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Lithium hydroxide
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{{chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 450704627 | ImageFile = Lithiumhydroxide t.png | ImageSize = 150px | ImageFile1 = Lithium-hydroxide-xtal-3D-SF.png | ImageSize1 = | ImageName1 = Lithium hydroxide | ImageFile2 = File:Kristallstruktur Lithiumhydroxid.png | ImageSize2 = | ImageCaption2 = {{colorbox|#C0C0C0}}{{nbsp}}{{chem2|[[Lithium|Li]]+}} {{colorbox|#EE0000}}{{nbsp}}{{chem2|[[Oxygen|O]](2−)}} {{colorbox|#FFFFFF}}{{nbsp}}{{chem2|[[Hydrogen|H]]+}} | ImageFile3 = Lithium hydroxide.jpg | ImageSize3 = | ImageName3 = Lithium-hydroxide.jpg | IUPACName = Lithium hydroxide |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 3802 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = 903YL31JAS | UNII1_Ref = {{fdacite|correct|FDA}} | UNII1 = G51XLP968G | UNII1_Comment = (monohydrate) | InChI = 1/Li.H2O/h;1H2/q+1;/p-1 | InChIKey = WMFOQBRAJBCJND-REWHXWO | ChEBI = 33979 | SMILES = [Li+].[OH-] | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Li.H2O/h;1H2/q+1;/p-1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = WMFOQBRAJBCJND-UHFFFAOYSA-M | CASNo = 1310-65-2 | CASNo_Ref = {{cascite|correct|CAS}} | CASNo2 = 1310-66-3 | CASNo2_Ref = {{cascite|correct|CAS}} | CASNo2_Comment = (monohydrate) | PubChem = 3939 | RTECS = OJ6307070 | UNNumber = 2680 | Gmelin = 68415 }} |Section2={{Chembox Properties | Odor = none | Formula = LiOH | MolarMass = {{ubl|23.95 g/mol (anhydrous)|41.96 g/mol (monohydrate)}} | Appearance = white solid | Density = {{ubl|1.46 g/cm<sup>3</sup> (anhydrous)|1.51 g/cm<sup>3</sup> (monohydrate)}} | MeltingPtC = 462 | BoilingPtC = 924 | BoilingPt_notes = (decomposes) | Solubility = {{ubl|anhydrous:|12.7 g/(100 mL) (0 °C)|12.8 g/(100 mL) (20 °C)|17.5 g/(100 mL) (100 °C)|<hr/>|monohydrate:|22.3 g/(100 mL) (10 °C)|26.8 g/(100 mL) (80 °C)<ref>{{RubberBible87th}}</ref>}} | Solvent1 = methanol | Solubility1 = {{ubl|9.76 g/(100 g) (anhydrous; 20 °C, 48 hours mixing)|13.69 g/(100 g) (monohydrate; 20 °C, 48 hours mixing)<ref name=Khosravi>{{cite book|last1=Khosravi|first1=Javad|name-list-style = vanc|year=2007|at=Chapter 9: Results|title=Production of Lithium Peroxide and Lithium Oxide in an Alcohol Medium|isbn=978-0-494-38597-5}}</ref>}} | Solvent2 = ethanol | Solubility2 = {{ubl|2.36 g/(100 g) (anhydrous; 20 °C, 48 hours mixing)|2.18 g/(100 g) (monohydrate; 20 °C, 48 hours mixing)<ref name="Khosravi"/>}} | Solvent3 = isopropanol | Solubility3 = {{ubl|0 g/(100 g) (anhydrous; 20 °C, 48 hours mixing)|0.11 g/(100 g) (monohydrate; 20 °C, 48 hours mixing)<ref name="Khosravi"/>}} | RefractIndex = {{ubl|1.464 (anhydrous)|1.460 (monohydrate)}} | pKa = 14.4<ref>{{cite journal|vauthors = Popov K, Lajunen LH, Popov A, Rönkkömäki H, Hannu-Kuure H, Vendilo A|year=2002|title=<sup>7</sup>Li, <sup>23</sup>Na, <sup>39</sup>K and <sup>133</sup>Cs NMR comparative equilibrium study of alkali metal cation hydroxide complexes in aqueous solutions. First numerical value for CsOH formation|url=https://www.infona.pl/resource/bwmeta1.element.elsevier-40fb73c1-ba37-32e0-914e-b264c7c0539b|journal=Inorganic Chemistry Communications|volume=5|issue=3|pages=223–225|doi=10.1016/S1387-7003(02)00335-0|access-date=2017-01-21|df=dmy-all|url-access=subscription}}</ref> | ConjugateBase = [[Lithium monoxide anion]] | MagSus = −12.3·10<sup>−6</sup> cm<sup>3</sup>/mol | Dipole = 4.754 [[Debye|D]]<ref>{{Cite book |url=https://www.worldcat.org/oclc/930681942 |title=CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data. |date=2016 |others=William M. Haynes, David R. Lide, Thomas J. Bruno |isbn=978-1-4987-5428-6 |edition=2016-2017, 97th |location=Boca Raton, Florida |oclc=930681942}}</ref> }} |Section4 = {{Chembox Thermochemistry | Thermochemistry_ref = <ref>{{Cite book|url=https://www.worldcat.org/oclc/930681942|title=CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data.|date=2016|others=William M. Haynes, David R. Lide, Thomas J. Bruno|isbn=978-1-4987-5428-6|edition=2016-2017, 97th|location=Boca Raton, Florida|oclc=930681942}}</ref> | HeatCapacity = 49.6 J/(mol·K) | Entropy = 42.8 J/(mol·K) | DeltaHform = −487.5 kJ/mol | DeltaGfree = −441.5 kJ/mol | DeltaHcombust = | DeltaHfus = 20.9 kJ/mol (at melting point) }} |Section5 = {{Chembox Hazards | ExternalSDS = {{cite web|url=http://www.inchem.org/documents/icsc/icsc/eics0913.htm|title=ICSC 0913}}<br/>{{cite web|url = http://www.inchem.org/documents/icsc/icsc/eics0914.htm|title=ICSC 0914}} (monohydrate) | MainHazards = Corrosive | NFPA-H = 3 | NFPA-F = 0 | NFPA-R = 0 | NFPA-S = | FlashPt = Non-flammable | LD50 = 210 mg/kg (oral, rat)<ref>{{cite web|url=https://chem.nlm.nih.gov/chemidplus/rn/1310-65-2|title=ChemIDplus – 1310-65-2 – WMFOQBRAJBCJND-UHFFFAOYSA-M – Lithium hydroxide anhydrous – Similar structures search, synonyms, formulas, resource links, and other chemical information|first=Michael|last=Chambers|name-list-style = vanc|website=chem.sis.nlm.nih.gov|access-date=12 April 2018}}</ref> }} |Section8 = {{Chembox Related | OtherAnions = [[Lithium amide]] | OtherCations = {{ubl|[[Sodium hydroxide]]|[[Potassium hydroxide]]|[[Rubidium hydroxide]]|[[Caesium hydroxide]]}} | OtherCompounds = [[Lithium oxide]] }} }} '''Lithium hydroxide''' is an [[inorganic compound]] with the [[chemical formula|formula]] LiOH. It can exist as anhydrous or hydrated, and both forms are white [[hygroscopic]] solids. They are soluble in water and slightly soluble in [[ethanol]]. Both are available commercially. While classified as a [[strong base]], lithium hydroxide is the weakest known alkali metal hydroxide.
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