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Tin(IV) chloride
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==Structure== [[File:Tin(IV) chloride space-filling3D.png|alt=Space-filling model of anhydrous SnCl4.|left|thumb|151x151px|Space-filling model of anhydrous SnCl<sub>4</sub>.]] [[File:SnCl4-xtal-down-b-axis-2005-CM-3D-polyhedra.png|200px|left|thumb|Structure of solid SnCl<sub>4</sub>.]] Anhydrous tin(IV) chloride solidifies at −33 °C to give [[monoclinic]] crystals with the P21/c [[space group]]. It is isostructural with [[SnBr4|SnBr<sub>4</sub>]]. The molecules adopt near-perfect tetrahedral symmetry with average Sn–Cl distances of 227.9(3) pm.<ref>{{cite journal |last=Reuter |first=Hans |author2=Pawlak, Rüdiger |title=Die Molekül- und Kristallstruktur von Zinn(IV)-chlorid |journal=Zeitschrift für anorganische und allgemeine Chemie |date=April 2000 |volume=626 |issue=4 |pages=925–929 |doi=10.1002/(SICI)1521-3749(200004)626:4<925::AID-ZAAC925>3.0.CO;2-R |language=German}}</ref>
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