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Ethyl tert-butyl ether
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{{Short description|Oxygenate gasoline additive in the production of gasoline from crude oil}} {{Use American English|date=March 2021}} {{Use dmy dates|date=March 2021}} {{More citations needed|date=November 2019}} {{DISPLAYTITLE:Ethyl ''tert''-butyl ether}} {{chembox | Watchedfields = changed | verifiedrevid = 413513038 | Name =Ethyl ''tert''-butyl ether | Reference = <ref>''Merck Index'', 11th Edition, '''3732'''.</ref> | ImageFile = Ethyl tert-butyl ether.svg | ImageSize = 250px | ImageFile1 = Ethyl-tert-butyl-ether-3D-balls.png | ImageSize1 = 160px | ImageName1 = Ball-and-stick model | PIN = 2-Ethoxy-2-methylpropane | OtherNames = Ethyl ''tert''-butyl ether<br>Ethyl tertiary butyl ether<br>Ethyl ''tert''-butyl oxide<br>''tert''-Butyl ethyl ether<br>Ethyl ''t''-butyl ether |Section1={{Chembox Identifiers | Abbreviations = ETBE | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 11996 | InChIKey = NUMQCACRALPSHD-UHFFFAOYAB | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C6H14O/c1-5-7-6(2,3)4/h5H2,1-4H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = NUMQCACRALPSHD-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 637-92-3 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = 3R9B16WR19 | EINECS = 211-309-7 | PubChem = 12512 | SMILES = O(C(C)(C)C)CC | InChI = 1/C6H14O/c1-5-7-6(2,3)4/h5H2,1-4H3 | RTECS =KN4730200 | MeSHName = | ChEBI = 141564 | KEGG_Ref = {{keggcite|correct|kegg}} | KEGG = }} |Section2={{Chembox Properties | C=6 | H=14 | O=1 | MolarMass =102.18 | Appearance =Clear colorless liquid | Density = 0.7364 g/cm<sup>3</sup> | MeltingPtC = -94 | MeltingPt_notes = | BoilingPtC = 69 to 71 | BoilingPt_notes = | Solubility = 1.2 g/100 g | SolubleOther = | Solvent = | pKa = | pKb = }} |Section7={{Chembox Hazards | MainHazards = | NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = | GHSPictograms = {{GHS02}}{{GHS07}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|224|225|315|319|335|336}} | PPhrases = {{P-phrases|210|233|240|241|242|243|261|264|271|280|302+352|303+361+353|304+340|305+351+338|312|321|332+313|337+313|362|370+378|403+233|403+235|405|501}} | FlashPtC = -19 | AutoignitionPtC = | ExploLimits = | PEL = }} }} '''Ethyl ''tertiary''-butyl ether''' ('''ETBE'''), also known as '''ethyl ''tert''-butyl ether''', is commonly used as an [[oxygenate]] [[gasoline additive]] in the production of [[gasoline]] from [[crude oil]]. ETBE offers equal or greater air quality benefits than [[ethanol]], while being technically and logistically less challenging. Unlike ethanol, ETBE does not induce evaporation of gasoline, which is one of the causes of [[smog]], and does not [[hygroscopic|absorb moisture]] from the atmosphere.
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