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Nitrogen trichloride
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{{Short description|Chemical compound}} {{chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 477001603 | ImageFile1 = NCl3 dimensions.svg | ImageName1 = Structural formula of nitrogen trichloride | ImageFile2 = Nitrogen-trichloride-3D-vdW.png | ImageName2 = Space-filling model of nitrogen trichloride | ImageCaption2 = {{legend|blue|[[Nitrogen]], N}}{{legend|lime|[[Chlorine]], Cl}} | ImageFile3 = Nitrogen trichloride.JPG | ImageSize3 = | ImageName3 = Nitrogen trichloride | OtherNames = Trichloramine<br />Agene<br />Nitrogen(III) chloride<br />Trichloroazane<br />Trichlorine nitride |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 55361 | InChI = 1/Cl3N/c1-4(2)3 | InChIKey = QEHKBHWEUPXBCW-UHFFFAOYAZ | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 37382 | SMILES = ClN(Cl)Cl | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Cl3N/c1-4(2)3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = QEHKBHWEUPXBCW-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 10025-85-1 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = VA681HRW8W | PubChem = 61437 | RTECS = QW974000 | EINECS = 233-045-1 | Gmelin = 1840 }} |Section2={{Chembox Properties | Formula = {{chem2|NCl3}} | N=1|Cl=3 | Appearance = yellow oily liquid | Odor = [[chlorine]]-like | Density = 1.653 g/mL | Solubility = immiscible<br> slowly decomposes | SolubleOther = soluble in [[benzene]], [[chloroform]], [[carbon tetrachloride|{{chem2|CCl4}}]], [[carbon disulfide|{{chem2|CS2}}]], [[phosphorus trichloride|{{chem2|PCl3}}]] | MeltingPtC = β40 | BoilingPtC = 71 | Viscosity = }} |Section3={{Chembox Structure | MolShape = trigonal pyramidal | CrystalStruct = [[orthorhombic]] (below β40 Β°C) | Dipole = 0.6 [[Debye|D]] }} |Section4={{Chembox Thermochemistry | DeltaHf = 232 kJ/mol }} |Section7={{Chembox Hazards | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 3 | NFPA-S = Ox | AutoignitionPtC = 93 | AutoignitionPt_notes = }} |Section8={{Chembox Related | OtherAnions = [[Nitrogen trifluoride]]<br />[[Nitrogen tribromide]]<br />[[Nitrogen triiodide]] | OtherCations = [[Phosphorus trichloride]]<br />[[Arsenic trichloride]] | OtherFunction_label = [[chloramines]] | OtherFunction = [[Monochloramine]]<br />[[Dichloramine]] | OtherCompounds = [[Nitrosyl chloride]]}} }} '''Nitrogen trichloride''', also known as '''trichloramine''', is the [[chemical compound]] with the [[chemical formula|formula]] {{chem2|NCl3}}. This yellow, oily, and explosive liquid is most commonly encountered as a product of [[chemical reaction]]s between [[ammonia]]-derivatives and [[chlorine]] (for example, in [[swimming pool]]s). Alongside [[monochloramine]] and [[dichloramine]], trichloramine is responsible for the distinctive 'chlorine smell' associated with swimming pools, where the compound is readily formed as a product from [[hypochlorous acid]] reacting with [[ammonia]] and other nitrogenous substances in the water, such as [[urea]] from [[urine]].<ref>{{cite web |date=July 2006 |title=Chloramines: Understanding "Pool Smell" |url=https://chlorine.americanchemistry.com/Science-Center/Chlorine-Compound-of-the-Month-Library/Chloramines-Understanding-Pool-Smell/ |website=[[American Chemistry Council]] |url-status=dead |archive-url=https://web.archive.org/web/20191217170314/https://chlorine.americanchemistry.com/Science-Center/Chlorine-Compound-of-the-Month-Library/Chloramines-Understanding-Pool-Smell/ |archive-date=17 December 2019 |access-date=17 December 2019}}</ref>
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