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Quantum electrodynamics
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==History== {{Main|History of quantum mechanics|History of quantum field theory}} [[File:Dirac 3.jpg|upright|thumb|right|[[Paul Dirac]]]] The first formulation of a [[quantum mechanics|quantum theory]] describing radiation and matter interaction is attributed to British scientist [[Paul Dirac]], who during the 1920s computed the coefficient of [[spontaneous emission]] of an [[atom]].<ref name=dirac> {{cite journal | author=P. A. M. Dirac | author-link= Paul Dirac | year=1927 | title=The Quantum Theory of the Emission and Absorption of Radiation | journal=[[Proceedings of the Royal Society of London A]] | volume=114 | pages=243β65 | doi=10.1098/rspa.1927.0039 |bibcode = 1927RSPSA.114..243D | issue=767 | doi-access=free }}</ref> He is credited with coining the term "quantum electrodynamics".<ref>{{Cite web |title=Quantum Field Theory > The History of QFT |url=https://plato.stanford.edu/entries/quantum-field-theory/qft-history.html |access-date=2023-10-22 |website=Stanford Encyclopedia of Philosophy |first1=Meinard |last1=Kuhlmann |date=Aug 10, 2020 |orig-date=Jun 22, 2006 |url-status=live |archive-url=https://archive.today/20240616034116/https://plato.stanford.edu/entries/quantum-field-theory/qft-history.html |archive-date= 16 Jun 2024 }}</ref> Dirac described the quantization of the [[electromagnetic field]] as an ensemble of [[harmonic oscillator]]s with the introduction of the concept of [[creation and annihilation operators]] of particles. In the following years, with contributions from [[Wolfgang Pauli]], [[Eugene Wigner]], [[Pascual Jordan]], [[Werner Heisenberg]] and [[Enrico Fermi]],<ref name="fermi"> {{cite journal | author=E. Fermi | author-link= Enrico Fermi | year=1932 | title=Quantum Theory of Radiation | journal=[[Reviews of Modern Physics]] | volume=4 | issue= 1 | pages=87β132 | doi=10.1103/RevModPhys.4.87 |bibcode = 1932RvMP....4...87F }}</ref> physicists came to believe that, in principle, it was possible to perform any computation for any physical process involving photons and charged particles. However, further studies by [[Felix Bloch]] with [[Arnold Nordsieck]],<ref name="bloch">{{cite journal | author-link1= Felix Bloch | author-link2= Arnold Nordsieck | year=1937 | title=Note on the Radiation Field of the Electron | journal=[[Physical Review]] | volume=52 | pages=54β59 | doi=10.1103/PhysRev.52.54 |bibcode = 1937PhRv...52...54B | issue=2 | last1= Bloch | first1= F. | last2= Nordsieck | first2= A. }}</ref> and [[Victor Weisskopf]],<ref name=weisskopf>{{cite journal | author=V. F. Weisskopf | author-link= Victor Weisskopf | year=1939 | title=On the Self-Energy and the Electromagnetic Field of the Electron | journal=[[Physical Review]] | volume=56 | issue= 1 | pages=72β85 | doi=10.1103/PhysRev.56.72 |bibcode = 1939PhRv...56...72W }}</ref> in 1937 and 1939, revealed that such computations were reliable only at a first order of [[Perturbation theory (quantum mechanics)|perturbation theory]], a problem already pointed out by [[Robert Oppenheimer]].<ref name=oppenheimer>{{cite journal | author=R. Oppenheimer | author-link= J. Robert Oppenheimer | year=1930 | title=Note on the Theory of the Interaction of Field and Matter | journal=[[Physical Review]] | volume=35 | pages=461β77 | doi=10.1103/PhysRev.35.461 |bibcode = 1930PhRv...35..461O | issue=5 }}</ref> At higher orders in the series infinities emerged, making such computations meaningless and casting doubt on the theory's internal consistency. This suggested that [[special relativity]] and [[quantum mechanics]] were fundamentally incompatible. [[File:Hans Bethe.jpg|upright|thumb|[[Hans Bethe]] ]] Difficulties increased through the end of the 1940s. Improvements in [[microwave]] technology made it possible to take more precise measurements of the shift of the levels of a [[hydrogen atom]],<ref name=lamb> {{cite journal | author-link1= Willis Lamb | author-link2=Robert Retherford | year=1947 | title=Fine Structure of the Hydrogen Atom by a Microwave Method | journal=[[Physical Review]] | volume=72 | pages= 241β43 | doi=10.1103/PhysRev.72.241 |bibcode = 1947PhRv...72..241L | issue=3 | last1= Lamb | first1= Willis | last2= Retherford | first2= Robert | doi-access=free }}</ref> later known as the [[Lamb shift]] and [[magnetic moment]] of the electron.