmation that the Sun had a CNO cycle, that the proposed magnitude of the cycle was accurate, and that von Weizsäcker and Bethe were correct.<ref name="BOREXINO"/><ref>{{Cite journal|last1=Agostini|first1=M.|last2=Altenmüller|first2=K.|last3=Appel|first3=S.|last4=Atroshchenko|first4=V.|last5=Bagdasarian|first5=Z.|last6=Basilico|first6=D.|last7=Bellini|first7=G.|last8=Benziger|first8=J.|last9=Biondi|first9=R.|last10=Bravo|first10=D.|last11=Caccianiga|first11=B.|date=25 November 2020|title=Experimental evidence of neutrinos produced in the CNO fusion cycle in the Sun|url=https://www.nature.com/articles/s41586-020-2934-0|journal=Nature|language=en|volume=587|issue=7835|pages=577–582|doi=10.1038/s41586-020-2934-0|pmid=33239797|issn=1476-4687|quote=This result therefore paves the way towards a direct measurement of the solar metallicity using CNO neutrinos. Our findings quantify the relative contribution of CNO fusion in the Sun to be of the order of 1 per cent;|arxiv=2006.15115|bibcode=2020Natur.587..577B|s2cid=227174644}}</ref><ref>{{Cite web|title=Neutrinos yield first experimental evidence of catalyzed fusion dominant in many stars|url=https://phys.org/news/2020-11-neutrinos-yield-experimental-evidence-catalyzed.html|access-date=2020-11-26|website=phys.org|language=en|quote=Pocar points out, "Confirmation of CNO burning in our sun, where it operates at only one percent, reinforces our confidence that we understand how stars work."}}</ref>
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