Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Tabun (nerve agent)
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==Chemistry and Synthesis== ===Reactions=== Tabun can be deactivated chemically using common oxidizing agents such as sodium hypochlorite.<ref>{{Cite web |title=Sodium Hypochlorite - Medical Countermeasures Database - CHEMM |url=https://chemm.hhs.gov/countermeasure_sodium-hypochlorite.htm |access-date=2023-11-25 |website=chemm.hhs.gov}}</ref> ===Historic synthesis=== Tabun was made on an industrial scale by Germany during World War II, based on a process developed by [[Gerhard Schrader]]. In the chemical agent factory in [[Brzeg Dolny|Dyhernfurth an der Oder]], code-named "Hochwerk", at least 12,000 metric tons of this agent were manufactured between 1942 and 1945. The manufacturing process consisted of two steps (see below)<!--, the first being reaction of gaseous [[dimethylamine]] ('''1''') with an excess of [[phosphoryl chloride]] ('''2'''), yielding dimethylamidophosphoric dichloride ('''3''', codenamed "Produkt 39" or "D 4") and dimethylammonium chloride ('''4'''). The [[dimethylamidophosphoric dichloride]] thus obtained was purified by vacuum distillation and thereafter transferred to the main tabun production line. Here it was reacted with an excess of [[sodium cyanide]] ('''5'''), dispersed in dry [[chlorobenzene]], yielding the intermediate [[dimethylamidophosphoric dicyanide]] (not depicted in the scheme) and [[sodium chloride]] ('''8'''); then, absolute [[ethanol]] ('''6''') was added, reacting with the dimethylamidophosphoric dicyanide to yield tabun ('''7''') and [[hydrogen cyanide]] ('''9'''). A-->; after the reactions, the mixture (consisting of ~75% solvent, ~25% desired product, plus insoluble salts and reactants)<!--the rest of the hydrogen cyanide--> was filtered <!--to remove the insoluble salts -->and vacuum-distilled.<!--to remove hydrogen cyanide and excess chlorobenzene, so--> This yielded a technical product consisting either of 95% <!--tabun with 5% chlorobenzene (Tabun A) or (later in the war) of--> or 80% tabun <!--with 20% chlorobenzene -->(then known as Tabun A or B, respectively,{{Inconsistent|date = March 2024}} the second a product later in the war).<ref name=Lohs1967>{{cite book |last=Lohs |first=K. |date=1967 |chapter = 3. Gifte, deren Wirkung sich hauptsächlich auf das Nervensystem bzw. [beziehungsweise] auf lebenswichtige Enzyme erstreckt [Poisons, mainly affecting the nervous system, in particular involving vital enzymes]|title= Synthetische Gifte: Zur Chemie, Toxikologie und zu Problemen ihrer völkerrechtswidrigen Anwendung durch imperialistische Armeen |edition= überarb. u. erg. [rev. and expand.] |language=German |trans-title=Synthetic poisons: On the chemistry, toxicology and problems of their illegal use by imperialist armies |url=https://www.gbv.de/dms/weimar/toc/182750841_toc.pdf | access-date=31 March 2024 | location = Berlin [East] | publisher = Militärverlag der Deutschen Demokratischen Republik (Military Publisher's of the [[German Democratic Republic]])}}{{better source|date = March 2024}} The translations of chapter and book title here were editor-generated.</ref>{{verification needed|date = March 2024}}{{better source|date = March 2024}} [[Image:TabunSynthesis.png|400px]]
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)