Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Electron diffraction
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==== Diffuse scattering ==== {{anchor|Figure 16}}[[File:NbCoSb showing diffuse scattering.png|thumb|Figure 16: Single frame extracted from a video of a Nb<sub>0.83</sub>CoSb sample showing diffuse intensity (snake-like) due to vacancies at the Nb sites|alt=Diffraction pattern showing extra features (wavy lines here) due to disorder.]] A further step beyond superstructures and aperiodic materials is what is called ''diffuse scattering'' in electron diffraction patterns due to disorder,<ref name="Cowley95" />{{Rp|location=Chpt 17}} which is also known for x-ray<ref>{{Cite journal |last=Welberry |first=T. R. |date=2014 |title=One Hundred Years of Diffuse X-ray Scattering |url=http://link.springer.com/10.1007/s11661-013-1889-2 |journal=Metallurgical and Materials Transactions A |language=en |volume=45 |issue=1 |pages=75β84 |doi=10.1007/s11661-013-1889-2 |bibcode=2014MMTA...45...75W |s2cid=137476417 |issn=1073-5623|url-access=subscription }}</ref> or neutron<ref>{{Cite book |last=Nield |first=Victoria M. |url=https://www.worldcat.org/oclc/45485010 |title=Diffuse neutron scattering from crystalline materials |date=2001 |publisher=Clarendon Press |others=David A. Keen |isbn=0-19-851790-4 |location=Oxford |oclc=45485010}}</ref> scattering. This can occur from inelastic processes, for instance, in bulk silicon the atomic vibrations ([[phonon]]s) are more prevalent along specific directions, which leads to streaks in diffraction patterns.<ref name="Cowley95" />{{Rp|location=Chpt 12}} Sometimes it is due to arrangements of [[point defect]]s. Completely disordered substitutional point defects lead to a general background which is called ''Laue monotonic scattering.''<ref name="Cowley95" />{{Rp|location=Chpt 12}} Often there is a [[probability distribution]] for the distances between point defects or what type of substitutional atom there is, which leads to distinct three-dimensional intensity features in diffraction patterns. An example of this is for a Nb<sub>0.83</sub>CoSb sample, with the diffraction pattern shown in [[#Figure 16|Figure 16]]. Because of the vacancies at the niobium sites, there is diffuse intensity with snake-like structure due to correlations of the distances between vacancies and also the relaxation of Co and Sb atoms around these vacancies.<ref>{{Cite journal |last1=Roth |first1=N. |last2=Beyer |first2=J. |last3=Fischer |first3=K. F. F. |last4=Xia |first4=K. |last5=Zhu |first5=T. |last6=Iversen |first6=B. B. |date=2021 |title=Tuneable local order in thermoelectric crystals |url=https://journals.iucr.org/m/issues/2021/04/00/fc5055/ |journal=IUCrJ |language=en |volume=8 |issue=4 |pages=695β702 |doi=10.1107/S2052252521005479 |issn=2052-2525 |pmc=8256708 |pmid=34258017|arxiv=2103.08543 |bibcode=2021IUCrJ...8..695R }}</ref>
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)