Editing Dynamic nuclear polarization (section)

===DNP-NMR enhancement curves===

[[File:Dnp350-01.png|thumb|right|400px|<sup>1</sup>H DNP-NMR enhancement curve for cellulose char heated for several hours at 350 °C. P<sub>H</sub> − 1 is the relative polarization or intensity of the <sup>1</sup>H signal.]]

Many types of solid materials can exhibit more than one mechanism for DNP. Some examples are carbonaceous materials such bituminous coal and charcoal (wood or cellulose heated at high temperatures above their decomposition point which leaves a residual solid char). To separate out the mechanisms of DNP and to characterize the electron-nuclear interactions occurring in such solids a DNP enhancement curve can be made. A typical enhancement curve is obtained by measuring the maximum intensity of the NMR [[free induction decay|FID]] of the <sup>1</sup>H nuclei, for example, in the presence of continuous microwave irradiation as a function of the microwave frequency offset.

Carbonaceous materials such as cellulose char contain large numbers of stable free electrons delocalized in large [[polycyclic aromatic hydrocarbon]]s. Such electrons can give large polarization enhancements to nearby protons via proton-proton spin-diffusion if they are not so close together that the electron-nuclear dipolar interaction does not broaden the proton resonance beyond detection. For small isolated clusters, the free electrons are fixed and give rise to solid-state enhancements (SS). The maximal proton solid-state enhancement is observed at microwave offsets of ω ≈ ω<sub>e</sub> ± ω<sub>H</sub>, where ω<sub>e</sub> and ω<sub>H</sub> are the electron and nuclear Larmor frequencies, respectively. For larger and more densely concentrated aromatic clusters, the free electrons can undergo rapid [[exchange interaction|electron exchange interactions]]. These electrons give rise to an Overhauser enhancement centered at a microwave offset of ω<sub>e</sub> − ω<sub>H</sub> = 0. The cellulose char also exhibits electrons undergoing thermal mixing effects (TM). While the enhancement curve reveals the types electron-nuclear spin interactions in a material, it is not quantitative and the relative abundance of the different types of nuclei cannot be determined directly from the curve.<ref>{{Cite journal
|last1=Wind
|first1=R.A.
|last2=Li
|first2=L.
|last3=Maciel
|first3=G.E.
|last4=Wooten
|first4=J.B.
|title=Characterization of Electron Spin Exchange Interactions in Cellulose Chars by Means of ESR, 1H NMR, and Dynamic Nuclear Polarization
|journal=Applied Magnetic Resonance
|year=1993
|volume=5
|issue=2
|pages=161–176
|issn=0937-9347
|doi=10.1007/BF03162519|s2cid=96672106
}}
</ref>
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