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Lead styphnate
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==Preparation== Lead styphnate (or, as it was then called, trinitro-orcinate) was discovered along with many other thrinitroresorcinate salts by British chemist [[John Stenhouse]] in 1871, the synthesis route involving action of trinitroresorcinol on [[lead acetate]].<ref>{{Cite book |last=Matyáš |first=Robert |url=https://books.google.com/books?id=wfJHAAAAQBAJ&pg=PA138 |title=Primary Explosives |last2=Pachman |first2=Jiří |date=2013-03-12 |publisher=Springer Science & Business Media |isbn=978-3-642-28436-6 |language=en}}</ref><ref>{{Cite book |last=Stenhouse |first=J. |url=http://archive.org/details/philtrans04851702 |title=Contributions to the History of Orcin.--No. I. Nitro-Substitution Compounds of the Orcins |date=March 1871 |publisher=Royal Society of London}}</ref> In 1919, Austrian chemist Edmund von Herz first established a preparation of anhydrous normal lead styphnate by the reaction of magnesium styphnate with lead acetate in the presence of [[nitric acid]].<ref>{{cite journal|author=J.R. Payne|title=Thermochmistry of lead styphnate|journal=Thermochimica Acta |year=1994|doi=10.1016/0040-6031(94)85003-8|volume=242|pages=13–21}}</ref><ref name=":0">{{citation | last1=Boileau | first1=Jacques | last2=Fauquignon | first2=Claude | last3=Hueber | first3=Bernard | last4=Meyer | first4=Hans H. | title=Ullmann's Encyclopedia of Industrial Chemistry | chapter=Explosives | publisher=Wiley-VCH Verlag GmbH & Co. KGaA | publication-place=Weinheim, Germany | date=2009-04-15 | doi=10.1002/14356007.a10_143.pub2| isbn=978-3527306732 }}</ref> :{C<sub>6</sub>N<sub>3</sub>O<sub>8</sub>}MgH<sub>2</sub>O + Pb(CH<sub>3</sub>CO<sub>2</sub>)<sub>2</sub> → {C<sub>6</sub>N<sub>3</sub>O<sub>8</sub>}PbH<sub>2</sub>O + Mg(CH<sub>3</sub>CO<sub>2</sub>)<sub>2</sub>
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