<ref name=foley> {{cite journal | author-link2=Polykarp Kusch | author-link1=Henry M. Foley | year=1948 | title=On the Intrinsic Moment of the Electron | journal=[[Physical Review]] | volume=73 | page=412 | doi=10.1103/PhysRev.73.412 | bibcode = 1948PhRv...73..412F | issue=3 | last1= Foley | first1= H.M. | last2= Kusch | first2= P. }}</ref> These experiments exposed discrepancies that the theory was unable to explain. A first indication of a possible solution was given by Bethe in 1947.<ref name=bethe/><ref name=schweber> {{cite book | last=Schweber | first=Silvan | author-link=Silvan Schweber | year=1994 | isbn=978-0-691-03327-3 | title=QED and the Men Who Did it: Dyson, Feynman, Schwinger, and Tomonaga | chapter=Chapter 5 | page=[https://archive.org/details/qedmenwhomadeitd0000schw/page/230 230] | publisher=Princeton University Press | chapter-url=https://archive.org/details/qedmenwhomadeitd0000schw/page/230 }}</ref> He made the first non-relativistic computation of the shift of the lines of the hydrogen atom as measured by Lamb and [[Robert Retherford|Retherford]].<ref name=bethe> {{cite journal | author=H. Bethe | author-link= Hans Bethe | year=1947 | title=The Electromagnetic Shift of Energy Levels | journal=[[Physical Review]] | volume=72 | pages=339β41 | doi=10.1103/PhysRev.72.339 |bibcode = 1947PhRv...72..339B | issue=4 | s2cid= 120434909 }}</ref> Despite limitations of the computation, agreement was excellent. The idea was simply to attach infinities to corrections of [[mass]] and [[charge (physics)|charge]] that were actually fixed to a finite value by experiments. In this way, the infinities get absorbed in those constants and yield a finite result with good experimental agreement. This procedure was named [[renormalization]]. [[File:Feynman and Oppenheimer at Los Alamos.jpg|thumb|right|[[Richard Feynman|Feynman]] (center) and [[J. Robert Oppenheimer|Oppenheimer]] (right) at [[Los Alamos National Laboratory|Los Alamos]].]] Based on Bethe's intuition and fundamental papers on the subject by [[Shin'ichirΕ Tomonaga]],<ref name=tomonaga> {{cite journal | author=S. Tomonaga | author-link= Sin-Itiro Tomonaga | year=1946 | title=On a Relativistically Invariant Formulation of the Quantum Theory of Wave Fields | journal=[[Progress of Theoretical Physics]] | volume=1 | pages= 27β42 | doi=10.1143/PTP.1.27 | issue=2 | bibcode=1946PThPh...1...27T | doi-access=free }}</ref> [[Julian Schwinger]],<ref name=schwinger1> {{cite journal | author=J. Schwinger | author-link= Julian Schwinger | year=1948 | title=On Quantum-Electrodynamics and the Magnetic Moment of the Electron | journal=[[Physical Review]] | volume=73 | pages= 416β17 | doi=10.1103/PhysRev.73.416 |bibcode = 1948PhRv...73..416S | issue=4 | doi-access=free }}</ref><ref name=schwinger2> {{cite journal | author=J. Schwinger | author-link= Julian Schwinger | year=1948 | title=Quantum Electrodynamics. I. A Covariant Formulation | journal=[[Physical Review]] | volume=74 | pages= 1439β61 | doi=10.1103/PhysRev.74.1439 |bibcode = 1948PhRv...74.1439S | issue=10 }}</ref> [[Richard Feynman]]<ref name=feynman1> {{cite journal | author=R. P. Feynman | author-link= Richard Feynman | year=1949 | title=SpaceβTime Approach to Quantum Electrodynamics | journal=[[Physical Review]] | volume=76 | pages= 769β89 | doi=10.1103/PhysRev.76.769 |bibcode = 1949PhRv...76..769F | issue=6 | doi-access=free }}</ref><ref name=feynman2>{{cite journal |author = R. P. Feynman |author-link = Richard Feynman |year = 1949 |title = The Theory of Positrons |journal = [[Physical Review]] |volume = 76 |pages = 749β59 |doi = 10.1103/PhysRev.76.749 |bibcode = 1949PhRv...76..749F |issue = 6 |s2cid = 120117564 |url = https://authors.library.caltech.edu/3520/ |access-date = 2021-11-19 |archive-date = 2022-08-09 |archive-url = https://web.archive.org/web/20220809030941/https://authors.library.caltech.edu/3520/ |url-status = dead |url-access= subscription }}</ref><ref name=feynman3> {{cite journal | author=R. P. Feynman | author-link= Richard