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Propyne
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{{Short description|Hydrocarbon compound (HC≡C–CH3)}} {{distinguish|propane|propene}} {{chembox | Verifiedfields = changed | verifiedrevid = 406858995 | Name = Propyne | ImageFile = PROPYNE.png | ImageSize = 120px | ImageName = Methylacetylene | ImageFile1 = Propyne-3D-vdW.png | ImageSize1 = 180px | PIN = Propyne<ref name=iupac2013>{{cite book | title = Nomenclature of Organic Chemistry. IUPAC Recommendations and Preferred Names 2013 (Blue Book) | chapter = Characteristic (Functional) and Substituent Groups | publisher = [[Royal Society of Chemistry|The Royal Society of Chemistry]] | date = 2014 | location = Cambridge | page = 374 | doi = 10.1039/9781849733069-00372 | isbn = 978-0-85404-182-4}}</ref><ref group="note">"Prop-1-yne" mistake fixed in the [https://www.qmul.ac.uk/sbcs/iupac/bibliog/BBerrors.html errata] {{Webarchive|url=https://web.archive.org/web/20190801093648/https://www.qmul.ac.uk/sbcs/iupac/bibliog/BBerrors.html |date=2019-08-01 }}. The locant is omitted according to P-14.3.4.2 (d), p. 31 for propene and P-31.1.1.1, Examples, p. 374 for propyne.</ref> | SystematicName = | OtherNames = Methylacetylene<br />Methyl acetylene<br />Allylyne | IUPACName = | Section1 = {{Chembox Identifiers | CASNo = 74-99-7 | CASNo_Ref = {{cascite|correct|CAS}} | UNII_Ref = {{fdacite|correct|FDA}} | UNII = 086L40ET1B | ChEMBL_Ref = {{ebicite|changed|EBI}} | ChEMBL = 116902 | SMILES = CC#C | EINECS = 200-828-4 | PubChem = 6335 | ChemSpiderID = 6095 | InChI = 1/C3H4/c1-3-2/h1H,2H3 | InChIKey = MWWATHDPGQKSAR-UHFFFAOYAI | StdInChI = 1S/C3H4/c1-3-2/h1H,2H3 | StdInChIKey = MWWATHDPGQKSAR-UHFFFAOYSA-N | RTECS = | MeSHName = C022030 | ChEBI = 48086 | ChEBI_Ref = {{ebicite|correct|ebi}} | Beilstein = 878138 }} | Section2 = {{Chembox Properties | Formula = {{chem2|CH3C\tCH}} | MolarMass = 40.0639 g/mol | Density = 0.53 g/cm<sup>3</sup> | MeltingPtC = -102.7 | BoilingPtC = -23.2 | Appearance = Colorless gas<ref name=NIOSH/> | Odor = Sweet<ref name=NIOSH/> | VaporPressure = 5.2 [[Standard atmosphere (unit)|atm]] (20°C)<ref name=NIOSH/> }} | Section3 = {{Chembox Hazards | PEL = TWA 1000 ppm (1650 mg/m<sup>3</sup>)<ref name=NIOSH>{{PGCH|0392}}</ref> | ExploLimits = 1.7%-?<ref name=NIOSH/> | IDLH = 1700 ppm<ref name=NIOSH/> | REL = TWA 1000 ppm (1650 mg/m<sup>3</sup>)<ref name=NIOSH/> }} | Section4 = | Section5 = | Section6 = }} '''Propyne''' ('''methylacetylene''') is an [[alkyne]] with the [[chemical formula]] {{chem2|CH3C\tCH}}. It is a component of [[MAPP gas|MAPD gas]]—along with its [[isomer]] [[propadiene]] (allene), which was commonly used in [[gas welding]]. Unlike [[acetylene]], propyne can be safely [[Condensation|condensed]].<ref name=Ullmann>Peter Pässler, Werner Hefner, Klaus Buckl, Helmut Meinass, Andreas Meiswinkel, Hans-Jürgen Wernicke, Günter Ebersberg, Richard Müller, Jürgen Bässler, Hartmut Behringer, Dieter Mayer, "Acetylene" in Ullmann's Encyclopedia of Industrial Chemistry Wiley-VCH, Weinheim 2007 ({{doi|10.1002/14356007.a01_097.pub2}}).</ref>
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