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Distillation
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===Pressure-swing distillation=== {{further|Azeotrope#Pressure swing distillation}} Pressure-swing distillation is essentially the same as the unidirectional distillation used to break azeotropic mixtures, but here both [[Azeotrope#Pressure swing distillation|positive and negative pressures may be employed]]. This improves the selectivity of the distillation and allows a chemist to optimize distillation by avoiding extremes of pressure and temperature that waste energy. This is particularly important in commercial applications. One example of the application of pressure-swing distillation is during the industrial purification of [[ethyl acetate]] after its catalytic synthesis from [[ethanol]].
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