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Normal order
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== Uses in quantum field theory== The [[vacuum expectation value]] of a normal ordered product of creation and annihilation operators is zero. This is because, denoting the [[vacuum state]] by <math>|0\rangle</math>, the creation and annihilation operators satisfy :<math>\langle 0 | \hat{a}^\dagger = 0 \qquad \textrm{and} \qquad \hat{a} |0\rangle = 0</math> (here <math>\hat{a}^\dagger</math> and <math>\hat{a}</math> are creation and annihilation operators (either bosonic or fermionic)). Let <math>\hat{O}</math> denote a non-empty product of creation and annihilation operators. Although this may satisfy :<math>\langle 0 | \hat{O} | 0 \rangle \neq 0,</math> we have :<math>\langle 0 | :\hat{O}: | 0 \rangle = 0.</math> Normal ordered operators are particularly useful when defining a quantum mechanical [[Hamiltonian (quantum mechanics)|Hamiltonian]]. If the Hamiltonian of a theory is in normal order then the ground state energy will be zero: <math>\langle 0 |\hat{H}|0\rangle = 0</math>. ===Free fields=== With two free fields Ο and Ο, :<math>:\phi(x)\chi(y):\,\,=\phi(x)\chi(y)-\langle 0|\phi(x)\chi(y)| 0\rangle</math> where <math>|0\rangle</math> is again the vacuum state. Each of the two terms on the right hand side typically blows up in the limit as y approaches x but the difference between them has a well-defined limit. This allows us to define :Ο(x)Ο(x):. ===Wick's theorem=== {{Main|Wick's theorem}} '''Wick's theorem''' states the relationship between the time ordered product of <math>n</math> fields and a sum of normal ordered products. This may be expressed for <math>n</math> even as :<math>\begin{align} T\left[\phi(x_1)\cdots \phi(x_n)\right]=&:\phi(x_1)\cdots \phi(x_n): +\sum_\textrm{perm}\langle 0 |T\left[\phi(x_1)\phi(x_2)\right]|0\rangle :\phi(x_3)\cdots \phi(x_n):\\ &+\sum_\textrm{perm}\langle 0 |T\left[\phi(x_1)\phi(x_2)\right]|0\rangle \langle 0 |T\left[\phi(x_3)\phi(x_4)\right]|0\rangle:\phi(x_5)\cdots \phi(x_n):\\ \vdots \\ &+\sum_\textrm{perm}\langle 0 |T\left[\phi(x_1)\phi(x_2)\right]|0\rangle\cdots \langle 0 |T\left[\phi(x_{n-1})\phi(x_n)\right]|0\rangle \end{align}</math> where the summation is over all the distinct ways in which one may pair up fields. The result for <math>n</math> odd looks the same except for the last line which reads :<math> \sum_\text{perm}\langle 0 |T\left[\phi(x_1)\phi(x_2)\right]|0\rangle\cdots\langle 0 | T\left[\phi(x_{n-2})\phi(x_{n-1})\right]|0\rangle\phi(x_n). </math> This theorem provides a simple method for computing vacuum expectation values of time ordered products of operators and was the motivation behind the introduction of normal ordering.
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