Editing Partition coefficient (section)

=== Electrochemical ===

Polarized liquid interfaces have been used to examine the thermodynamics and kinetics of the transfer of charged species from one phase to another. Two main methods exist. The first is [[ITIES]], "interfaces between two immiscible electrolyte solutions".<ref name="pmid12948031">{{cite journal | vauthors = Ulmeanu SM, Jensen H, Bouchard G, Carrupt PA, Girault HH | title = Water-oil partition profiling of ionized drug molecules using cyclic voltammetry and a 96-well microfilter plate system | journal = Pharmaceutical Research | volume = 20 | issue = 8 | pages = 1317–22 | date = August 2003 | pmid = 12948031 | doi = 10.1023/A:1025025804196 | s2cid = 9917932 | url = http://infoscience.epfl.ch/record/269694/files/11095_2004_Article_468694.pdf }}</ref> The second is droplet experiments.<ref>{{Cite journal| vauthors = Scholz F, Komorsky-Lovrić Š, Lovrić M |date=February 2000|title=A new access to Gibbs energies of transfer of ions across liquid{{!}}liquid interfaces and a new method to study electrochemical processes at well-defined three-phase junctions|url=https://linkinghub.elsevier.com/retrieve/pii/S1388248199001563|journal=Electrochemistry Communications|language=en|volume=2|issue=2|pages=112–118|doi=10.1016/S1388-2481(99)00156-3}}</ref> Here a reaction at a triple interface between a conductive solid, droplets of a redox active liquid phase and an [[electrolyte]] solution have been used to determine the energy required to transfer a charged species across the interface.<ref name="Bond_1994">{{cite journal | vauthors = Bond AM, Marken F | title = Mechanistic aspects of the electron and ion transport processes across the electrode | journal = [[Journal of Electroanalytical Chemistry]] | volume = 372 | issue = 1–2 | pages = 125–135 | year = 1994 | doi = 10.1016/0022-0728(93)03257-P }}</ref>