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Goethite
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{{Short description|Iron(III) oxide-hydroxide named in honor to the poet Goethe}} {{Infobox mineral | name = Goethite | category = [[oxide minerals]] hydroxide subgroup | image = Goethite-169735.jpg | caption = | formula = α-[[Iron|Fe]][[Oxygen|O]]([[Hydroxide|OH]]) | IMAsymbol = Gth<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = | strunz = 4.FD.10 | system = [[Orthorhombic]] | class = Dipyramidal (mmm) <br/>[[H–M symbol]]: (2/m 2/m 2/m) | symmetry = ''Pbnm'' | color = Yellowish to reddish to dark brown or black | habit = radial acicular, mammillary, botryoidal, stalactitic, massive, as encrustation, as pseudomorph; may be banded or iridescent | twinning = | cleavage = Perfect {010} | fracture = Uneven to splintery | mohs = 5.0–5.5 | luster = Adamantine to dull | refractive = Opaque to sub-translucent | opticalprop = | birefringence = | pleochroism = | streak = Brown, brownish yellow to orange yellow | gravity = 3.3–4.3 | density = | melt = | fusibility = Fusible at 5–5.5 | diagnostic = | solubility = HCl soluble | diaphaneity = | other = weakly magnetic | references = <ref name=HurlbutKlein1985>{{cite book |last1=Hurlbut |first1=Cornelius S. |last2=Klein |first2=Cornelis |year=1985 |title=Manual of Mineralogy |edition=20th |publisher=Wiley |isbn=0-471-80580-7 |url-access=registration |url=https://archive.org/details/manualofmineralo00klei }}</ref><ref name=Barthelmy2012>{{cite web |last1=Barthelmy |first1=David |title=Goethite Mineral Data |url=http://webmineral.com/data/Goethite.shtml |website=Mineralogy Database |access-date=8 April 2022 |date=2012}}</ref><ref name=Mindat>{{mindat|title=Goethite|id=1719}}</ref><ref name=HOM>{{cite web |last1=Anthony |first1=John W. |last2=Bideaux |first2=Richard A. |last3=Bladh |first3=Kenneth W. |last4=Nichols |first4=Monte C. |title=Goethite |url=http://www.handbookofmineralogy.org/pdfs/goethite.pdf |archive-url=https://ghostarchive.org/archive/20221009/http://www.handbookofmineralogy.org/pdfs/goethite.pdf |archive-date=2022-10-09 |url-status=live |website=Handbook of Mineralogy |publisher=Mineral Data Publishing |access-date=14 March 2022 |date=2005}}</ref> }} [[File:Goethite-182557.jpg|thumb|upright|Unusual specimen of goethite replacing a [[gypsum]] [[stalactite]]; the center is hollow. From [[Santa Eulalia, Chihuahua]], Mexico.]] '''Goethite''' ({{IPAc-en|ˈ|ɡ|ɜːr|t|aɪ|t}},<ref>{{Cite dictionary |url=http://www.lexico.com/definition/goethite |archive-url=https://web.archive.org/web/20210805045033/https://www.lexico.com/definition/goethite |url-status=dead |archive-date=August 5, 2021 |title=goethite |dictionary=[[Lexico]] UK English Dictionary |publisher=[[Oxford University Press]]}}</ref><ref>{{cite Merriam-Webster|goethite}}</ref> {{IPAc-en|usalso|ˈ|ɡ|oʊ|θ|aɪ|t}}<ref>{{cite Dictionary.com|goethite}}</ref><ref>{{cite American Heritage Dictionary|goethite}}</ref>) is a mineral of the [[diaspore]] group, consisting of [[iron(III) oxide-hydroxide]], specifically the α-[[Polymorphism (materials science)|polymorph]]. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a [[pigment]] (brown [[ochre]]). Evidence has been found of its use in paint pigment samples taken from the [[Lascaux|caves of Lascaux]] in [[France]]. It was first described in 1806 based on samples found in the Hollertszug Mine in [[Herdorf]], [[Germany]].<ref name=Mindat/> The mineral was named after the [[Germany|German]] [[polymath]] and poet [[Johann Wolfgang von Goethe]] (1749–1832).
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