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Orpiment
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{{Short description|Orange-yellow arsenic sulfide mineral}} {{infobox mineral | name = Orpiment | category = [[Sulfide mineral]] | boxwidth = | boxbgcolor = | image = Orpiment-148270.jpg | imagesize = | alt = | caption = Orpiment crystal from Twin Creeks Mine, Potosi District, [[Humboldt County, Nevada]], United States (Size: 3.3 cm × 2.1 cm × 2.1 cm) | formula = As<sub>2</sub>S<sub>3</sub> | IMAsymbol = Orp<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3 |pages=291–320|doi=10.1180/mgm.2021.43 |bibcode=2021MinM...85..291W |s2cid=235729616 |doi-access=free}}</ref> | molweight = | strunz = 2.FA.30 | dana = | system = [[Monoclinic]] | class = Prismatic (2/m) <br /><small>(same [[H-M symbol]])</small> | symmetry = ''P''2<sub>1</sub>/n | unit cell = a = 11.475(5), b = 9.577(4) <br />c = 4.256(2) [Å], β = 90.45(5)°; Z = 4 | color = Lemon-yellow to golden or brownish yellow | colour = | habit = Commonly in foliated columnar or fibrous aggregates; may be reniform or botryoidal; also granular or powdery; rarely as prismatic crystals | twinning = On {100} | cleavage = Perfect on {010}, imperfect on {100}; | fracture = | tenacity = [[Sectility|Sectile]] | mohs = 1.5–2 | luster = Resinous, pearly on cleavage surface | streak = Pale lemon-yellow | diaphaneity = Transparent | gravity = 3.49 | density = | polish = | opticalprop = Biaxial (−) | refractive = n<sub>α</sub> = 2.400 n<sub>β</sub> = 2.810 n<sub>γ</sub> = 3.020 | birefringence = δ = 0.620 | pleochroism = In reflected light, strong, white to pale gray with reddish tint; in transmitted light, Y = yellow, Z = greenish yellow | 2V = Measured: 30° to 76°, Calculated: 62° | dispersion = r > v, strong | extinction = | length fast/slow = | fluorescence= | absorption = | melt = | fusibility = | diagnostic = | solubility = | other = | alteration = | references =<ref name=Handbook>{{cite web |last1=Anthony |first1=John W. |last2=Bideaux |first2=Richard A. |last3=Bladh |first3=Kenneth W. |last4=Nichols |first4=Monte C. |title=Orpiment |url=http://www.handbookofmineralogy.org/pdfs/orpiment.pdf |website=Handbook of Mineralogy |publisher=Mineral Data Publishing |access-date=14 March 2022 |date=2005}}</ref><ref name=Mindat>{{mindat|id=3021|title=Orpiment|accessdate=26 May 2022}}</ref><ref name=Webmin>{{WebMineral|url=http://webmineral.com/data/Orpiment.shtml|name=Orpiment|accessdate=26 May 2022}}</ref> }} '''Orpiment''', also known as ″'''yellow [[arsenic blende]]'''″ is a deep-colored, orange-yellow [[arsenic]] [[sulfide mineral]] with formula {{chem|As|2|S|3}}. It is found in volcanic [[fumarole]]s, low-temperature [[hydrothermal]] veins, and [[hot spring]]s and may be formed through [[sublimation (phase transition)|sublimation]]. Orpiment takes its name from the Latin ''auripigmentum'' (''aurum'', "gold" + ''pigmentum'', "[[pigment]]"), due to its deep-yellow color. Orpiment once was widely used in artworks, medicine, and other applications. Because of its toxicity and instability, its usage has declined.
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