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Calcium oxide
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{{Short description|Chemical compound of calcium}} {{Redirect-distinguish|Quicklime|Quickline}} {{Chembox | Name = Calcium oxide | ImageFile = Calcium-oxide-3D-vdW.png | ImageSize = | ImageName = Calcium oxide | ImageFile1 = Calcium oxide powder.JPG | ImageCaption = Ionic crystal structure of calcium oxide<br/>{{colorbox|#ffffff}} [[Calcium|Ca<sup>2+</sup>]] {{colorbox|#ff0000}} [[Oxygen|O]]<sup>[[Oxide|2-]]</sup> | ImageCaption1 = Powder sample of white calcium oxide | IUPACName = Calcium oxide | OtherNames = {{Unbulleted list|[[Lime (material)|Lime]]|Quicklime|Burnt lime|Unslaked lime|Free lime ''(building)''|Caustic lime|Pebble lime|Calcia|Oxide of calcium}} | SystematicName = | Section1 = {{Chembox Identifiers | ChemSpiderID = 14095 | UNII = C7X2M0VVNH | InChI = 1/Ca.O/rCaO/c1-2 | ChEBI = 31344 | ChEMBL = 2104397 | EC_number = 215-138-9 | InChIKey = ODINCKMPIJJUCX-BFMVISLHAU | CASNo = 1305-78-8 | PubChem = 14778 | RTECS = EW3100000 | Gmelin = 485425 | KEGG = C13140 | UNNumber = 1910 | StdInChI=1S/Ca.O | StdInChIKey = ODINCKMPIJJUCX-UHFFFAOYSA-N | SMILES = O=[Ca] }} | Section2 = {{Chembox Properties | Formula = CaO | MolarMass = 56.0774{{nbsp}}g/mol | Appearance = White to pale yellow/brown powder | Odor = Odorless | Density = 3.34{{nbsp}}g/cm<sup>3</sup><ref name=crc/> | Solubility = Reacts to form [[calcium hydroxide]] | MeltingPtC = 2613 | MeltingPt_ref = <ref name=crc>{{RubberBible92nd|page=4.55}}</ref> | BoilingPtC = 2850 | BoilingPt_notes = (100{{nbsp}}[[hPa]])<ref name=r1>[http://gestis.itrust.de/nxt/gateway.dll/gestis_de/001200.xml?f=templates$fn=default.htm$3.0 Calciumoxid] ({{webarchive|url=https://web.archive.org/web/20131230232501/http://gestis.itrust.de/nxt/gateway.dll/gestis_de/001200.xml?f=templates%24fn%3Ddefault.htm%243.0 |date=2013-12-30 }}). GESTIS database</ref> | pKa = 12.8 | Solvent2 = Methanol | Solubility2 = Insoluble (also in [[diethyl ether]], [[octanol]]) | MagSus = −15.0×10<sup>−6</sup>{{nbsp}}cm<sup>3</sup>/mol }} | Section3 = {{Chembox Structure | CrystalStruct = [[Cubic crystal system|Cubic]], [[Pearson symbol|cF8]] }} | Section4 = | Section5 = {{Chembox Thermochemistry | DeltaHf = −635 kJ·mol<sup>−1</sup><ref name=b1>{{cite book| author = Zumdahl, Steven S.|title =Chemical Principles 6th Ed.| publisher = Houghton Mifflin Company| year = 2009| isbn = 978-0-618-94690-7|page=A21}}</ref> | Entropy = 40 J·mol<sup>−1</sup>·K<sup>−1</sup><ref name=b1 /> }} | Section6 = {{Chembox Pharmacology | ATCvet = yes | ATCCode_prefix = P53 | ATCCode_suffix = AX18 }} | Section7 = {{Chembox Hazards | GHSPictograms = {{GHS05}}{{GHS07}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|302|314|315|335}} | PPhrases = {{P-phrases|260|261|264|270|271|280|301+312|301+330+331|302+352|303+361+353|304+340|305+351+338|310|312|321|330|332+313|362|363|403+233|405|501}} | ExternalSDS = [https://www.inchem.org/documents/icsc/icsc/eics0409.htm ICSC 0409] | NFPA-H = 3 | NFPA-F = 0 | NFPA-R = 2 | NFPA-S = w | FlashPt = Non-flammable | FlashPt_ref = <ref name=PGCH/> | PEL = TWA 5{{nbsp}}mg/m<sup>3</sup><ref name=PGCH>{{PGCH|0093}}</ref> | REL = TWA 2{{nbsp}}mg/m<sup>3</sup><ref name=PGCH/> | IDLH = 25{{nbsp}}mg/m<sup>3</sup><ref name=PGCH/> | LD50 = >2000 mg/kg oral, female rat <ref>https://www.fishersci.com/store/msds?partNumber=AC196910025&countryCode=US&language=en</ref> }} | Section8 = {{Chembox Related | OtherAnions = {{Plainlist| * [[Calcium sulfide]] * [[Calcium hydroxide]] * [[Calcium selenide]] * [[Calcium telluride]] }} | OtherCations = {{Plainlist| * [[Beryllium oxide]] * [[Magnesium oxide]] * [[Strontium oxide]] * [[Barium oxide]] * [[Radium oxide]] }} }} }} '''Calcium oxide''' ([[chemical formula|formula]]: [[calcium|Ca]][[oxygen|O]]), commonly known as '''quicklime''' or '''burnt lime''', is a widely used [[chemical compound]]. It is a white, [[corrosive substance|caustic]], [[alkali]]ne, [[crystal]]line solid at [[room temperature]]. The broadly used term ''[[lime (material)|lime]]'' connotes calcium-containing [[inorganic compound]]s, in which [[carbonate]]s, [[oxide]]s, and [[hydroxide]]s of calcium, [[silicon]], [[magnesium]], [[aluminium]], and [[iron]] predominate. By contrast, ''quicklime'' specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in [[building material|building products]], such as [[cement]], is called '''free lime'''.<ref>{{cite web |url=http://www.dictionaryofconstruction.com/definition/free-lime.html |title=free lime |publisher= DictionaryOfConstruction.com |archive-url=https://web.archive.org/web/20171209222951/http://www.dictionaryofconstruction.com/definition/free-lime.html |archive-date=2017-12-09 |url-status=dead}}</ref> Quicklime is relatively inexpensive. Both it and the chemical derivative [[calcium hydroxide]] (of which quicklime is the [[base anhydride]]) are important commodity chemicals.
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