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Isoelectronicity
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==Examples== {{multiple image |align = right |total_width = 315 |image1 = L-serine-2D-skeletal.png |caption1 = [[Serine]] |image2 = L-cysteine-2D-skeletal.png |caption2 = [[Cysteine]] |image3 = L-selenocysteine-2D-skeletal.png |caption3 = [[Selenocysteine]] |footer = Three isoelectronic amino acids }} {{multiple image |align = right |image1 = Dimethyl ether Structural Formulae.svg |width1 = 150 |caption1 = Dimethyl ether |image2 = (E)-Azomethane.svg |width2 = 150 |caption2 = Azomethane |footer = Both molecules have the same electron configuration, but due to the double bond and extra atom in azomethane, they are not isoelectronic }} The {{chem|N|link=nitrogen}} atom and the {{chem|O|+|link=oxygen}} ion are isoelectronic because each has five [[valence electron]]s, or more accurately an electronic configuration of [He] 2s<sup>2</sup> 2p<sup>3</sup>. Similarly, the [[cation]]s {{chem|K|+|link=potassium}}, {{chem|Ca|2+|link=calcium}}, and {{chem|Sc|3+|link=scandium}} and the [[anion]]s {{chem|Cl|-|link=chloride}}, {{chem|S|2-|link=sulfide}}, and {{chem|P|3-|link=phosphide}} are all isoelectronic with the {{chem|Ar|link=argon}} atom. {{chem|CO}}, {{chem|CN|-|link=Cyanide}}, {{chem|N|2}}, and {{chem|NO|+}} are isoelectronic because each has two atoms triple bonded together, and due to the charge have analogous electronic configurations ({{chem|N|-}} is identical in electronic configuration to {{chem|O}} so {{chem|CO}} is identical electronically to {{chem|CN|-}}). [[Molecular orbital diagram]]s best illustrate isoelectronicity in diatomic molecules, showing how [[atomic orbital]] mixing in isoelectronic species results in identical orbital combination, and thus also bonding. More complex molecules can be polyatomic also. For example, the [[amino acid]]s [[serine]], [[cysteine]], and [[selenocysteine]] are all isoelectronic to each other. They differ by which specific [[chalcogen]] is present at one location in the side-chain. {{chem|CH|3|COCH|3}} ([[acetone]]) and {{chem|CH|3|N|2|CH|3}} ([[azomethane]]) are not isoelectronic. They do have the same number of electrons but they do not have the same structure.
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