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Potassium oxide
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{{chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 448711409 | ImageFile = Potassium-oxide-powder.png | ImageFile1 = Potassium-oxide-3D-vdW.png | ImageName = Potassium Oxide spacefilling model | IUPACName = potassium oxide | SystematicName = potassium oxidopotassium | OtherNames = [[potash]], dipotassium oxide |Section1={{Chembox Identifiers | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 12136-45-7 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 23354117 | ChemSpiderID_Comment = | ChEBI = 88321 | EC_number = 235-227-6 | PubChem = 25520 | UNNumber = 2033 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = 58D606078H | MeSHName = Potassium+oxide | SMILES = O([K])[K] | StdInChI_Ref = {{stdinchicite|changed|chemspider}} | StdInChI = 1S/2K.O | StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} | StdInChIKey = NOTVAPJNGZMVSD-UHFFFAOYSA-N }} |Section2={{Chembox Properties | K=2 | O=1 | Appearance = Pale yellow solid | Odor = Odorless | Density = 2.32 g/cm<sup>3</sup> (20 °C)<ref name=chemister>{{cite web|last = Anatolievich|first = Kiper Ruslan|website=chemister.ru|url = http://chemister.ru/Database/properties-en.php?dbid=1&id=516|title = potassium oxide|access-date = 2014-07-04}}</ref><br> 2.13 g/cm<sup>3</sup> (24 °C)<ref name=crc /> | Solubility = Reacts<ref name=chemister /> forming [[Potassium hydroxide|KOH]] | SolubleOther = Soluble in [[diethyl ether]]<ref name=crc /> | MeltingPtC = 740 | MeltingPt_ref = <ref name=crc>{{CRC90}}</ref> }} |Section3={{Chembox Structure | CrystalStruct = [[Antifluorite]] [[cubic crystal system|cubic]], [[pearson symbol|cF12]]<ref name=socacs>{{cite book|page = 25|title = The Structure of Crystals|edition = 2nd|year = 1935|last = Wyckoff|first = Ralph W.G.|publisher = Reinhold Publishing Corp.|work = American Chemical Society}}</ref> | SpaceGroup = Fm{{overline|3}}m, No. 225<ref name=socacs /> | Coordination = Tetrahedral (K<sup>+</sup>)<br> Cubic (O<sup>2−</sup>) | LattConst_a = 6.436 Å<ref name=socacs /> | LattConst_alpha = 90 }} |Section4={{Chembox Thermochemistry | DeltaHf = −363.17 kJ/mol<ref name=chemister /><ref name=nist>{{nist|name=Dipotassium oxide|id=12136457|accessdate=2014-07-04|mask=FFFF|units=SI}}</ref> | Entropy = 94.03 J/mol·K<ref name=nist /> | HeatCapacity = 83.62 J/mol·K<ref name=nist /> | DeltaGf = −322.1 kJ/mol<ref name=chemister /> }} |Section7={{Chembox Hazards | ExternalSDS = [http://www.inchem.org/documents/icsc/icsc/eics0769.htm ICSC 0769] | MainHazards = Corrosive, reacts violently with water | NFPA-H = 3 | NFPA-F = 0 | NFPA-R = 1 | NFPA-S = W | GHSPictograms = {{GHS05}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|314}} | PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}} }} |Section8={{Chembox Related | OtherAnions = [[Potassium sulfide]]<br>[[Potassium selenide]]<br>[[Potassium telluride]]<br>[[Potassium polonide]] | OtherCations = [[Lithium oxide]]<br> [[Sodium oxide]]<br> [[Rubidium oxide]]<br> [[Caesium oxide]] | OtherFunction = [[Potassium peroxide]]<br> [[Potassium superoxide]]<br>[[Potassium ozonide]] | OtherFunction_label = [[potassium]] [[oxide]]s | OtherCompounds = [[Potassium hydroxide]] }} }} '''Potassium oxide''' ([[Potassium|K{{sub|2}}]][[Oxide|O]]) is an ionic [[Chemical compound|compound]] of [[potassium]] and [[oxygen]]. It is a [[Base (chemistry)|base]]. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertilizers and cements, are assayed assuming the percent composition that would be equivalent to K<sub>2</sub>O.
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