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Copper(II) oxide
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{{Short description|Chemical compound – an oxide of copper with formula CuO}} {{chembox | Verifiedfields = changed | verifiedrevid = 476999309 | ImageFile = copperIIoxide.jpg | ImageSize = | ImageFile1 = Copper(II)-oxide-unit-cell-3D-balls.png | ImageSize1 = | ImageFile2 = Copper(II)-oxide-3D-balls.png | ImageSize2 = | IUPACName = Copper(II) oxide | OtherNames = Cupric oxide | Section1 = {{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 144499 | ChEBI_Ref = {{ebicite|changed|EBI}} | ChEBI = 75955 | ChEMBL_Ref = {{ebicite|changed|EBI}} | ChEMBL = 1909057 | SMILES = [Cu]=O | UNII_Ref = {{fdacite|correct|FDA}} | UNII = V1XJQ704R4 | InChIKey = QPLDLSVMHZLSFG-PHEGLCPBAN | InChI1 = 1/Cu.O/q+2;-2 | InChIKey1 = KKCXRELNMOYFLS-UHFFFAOYAT | SMILES1 = [Cu+2].[O-2] | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Cu.O/q+2;-2 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = KKCXRELNMOYFLS-UHFFFAOYSA-N | CASNo = 1317-38-0 | CASNo_Ref = {{cascite|correct|CAS}} | EC_number = 215-269-1 | PubChem = 14829 | InChI = 1/Cu.O/rCuO/c1-2 | RTECS = GL7900000 }} | Section2 = {{Chembox Properties | Formula = CuO | MolarMass = 79.545 g/mol | Appearance = black to brown powder | Density = 6.315 g/cm<sup>3</sup> | MeltingPtC = 1326 | BoilingPtC = 2000 | Solubility = insoluble | SolubleOther = soluble in [[ammonium chloride]], [[potassium cyanide]] <br> insoluble in [[ethanol|alcohol]], [[ammonium carbonate]] | BandGap = 1.2 [[Electronvolt|eV]] | pKa = | pKb = | RefractIndex = 2.63 | MagSus = +238.9·10<sup>−6</sup> cm<sup>3</sup>/mol }} | Section3 = {{Chembox Structure | CrystalStruct = [[monoclinic]], [[Pearson symbol|mS8]]<ref name= "Hull">The effect of hydrostatic pressure on the ambient temperature structure of CuO, Forsyth J.B., Hull S., J. Phys.: Condens. Matter 3 (1991) 5257–5261, {{doi|10.1088/0953-8984/3/28/001}}. [[Crystallographic point group]]: 2/m or ''C<sub>2h</sub>''. [[Space group]]: C2/c. Lattice parameters: ''a'' = 4.6837(5), ''b'' = 3.4226(5), ''c'' = 5.1288(6), ''α'' = 90°, ''β'' = 99.54(1)°, ''γ'' = 90°.</ref> | SpaceGroup = C2/c, #15 | LattConst_a = 4.6837 | LattConst_b = 3.4226 | LattConst_c = 5.1288 | LattConst_beta = 99.54 | Coordination = }} | Section4 = {{Chembox Thermochemistry | DeltaHf = −156 kJ·mol<sup>−1</sup> | Entropy = 43 J·mol<sup>−1</sup>·K<sup>−1</sup> }} | Section7 = {{Chembox Hazards | ExternalSDS = [https://fscimage.fishersci.com/msds/05655.htm Fisher Scientific] | GHSPictograms = {{GHS07}}{{GHS09}} | GHSSignalWord = Warning | HPhrases = {{H-phrases|302|410|412}} | PPhrases = {{P-phrases|P264|P270|P273|P301+P317|P330|P391|P501}} | MainHazards = | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 1 | NFPA-S = | FlashPt = Non-flammable | PEL = TWA 1 mg/m<sup>3</sup> (as Cu)<ref name=PGCH>{{PGCH|0150}}</ref> | REL = TWA 1 mg/m<sup>3</sup> (as Cu)<ref name=PGCH/> | IDLH = TWA 100 mg/m<sup>3</sup> (as Cu)<ref name=PGCH/> }} | Section8 = {{Chembox Related | OtherAnions = [[Copper(II) sulfide]] | OtherCations = [[Nickel(II) oxide]]<br/>[[Zinc oxide]] | OtherFunction = | OtherFunction_label = | OtherCompounds = [[Copper(I) oxide]] }} }} '''Copper(II) oxide''' or '''cupric oxide''' is an [[inorganic compound]] with the formula CuO. A black solid, it is one of the two stable [[oxide]]s of [[copper]], the other being Cu<sub>2</sub>O or [[copper(I) oxide]] (cuprous oxide). As a [[mineral]], it is known as [[tenorite]], or sometimes black copper. It is a product of [[Copper extraction|copper mining]] and the precursor to many other copper-containing products and chemical compounds.<ref name=Ullmann>{{Ullmann|first1=H. Wayne|last1=Richardson |title=Copper Compounds|year=2002|doi=10.1002/14356007.a07_567}}</ref>
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