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Strontianite
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{{Short description|Rare carbonate mineral and raw material for the extraction of strontium}} {{Use dmy dates|date=April 2022}} {{Infobox mineral | name = Strontianite | boxwidth = | boxbgcolor = | image = Mineraly.sk - stroncianit.jpg | imagesize = 260px | alt = | caption = Strontianite from [[Slovakia]] | category = [[Carbonate minerals]] | formula = SrCO<sub>3</sub> | IMAsymbol = Str<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = 147.63 g/mol | strunz = 5.AB.15 (10 ed) <br /><small>5/B.04-20 (8 ed)</small> | dana = 14.01.03.03 | system = [[Orthorhombic]] | class = Dipyramidal (mmm) <br />[[H-M symbol]]: (2/m 2/m 2/m) | symmetry = ''Pmcn'' | unit cell = a = 5.1 [[angstrom|Å]], b = 8.4 Å <br />c = 6.0 Å; Z = 4 | color = Colourless, white, gray, light yellow, green or brown; colourless in transmitted light | habit = Prismatic, acicular, pseudo hexagonal, columnar to fibrous, granular, massive | twinning = Very common, usually contact, rarely penetration, also repeated | cleavage = {110} nearly perfect, {021} poor, {010} traces | fracture = Subconchoidal to uneven | tenacity = Brittle | mohs = {{frac|3|1|2}} | lustre = Vitreous, resinous on breaks, greasy | streak = White | diaphaneity = Transparent to translucent | gravity = 3.74 to 3.78 Transparent versions are heavier than the other ones | density = | polish = | opticalprop = Biaxial (−) | refractive = n<sub>α</sub> = 1.52, n<sub>β</sub> = 1.66, n<sub>γ</sub> = 1.67 | birefringence = 0.15 | pleochroism = | 2V = Measured: 7°, Calculated: 12° to 8° | dispersion = | extinction = | length fast/slow = | fluorescence = Almost always fluorescent | absorption = | melt = | fusibility = | diagnostic = | solubility = Soluble in dilute HCl | impurities = | alteration = Celestine SrSO<sub>4</sub> | other = | prop1 = | prop1text = | references = <ref name=Dana>Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley</ref><ref name=Mindat>[http://www.mindat.org/min-3805.html Strontianite on Mindat.org retrieved 23/08/11] </ref><ref name=Webmin>{{cite web|url=http://www.webmineral.com/data/Strontianite.shtml|title=Strontianite Mineral Data|first=Dave|last=Barthelmy|access-date=August 23, 2011}}</ref><ref name=HOM>{{cite web|url=http://rruff.info/doclib/hom/strontianite.pdf|title=Strontianite in the Handbook of Mineralogy |access-date=August 24, 2011}}</ref> }} '''Strontianite''' ([[Strontium|Sr]][[Carbon|C]][[Oxygen|O]]<sub>3</sub>) is an important raw material for the extraction of [[strontium]]. It is a rare [[carbonate mineral]] and one of only a few strontium minerals. It is a member of the aragonite group. Aragonite group members:<ref name=Dana/> [[aragonite]] (CaCO<sub>3</sub>), [[witherite]] (BaCO<sub>3</sub>), strontianite (SrCO<sub>3</sub>), [[cerussite]] (PbCO<sub>3</sub>) The ideal formula of strontianite is SrCO<sub>3</sub>, with [[molar mass]] 147.63 g,<ref name=Webmin/> but [[calcium]] (Ca) can substitute for up to 27% of the strontium (Sr) [[Ion|cations]], and [[barium]] (Ba) up to 3.3%.<ref name=Dana/> The mineral was named in 1791 for the locality, [[Strontian]], Argyllshire, Scotland, where the element [[strontium]] had been discovered the previous year.<ref name=Dana/> Although good mineral specimens of strontianite are rare, strontium is a fairly common [[Chemical element|element]], with abundance in the [[Crust (geology)|Earth's crust]] of 370 parts per million by weight, 87 parts per million by [[Mole (unit)|moles]], much more common than [[copper]] with only 60 parts per million by weight, 19 by moles.<ref name=Chemicool>{{cite web|url=http://www.chemicool.com/elements/strontium.html|title=Strontium|access-date=August 24, 2011}}</ref> Strontium is never found free in nature. The principal strontium ores are [[Celestine (mineral)|celestine]] SrSO<sub>4</sub> and strontianite SrCO<sub>3</sub>. The main commercial process for strontium metal production is [[Redox|reduction]] of [[strontium oxide]] with [[aluminium]].<ref name=Chemicool/>
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