Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Crystallization
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
===Growth=== {{Main|Crystal growth}} Once the first small crystal, the nucleus, forms it acts as a convergence point (if unstable due to supersaturation) for [[molecules]] of solute touching β or adjacent to β the crystal so that it increases its own dimension in successive layers. The pattern of growth resembles the rings of an onion, as shown in the picture, where each colour indicates the same mass of solute; this mass creates increasingly thin layers due to the increasing surface area of the growing crystal. The supersaturated solute mass the original nucleus may ''capture'' in a time unit is called the ''growth rate'' expressed in kg/(m<sup>2</sup>*h), and is a constant specific to the process. Growth rate is influenced by several physical factors, such as [[surface tension]] of solution, [[pressure]], [[temperature]], relative crystal [[velocity]] in the solution, [[Reynolds number]], and so forth. The main values to control are therefore: * Supersaturation value, as an index of the quantity of solute available for the growth of the crystal; * Total crystal surface in unit fluid mass, as an index of the capability of the solute to fix onto the crystal; * Retention time, as an index of the probability of a molecule of solute to come into contact with an existing crystal; * Flow pattern, again as an index of the probability of a molecule of solute to come into contact with an existing crystal (higher in [[laminar flow]], lower in [[turbulent flow]], but the reverse applies to the probability of contact). The first value is a consequence of the physical characteristics of the solution, while the others define a difference between a well- and poorly designed crystallizer.
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)