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Barium chloride
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==Preparation== On an industrial scale, barium chloride is prepared via a two step process from [[barite]] ([[barium sulfate]]).<ref>{{Greenwood&Earnshaw2nd}}</ref> The first step requires high temperatures. :{{chem2|BaSO4 + 4 C β BaS + 4 CO}} The second step requires reaction between [[barium sulfide]] and [[hydrogen chloride]]: :{{chem2|BaS + 2 HCl β BaCl2 + H2S}} or between [[barium sulfide]] and [[calcium chloride]]: :{{chem2|BaS + CaCl2 β CaS + BaCl2}}<ref name="sciencedirect"></ref> In place of HCl, [[chlorine]] can be used.<ref name="Ullman2005"/> Barium chloride is extracted out from the mixture with water. From water solutions of barium chloride, its dihydrate ({{chem2|BaCl2*2H2O}}) can be crystallized as colorless crystals.<ref name="sciencedirect"></ref> Barium chloride can in principle be prepared by the reaction between [[barium hydroxide]] or [[barium carbonate]] with [[hydrogen chloride]]. These basic salts react with [[hydrochloric acid]] to give hydrated barium chloride. :{{chem2|Ba(OH)2 + 2 HCl β BaCl2 + 2 H2O}} :{{chem2|BaCO3 + 2 HCl β BaCl2 + H2O + CO2}}
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