Editing Reactive-ion etching (section)

== Method of operation ==
[[File:Etching wet-chemical vs rie (EN).svg|thumb|Reactive ion etching (bottom) compared to [[photochemical etching]] (center)]]
[[File:Rieoperation.svg|thumb|A diagram of a common RIE setup. An RIE consists of two electrodes (1 and 4) that create an electric field (3) meant to accelerate ions (2) toward the surface of the samples (5).]]
Plasma is initiated in the system by applying a strong RF ([[radio frequency]]) electromagnetic field to the wafer platter. The field is typically set to a frequency of [[ISM band|13.56]] [[Megahertz]], applied at a few hundred [[watt]]s. The oscillating electric field ionizes the gas molecules by stripping them of electrons, creating a [[Plasma (physics)|plasma]].

In each cycle of the field, the electrons are electrically accelerated up and down in the chamber, sometimes striking both the upper wall of the chamber and the wafer platter. At the same time, the much more massive ions move relatively little in response to the RF electric field. When electrons are absorbed into the chamber walls they are simply fed out to ground and do not alter the electronic state of the system. However, electrons deposited on the wafer platter cause the platter to build up charge due to its DC isolation. This charge build up develops a large negative voltage on the platter, typically around a few hundred volts. The plasma itself develops a slightly positive charge due to the higher concentration of positive ions compared to free electrons.

Because of the large voltage difference, the positive ions tend to drift toward the wafer platter, where they collide with the samples to be etched. The ions react chemically with the materials on the surface of the samples, but can also knock off ([[sputter]]) some material by transferring some of their [[kinetic energy]]. Due to the mostly vertical delivery of reactive ions, reactive-ion etching can produce very [[anisotropic]] etch profiles, which contrast with the typically [[isotropic]] profiles of [[Chemical milling|wet chemical etching]].

Etch conditions in an RIE system depend strongly on the many process parameters, such as pressure, gas flows, and RF power.  A modified version of RIE is [[deep reactive-ion etching]], used to excavate deep features.