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Distillation
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===Other types=== * The process of [[reactive distillation]] involves using the reaction vessel as the still. In this process, the product is usually significantly lower boiling than its reactants. As the product is formed from the reactants, it is vaporized and removed from the reaction mixture. This technique is an example of a continuous vs. a batch process; advantages include less downtime to charge the reaction vessel with starting material, and less workup. Distillation "over a reactant" could be classified as a reactive distillation. It is typically used to remove volatile impurity from the distillation feed. For example, a little [[lime (material)|lime]] may be added to remove carbon dioxide from water followed by a second distillation with a little [[sulfuric acid]] added to remove traces of ammonia. * [[Catalytic distillation]] is the process by which the reactants are catalyzed while being distilled to continuously separate the products from the reactants. This method is used to assist equilibrium reactions in reaching completion. * [[Pervaporation]] is a method for the separation of mixtures of liquids by partial vaporization through a non-porous [[Artificial membrane|membrane]]. * [[Extractive distillation]] is defined as distillation in the presence of a miscible, high boiling, relatively non-volatile component, the solvent, that forms no [[azeotrope]] with the other components in the mixture. * [[Flash evaporation]] (or partial evaporation) is the partial [[vaporization]] that occurs when a saturated liquid stream undergoes a reduction in pressure by passing through a throttling [[valve]] or other throttling device. This process is one of the simplest unit operations, being equivalent to a distillation with only one equilibrium stage. * Codistillation is distillation which is performed on mixtures in which the two compounds are not miscible. In the laboratory, the [[Dean-Stark apparatus]] is used for this purpose to remove water from synthesis products. The Bleidner apparatus is another example with two refluxing solvents. * Membrane distillation is a type of distillation in which vapors of a mixture to be separated are passed through a membrane, which selectively permeates one component of mixture. Vapor pressure difference is the driving force. It has potential applications in seawater desalination and in removal of organic and inorganic components. The unit process of [[evaporation]] may also be called "distillation": * In [[rotary evaporation]] a vacuum distillation apparatus is used to remove bulk [[solvent]]s from a sample. Typically the vacuum is generated by a [[aspirator (pump)|water aspirator]] or a [[membrane pump]]. * In a [[Kugelrohr apparatus]] a short path distillation apparatus is typically used (generally in combination with a (high) vacuum) to distill high boiling (> 300 Β°C) compounds. The apparatus consists of an oven in which the compound to be distilled is placed, a receiving portion which is outside of the oven, and a means of rotating the sample. The vacuum is normally generated by using a high vacuum pump. Other uses: * [[Dry distillation]] or [[destructive distillation]], despite the name, is not truly distillation, but rather a [[chemical reaction]] known as [[pyrolysis]] in which solid substances are heated in an inert or [[redox|reducing]] atmosphere and any volatile fractions, containing high-boiling liquids and products of pyrolysis, are collected. The destructive distillation of [[wood]] to give [[methanol]] is the root of its common name β ''wood alcohol''. * [[Freeze distillation]] is an analogous method of purification using [[freezing]] instead of evaporation. It is not truly distillation, but a [[Recrystallization (chemistry)|recrystallization]] where the product is the [[mother liquor]], and does not produce products equivalent to distillation. This process is used in the production of [[American-style lager#Ice beer|ice beer]] and [[ice wine]] to increase ethanol and [[sugar]] content, respectively. It is also used to produce [[Applejack (beverage)|applejack]]. Unlike distillation, freeze distillation concentrates poisonous congeners rather than removing them; As a result, many countries prohibit such applejack as a health measure. Also, distillation by evaporation can separate these since they have different boiling points. * Distillation by filtration: In early alchemy and chemistry, otherwise known as natural philosophy, a form of "distillation" by capillary filtration was known as a form of distillation at the time. In this, a series of cups or bowls were set upon a stepped support with a "wick" of cotton or felt-like material, which had been wetted with water or a clear liquid with each step dripping down through the wetted cloth through capillary action in succeeding steps, creating a "purification" of the liquid, leaving solid materials behind in the upper bowls and purifying the succeeding product through capillary action through the moistened cloth. This was called "distillatio" by filtration by those using the method.
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