Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Coordination complex
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==Application of coordination compounds== As metals only exist in solution as coordination complexes, it follows then that this class of compounds is useful in a wide variety of ways. ===Bioinorganic chemistry=== In [[bioinorganic chemistry]] and [[bioorganometallic chemistry]], coordination complexes serve either structural or catalytic functions. An estimated 30% of proteins contain metal ions. Examples include the intensely colored [[Vitamin B12|vitamin B<sub>12</sub>]], the [[Heme|heme group]] in [[hemoglobin]], the [[cytochrome]]s, the [[Chlorin|chlorin group]] in [[chlorophyll]], and [[carboxypeptidase]], a hydrolytic enzyme important in digestion. Another complex ion enzyme is [[catalase]], which decomposes the cell's waste [[hydrogen peroxide]]. Synthetic coordination compounds are also used to bind to proteins and especially nucleic acids (e.g. anticancer drug [[cisplatin]]). ===Industry=== [[Homogeneous catalysis]] is a major application of coordination compounds for the production of organic substances. Processes include [[hydrogenation]], [[hydroformylation]], [[oxidation]]. In one example, a combination of titanium trichloride and triethylaluminium gives rise to [[Ziegler–Natta catalyst]]s, used for the [[polymerization]] of ethylene and propylene to give polymers of great commercial importance as fibers, films, and plastics. Nickel, cobalt, and copper can be extracted using [[hydrometallurgy|hydrometallurgical processes]] involving complex ions. They are extracted from their ores as [[Metal ammine complex|ammine]] complexes. Metals can also be separated using the selective precipitation and solubility of complex ions. Cyanide is used chiefly for extraction of gold and silver from their ores. [[Phthalocyanine]] complexes are an important class of pigments. ===Analysis=== At one time, coordination compounds were used to identify the presence of metals in a sample. [[Qualitative inorganic analysis]] has largely been superseded by instrumental methods of analysis such as [[atomic absorption spectroscopy]] (AAS), [[inductively coupled plasma atomic emission spectroscopy]] (ICP-AES) and [[inductively coupled plasma mass spectrometry]] (ICP-MS).
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)