Editing X-ray spectroscopy (section)

==Characteristic X-ray spectroscopy==

When an electron from the inner shell of an atom is excited by the energy of a photon, it moves to a higher energy level. When it returns to the low energy level, the energy it previously gained by excitation is emitted as a photon of one of the wavelengths uniquely characteristic of the element. Analysis of the X-ray [[emission spectrum]] produces qualitative results about the elemental composition of the specimen. Comparison of the specimen's spectrum with the spectra of samples of known composition produces quantitative results (after some mathematical corrections for absorption, fluorescence and atomic number). 

Atoms can be excited by a high-energy beam of charged particles such as electrons (in an [[electron microscope]] for example), protons (see [[PIXE]]) or a beam of X-rays (see [[X-ray fluorescence]], or XRF or also recently in transmission XRT). These methods enable elements from the entire periodic table to be analysed, with the exception of H, He and Li.

In [[electron microscopy]] an electron beam excites X-rays; there are two main techniques for analysis of spectra of characteristic X-ray radiation: [[energy-dispersive X-ray spectroscopy]] (EDS) and [[wavelength dispersive X-ray spectroscopy]] (WDS). In X-ray transmission (XRT), the equivalent atomic composition (Z<sub>eff</sub>) is captured based on [[Photoelectric effect|photoelectric]] and [[Compton scattering|Compton]] effects.

=== Energy-dispersive X-ray spectroscopy  ===
{{main|Energy-dispersive X-ray spectroscopy}}
In an energy-dispersive X-ray spectrometer, a semiconductor detector measures energy of incoming photons. To maintain detector integrity and resolution it should be cooled with liquid nitrogen or by Peltier cooling. EDS is widely employed in [[electron microscopes]] (where imaging rather than spectroscopy is a main task) and in cheaper and/or portable XRF units.{{cn|date=February 2020}}
[[File:Bragg X-ray spectrometer, England Wellcome L0059139.jpg|thumb|Bragg X-ray Spectrometer]]

=== Wavelength-dispersive X-ray spectroscopy ===
{{main|Wavelength-dispersive X-ray spectroscopy}}
In a wavelength-dispersive X-ray spectrometer, a [[single crystal]] diffracts the photons according to [[Bragg's law]], which are then collected by a detector. By moving the diffraction crystal and detector relative to each other, a wide region of the spectrum can be observed. To observe a large spectral range, three of four different single crystals may be needed. In contrast to EDS, WDS is a method of sequential spectrum acquisition. While WDS is slower than EDS and more [[Sensitivity and specificity|sensitive]] to the positioning of the sample in the spectrometer, it has superior [[spectral resolution]] and sensitivity. WDS is widely used in [[microprobe]]s (where X-ray microanalysis is the main task) and in XRF; 
it is widely used in the field of X-ray diffraction to calculate various data such as interplanar spacing and wavelength of the incident X-ray using Bragg's law.