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Old quantum theory
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== Limitations == The old quantum theory had some limitations:<ref>{{cite book |first=G.S. |last=Chaddha |title=Quantum Mechanics |publisher=New Age international |location=New Delhi |year=2006 |isbn=978-81-224-1465-3 |pages=8β9 |url=https://books.google.com/books?id=Bzj2JcPeAHAC&pg=PA9}}</ref> * The old quantum theory provides no means to calculate the intensities of the spectral lines. * It fails to explain the anomalous Zeeman effect (that is, where the spin of the electron cannot be neglected). * It cannot quantize "chaotic" systems, i.e. dynamical systems in which trajectories are neither closed nor periodic and whose analytical form does not exist. This presents a problem for systems as simple as a 2-electron atom which is classically chaotic analogously to the famous gravitational [[three-body problem]]. However it can be used to describe atoms with more than one electron (e.g. Helium) and the Zeeman effect.<ref>{{cite journal|last1=Solov'ev|title=Classical approach in atomic physics|journal= European Physical Journal D|year=2011|volume=65|pages=331β351|doi=10.1140/epjd/e2011-20261-6|arxiv = 1003.4387 |bibcode = 2011EPJD...65..331S|first1=E. A.|issue=3 |s2cid=119204790}}</ref> It was later proposed that the old quantum theory is in fact the [[WKB approximation|semi-classical approximation]] to the canonical quantum mechanics<ref> {{cite book |author=[[Lev Landau|L.D. Landau]], [[Evgeny Lifshitz|E.M. Lifshitz]] |year=1977 |title=Quantum Mechanics: Non-Relativistic Theory |edition=3rd |volume=3 |publisher=[[Pergamon Press]] |isbn=978-0-08-020940-1 }}</ref> but its limitations are still under investigation.
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