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Second quantization
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{{Use American English|date = February 2019}} {{Short description|Formulation of the quantum many-body problem}} {{Quantum field theory}} '''Second quantization''', also referred to as '''occupation number representation''', is a formalism used to describe and analyze [[Quantum mechanics|quantum]] [[n-body problem|many-body]] systems. In [[quantum field theory]], it is known as [[canonical quantization]], in which the fields (typically as the [[Wave function|wave functions]] of matter) are thought of as [[field operator]]s, in a manner similar to how the physical quantities (position, momentum, etc.) are thought of as operators in [[first quantization]]. The key ideas of this method were introduced in 1927 by [[Paul Dirac]],<ref name="Dirac1927">{{cite journal | last = Dirac | first = Paul Adrien Maurice | title = The quantum theory of the emission and absorption of radiation | journal = Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character | volume = 114 | number = 767 | pages = 243–265 | doi = 10.1098/rspa.1927.0039 | year = 1927 | bibcode = 1927RSPSA.114..243D | doi-access = free }}</ref> and were later developed, most notably, by [[Pascual Jordan]]<ref name="Jordan1928">{{cite journal | last1 = Jordan | first1 = Pascual | last2 = Wigner | first2 = Eugene | title = Über das Paulische Äquivalenzverbot | journal = Zeitschrift für Physik | volume = 47 | number = 9 | pages = 631–651 | doi = 10.1007/bf01331938 | year = 1928 | bibcode = 1928ZPhy...47..631J | s2cid = 126400679 | language = de }}</ref> and [[Vladimir Fock]].<ref name="Fock1932">{{cite journal | last = Fock | first = Vladimir Aleksandrovich | title = Konfigurationsraum und zweite Quantelung | journal = Zeitschrift für Physik | volume = 75 | number = 9–10 | pages = 622–647 | doi = 10.1007/bf01344458 | s2cid = 186238995 | year = 1932 | bibcode = 1932ZPhy...75..622F | language = de }}</ref><ref name="Reed1975">{{cite book | last1 = Reed | first1 = Michael | author-link1 = Michael C. Reed | last2 = Simon | first2 = Barry | author-link2 = Barry Simon | title = Methods of Modern Mathematical Physics. Volume II: Fourier Analysis, Self-Adjointness | publisher = Academic Press | location = San Diego | year = 1975 | pages = 328 | isbn = 9780080925370 }}</ref> In this approach, the quantum many-body states are represented in the [[Fock state]] basis, which are constructed by filling up each single-particle state with a certain number of identical particles.<ref name="Becchi2010">{{cite journal | last = Becchi | first = Carlo Maria | title = Second quantization | journal = Scholarpedia | volume = 5 | number = 6 | pages = 7902 | doi = 10.4249/scholarpedia.7902 | year = 2010 | bibcode = 2010SchpJ...5.7902B | doi-access = free }}</ref> The second quantization formalism introduces the [[creation and annihilation operators]] to construct and handle the Fock states, providing useful tools to the study of the quantum many-body theory.
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