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Particle in a ring
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== Wave function == [[Image:Quantum-rigid-rotator 1+2-animation-color.gif|thumb|Animated wave function of a “coherent” state consisting of eigenstates n=1 and n=2.]] Using [[polar coordinates]] on the 1-dimensional ring of radius R, the [[wave function]] depends only on the [[angle|angular]] [[coordinate]], and so<ref>{{cite book |last=Cox |first=Heater |title=Problems and Solutions to accompany Physical Chemistry: a Molecular Approach |publisher=University Science Books |page=141 |isbn=978-0935702439}}</ref> :<math> \nabla^2 = \frac{1}{R^2} \frac{\partial^2}{\partial \theta^2} </math> Requiring that the wave function be [[periodic function|periodic]] in <math> \ \theta </math> with a period <math> 2 \pi</math> (from the demand that the wave functions be single-valued [[function (mathematics)|function]]s on the [[circle]]), and that they be [[normalizing constant|normalized]] leads to the conditions :<math> \int_{0}^{2 \pi} \left| \psi ( \theta ) \right|^2 \, d\theta = 1\ </math>, and :<math> \ \psi (\theta) = \ \psi ( \theta + 2\pi)</math> Under these conditions, the solution to the Schrödinger equation is given by :<math> \psi_{\pm}(\theta) = \frac{1}{\sqrt{2 \pi }}\, e^{\pm i \frac{R}{\hbar} \sqrt{2 m E} \, \theta } </math>
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