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Autoignition temperature
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==Autoignition temperature of selected substances== Temperatures vary widely in the literature and should only be used as estimates. Factors that may cause variation include [[partial pressure]] of oxygen, altitude, humidity, and amount of time required for ignition. Generally the autoignition temperature for hydrocarbon/air mixtures decreases with increasing [[molecular mass]] and increasing [[Catenation|chain length]]. The autoignition temperature is also higher for branched-chain hydrocarbons than for straight-chain hydrocarbons.<ref>Zabetakis, M. G. (1965), Flammability characteristics of combustible gases and vapours, U.S. Department of Mines, Bulletin 627.</ref> {| class="wikitable sortable" |- ! Substance !! data-sort-type="number" | Autoignition{{ref label|standCond|D|D}}!!scope="col" class="unsortable" |Note |- | [[Barium]] || {{convert|550|C|F|sortable=on|abbr=on}} ||550±90<ref name="LAURENDEAU">{{cite journal |last1=Laurendeau |first1=N. M. |last2=Glassman |first2=I. |title=Ignition Temperatures of Metals in Oxygen Atmospheres |journal=Combustion Science and Technology |date=1971-04-01|volume=3 |issue=2 |pages=77–82 |doi=10.1080/00102207108952274 |language=en}}</ref>{{ref label|Pressure|C|C}} |- | [[Bismuth]] || {{convert|735|C|F|sortable=on|abbr=on}} || 735±20<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Butane]] || {{convert|405|C|F|sortable=on|abbr=on}} || <ref>{{cite web |url=http://www.wolframalpha.com/input/?i=butane|title=Butane - Safety Properties |publisher=Wolfram|Alpha}}</ref> |- | [[Calcium]] || {{convert|790|C|F|sortable=on|abbr=on}} || 790±10<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Carbon disulfide]] || {{convert|90|C|F|sortable=on|abbr=on}} || <ref name=ETB/> |- | [[Diesel fuel|Diesel]] or [[Jet fuel|Jet A-1]] || {{convert|210|C|F|sortable=on|abbr=on}} || <ref name=TCForensics/> |- | [[Diethyl ether]] || {{convert|160|C|F|sortable=on|abbr=on}} || <ref>{{cite web |url=http://www.wolframalpha.com/input/?i=diethyl+ether|title=Diethyl Ether - Safety Properties |publisher=Wolfram|Alpha}}</ref> |- | [[Ethanol]] || {{convert|365|C|F|sortable=on|abbr=on}} || <ref name=ETB>{{citation |url=http://www.engineeringtoolbox.com/fuels-ignition-temperatures-d_171.html |title=Fuels and Chemicals - Autoignition Temperatures |publisher=engineeringtoolbox.com}}</ref> |- | [[Gasoline]] (Petrol) || {{convert|247|-|280|C|F|sortable=on|abbr=on}} || <ref name=ETB/> |- | [[Hydrogen]] || {{convert|535|C|F|sortable=on|abbr=on}} || |- | [[Iron]] || {{convert|1315|C|F|sortable=on|abbr=on}} || 1315±20<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Lead]] || {{convert|850|C|F|sortable=on|abbr=on}} || 850±5<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Leather]] / [[parchment]] ||{{convert|200|-|212|C|F|sortable=on|abbr=on}} || <ref name=TCForensics>{{cite web|last1=Cafe|first1=Tony|title=PHYSICAL CONSTANTS FOR INVESTIGATORS|url=http://www.tcforensic.com.au/docs/article10.html|website=tcforensic.com.au|publisher=TC Forensic P/L.|access-date=11 February 2015}}</ref><ref name=LeatherInt>{{cite web|title=Flammability and flame retardancy of leather|url=http://www.leathermag.com/features/featureflammability-and-flame-retardancy-of-leather/|website=leathermag.com|publisher=Leather International / Global Trade Media|access-date=11 February 2015}}</ref> |- | [[Magnesium]] || {{convert|635|C|F|sortable=on|abbr=on}} || 635±5<ref name="LAURENDEAU"/>{{ref label|Magnesium|B|B}}{{ref label|Pressure|C|C}} |- | [[Magnesium]] || {{convert|473|C|F|sortable=on|abbr=on}} || <ref name=ETB/>{{ref label|Magnesium|B|B}} |- | [[Methane]] || {{convert|537|C|F|sortable=on|abbr=on}} || |- | [[Molybdenum]] || {{convert|780|C|F|sortable=on|abbr=on}} || 780±5<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Paper]] ||{{convert|218|-|246|C|F|sortable=on|abbr=on}} || <ref name=TCForensics/><ref>{{cite journal |url=http://www.tcforensic.com.au/docs/article10.html |title=Physical Constants for Investigators|author=Tony Cafe |journal=Journal of Australian Fire Investigators}} (Reproduced from "Firepoint" magazine)</ref> |- | [[Allotropes of phosphorus#White phosphorus|Phosphorus (white)]]|| {{convert|34|C|F|sortable=on|abbr=on}} || <ref name=ETB/>{{ref label|Phosphorus|A|A}}{{ref label|Magnesium|B|B}} |- | [[Silane]] || {{convert|21|C|F|sortable=on|abbr=on}} || <ref name=ETB/> <small>or below</small> |- | [[Strontium]] || {{convert|1075|C|F|sortable=on|abbr=on}} || 1075±120<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Tin]] || {{convert|940|C|F|sortable=on|abbr=on}} || 940±25<ref name="LAURENDEAU"/>{{ref label|Pressure|C|C}} |- | [[Triethylborane]] || {{convert|-20|C|F|sortable=on|abbr=on}} || <ref name=ETB/> |} {| |- |{{note label|Phosphorus|A|A}} On contact with an [[organic substance]], [[Melting|melts]] otherwise. |- |{{note label|Magnesium|B|B}} There are two distinct results in the published literature. Both are separately listed in this table. |- |{{note label|Pressure|C|C}} At 1 [[Atmosphere (unit)|atm]]. The ignition temperature depends on the air pressure. |- |{{note label|standCond|D|D}}Under [[standard conditions for temperature and pressure|standard conditions for pressure]]. |}
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