Feynman | year=1950 | title=Mathematical Formulation of the Quantum Theory of Electromagnetic Interaction | journal=[[Physical Review]] | volume=80 | pages= 440β57 | doi=10.1103/PhysRev.80.440 |bibcode = 1950PhRv...80..440F | issue=3 | url=https://authors.library.caltech.edu/3528/1/FEYpr50.pdf }}</ref> and [[Freeman Dyson]],<ref name=dyson1> {{cite journal | author=F. Dyson | author-link= Freeman Dyson | year=1949 | title=The Radiation Theories of Tomonaga, Schwinger, and Feynman | journal=[[Physical Review]] | volume=75 | pages= 486β502 | doi=10.1103/PhysRev.75.486 |bibcode = 1949PhRv...75..486D | issue=3 | doi-access=free }}</ref><ref name=dyson2> {{cite journal | author=F. Dyson | author-link= Freeman Dyson | year=1949 | title=The S Matrix in Quantum Electrodynamics | journal=[[Physical Review]] | volume=75 | pages= 1736β55 | doi=10.1103/PhysRev.75.1736 |bibcode = 1949PhRv...75.1736D | issue=11 }}</ref> it was finally possible to produce fully [[Lorentz covariance|covariant]] formulations that were finite at any order in a perturbation series of quantum electrodynamics. Tomonaga, Schwinger, and Feynman were jointly awarded the 1965 [[Nobel Prize in Physics]] for their work in this area.<ref name=nobel65>{{cite web | title = The Nobel Prize in Physics 1965 | publisher = Nobel Foundation | url = http://nobelprize.org/nobel_prizes/physics/laureates/1965/index.html|access-date=2008-10-09}}</ref> Their contributions, and Dyson's, were about [[Lorentz covariance|covariant]] and [[gauge-invariant]] formulations of quantum electrodynamics that allow computations of observables at any order of [[Perturbation theory (quantum mechanics)|perturbation theory]]. Feynman's mathematical technique, based on his [[Feynman diagram|diagrams]], initially seemed unlike the field-theoretic, [[Operator (physics)|operator]]-based approach of Schwinger and Tomonaga, but Dyson later showed that the two approaches were equivalent.<ref name="dyson1"/> Renormalization, the need to attach a physical meaning at certain divergences appearing in the theory through [[integral]]s, became one of the fundamental aspects of [[quantum field theory]] and is seen as a criterion for a theory's general acceptability. Even though renormalization works well in practice, Feynman was never entirely comfortable with its mathematical validity, referring to renormalization as a "shell game" and "hocus pocus".<ref name=feynbook/>{{rp|128}} Neither Feynman nor Dirac were happy with that way to approach the observations made in theoretical physics, above all in quantum mechanics.<ref name=":1">{{Citation |title=The story of the positron - Paul Dirac (1975) |url=https://www.youtube.com/watch?v=Ci86Aps7CMo |access-date=2023-07-19 |language=en}}</ref> QED is the model and template for all subsequent quantum field theories. One such subsequent theory is [[quantum chromodynamics]], which began in the early 1960s and attained its present form in the 1970s, developed by [[H. David Politzer]], [[Sidney Coleman]], [[David Gross]] and [[Frank Wilczek]]. Building on Schwinger's pioneering work, [[Gerald Guralnik]], [[C. R. Hagen|Dick Hagen]], and [[Tom W. B. Kibble|Tom Kibble]],<ref> {{cite journal | last1=Guralnik | first1=G. S. | last2=Hagen | first2=C. R. | last3=Kibble | first3=T. W. B. | year=1964 | title=Global Conservation Laws and Massless Particles | journal=[[Physical Review Letters]] | volume=13 | pages=585β87 | doi=10.1103/PhysRevLett.13.585 | bibcode = 1964PhRvL..13..585G | issue=20 | doi-access=free }}</ref><ref> {{cite journal | last=Guralnik | first=G. S. | year=2009 | title=The History of the Guralnik, Hagen and Kibble development of the Theory of Spontaneous Symmetry Breaking and Gauge Particles | journal=[[International Journal of Modern Physics A]] | volume=24 | pages=2601β27 | doi=10.1142/S0217751X09045431 | arxiv=0907.3466 |bibcode = 2009IJMPA..24.2601G | issue=14 | s2cid=16298371 }}</ref> [[Peter Higgs]], [[Jeffrey Goldstone]], and others, [[Sheldon Glashow]], [[Steven Weinberg]] and [[Abdus Salam]] independently showed how the [[weak nuclear force]] and quantum electrodynamics could be merged into a single [[electroweak force]].
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