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Calcium peroxide
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{{Short description|Chemical compound}} {{Redirect|CaO2|"CaO2" as a symbol for arterial oxygen content|Hypoxia (medical)#arterial oxygen content}} {{Chembox | Watchedfields = changed | verifiedrevid = 476998612 | Name = Calcium peroxide | ImageFile = Crystal structure of CaO2.jpg | ImageName = Calcium peroxide | OtherNames = {{Unbulleted list | Calcium dioxide<ref>{{cite web | url=https://sor.epa.gov/sor_internet/registry/substreg/searchandretrieve/advancedsearch/externalSearch.do?p_type=SRSITN&p_value=82271 | title=Substance Registry Services | US EPA }}</ref> }} |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 14096 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = 7FRO2ENO91 | InChI = 1/Ca.O2/c;1-2/q+2;-2 | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 48233 | EC_number = 215-139-4 | Gmelin = 674257 | KEGG = C18566 | UNNumber = 1457 | SMILES = [Ca+2].[O-][O-] | InChIKey = LHJQIRIGXXHNLA-UHFFFAOYAW | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Ca.O2/c;1-2/q+2;-2 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = LHJQIRIGXXHNLA-UHFFFAOYSA-N | CASNo = 1305-79-9 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 14779 | RTECS = EW3865000 }} |Section2={{Chembox Properties | Ca=1 | O=2 | Density = 2.91 g/cm<sup>3</sup> | Appearance = white or yellowish powder | Odor = odorless | Solubility = decomposes | MeltingPt= ~ | MeltingPtC = 355 | MeltingPt_notes = (decomposes) | BoilingPt = | pKa = 12.5 | RefractIndex = 1.895 | MagSus = β23.8Β·10<sup>β6</sup> cm<sup>3</sup>/mol }} |Section3={{Chembox Structure | CrystalStruct = Orthorhombic<ref name=a1>{{cite journal |journal=RSC Advances |year=2013 |title=Structures and stabilities of alkaline earth metal peroxides XO2 (X = Ca, Be, Mg) studied by a genetic algorithm |first1=X. |last1=Zhao |doi=10.1039/C3RA43617A |last2=Nguyen |first2=M.C. |last3=Wang |first3=C.Z. |last4=Ho |first4=K.M. |volume=3 |issue=44 |page=22135 |bibcode=2013RSCAd...322135Z |url=https://zenodo.org/record/1230026 }}</ref> | SpaceGroup = Pna2<sub>1</sub> | Coordination = 8<ref name=a1/> }} |Section7={{Chembox Hazards | ExternalSDS = | GHSPictograms = {{GHS03}}{{GHS07}} | GHSSignalWord = Warning | HPhrases = {{H-phrases|272|315|319|335}} | PPhrases = {{P-phrases|210|220|221|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|370+378|403+233|405|501}} | LD50 = >5000 mg/kg (oral, rat) <br> >10000 mg/kg (dermal, rat) }} |Section8={{Chembox Related | OtherAnions = [[Calcium oxide]] | OtherCations = [[Strontium peroxide]]<br/>[[Barium peroxide]]<br/>[[Sodium peroxide]] }} }} '''Calcium peroxide''' or '''calcium dioxide''' is the [[inorganic compound]] with the formula CaO<sub>2</sub>. It is the [[peroxide]] (O<sub>2</sub><sup>2−</sup>) salt of Ca<sup>2+</sup>. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in [[water]].<ref name = Ullmann>{{Ullmann | title = Peroxo Compounds, Inorganic | vauthors = Jakob H, Leininger S, Lehmann T, Jacobi S, Gutewort S |display-authors=3| doi = 10.1002/14356007.a19_177.pub2}}</ref>
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