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Diode-pumped solid-state laser
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== Common DPSSL processes == [[File:YAG2.svg|thumb|300px|Neodymium ions in various types of ionic crystals, and also in glasses, act as a laser gain medium, typically emitting 1,064 nm light from a particular atomic transition in the neodymium ion, after being "pumped" into excitation from an external source. Selection of 946 nm transition light is possible, as well]] The most common DPSSL in use is the 532 nm [[wavelength]] '''green''' [[laser pointer]]. A powerful (>200 [[milliwatt|mW]]) 808 nm wavelength [[infrared]] [[GaAlAs]] laser diode pumps a neodymium-doped [[yttrium aluminium garnet]] (Nd:YAG) or a [[neodymium-doped yttrium orthovanadate]] (Nd:YVO<sub>4</sub>) crystal which produces 1064 nm wavelength light from the main spectral transition of [[neodymium]] ion. This light is then ''frequency doubled'' using a [[nonlinear optics|nonlinear optical]] process in a [[potassium titanyl phosphate|KTP]] crystal, producing 532 nm light. Green DPSSLs are usually around 20% efficient, although some lasers can reach up to 35% efficiency. In other words, a green DPSSL using a 2.5 W pump diode would be expected to output around 500-900 mW of 532 nm light. In optimal conditions, Nd:YVO<sub>4</sub> has a conversion efficiency of 60%,<ref>{{cite web|url=http://www.unitedcrystals.com/YVO4Prop.html|title=Nd:YVO4 Properties|website=www.unitedcrystals.com}}</ref> while KTP has a conversion efficiency of 80%.<ref>{{cite web|url=http://www.unitedcrystals.com/KTPProp.html|title=KTP Properties|website=www.unitedcrystals.com}}</ref> In other words, a green DPSSL can theoretically have an overall efficiency of 48%. In the realm of very high output powers, the KTP crystal becomes susceptible to optical damage. Thus, high-power DPSSLs generally have a larger beam diameter, as the 1064 nm laser is expanded before it reaches the KTP crystal, reducing the irradiance from the infrared light. In order to maintain a lower beam diameter, a crystal with a higher damage threshold, such as [[lithium triborate]] (LBO), is used instead. '''Blue''' DPSSLs use a nearly identical process, except that the 808 nm light is being converted by an Nd:YAG crystal to 946 nm light (selecting this non-principal spectral line of neodymium in the same Nd-doped crystals), which is then frequency-doubled to 473 nm by a [[beta barium borate]] (BBO) crystal or LBO crystal. Because of the lower gain for the materials, blue lasers are relatively weak, and are only around 3-5% efficient. In the late 2000s, it was discovered that [[bismuth triborate]] (BiBO) crystals were more efficient than BBO or LBO for second harmonic generation in mode-locked lasers and do not have the disadvantage of being [[hygroscopy|hygroscopic]],<ref name=redop>{{cite web|url=http://www.redoptronics.com/BIBO-crystal.html|title=BIBO Crystal for Blue Laser|website=www.redoptronics.com}}</ref> which degrades the crystal if it is exposed to moisture. In continuous-wave laser applications, however, BiBO may exhibit instabilities which degrade its performance.<ref>{{Cite journal |last1=Ruseva |first1=Valentina |last2=Hald |first2=Jan |date=2004-06-01 |title=Generation of UV light by frequency doubling in BIBO |url=https://linkinghub.elsevier.com/retrieve/pii/S0030401804002986 |journal=Optics Communications |language=en |volume=236 |issue=1β3 |pages=219β223 |doi=10.1016/j.optcom.2004.03.033|bibcode=2004OptCo.236..219R |url-access=subscription }}</ref> '''Yellow''' DPSSLs use an even more complicated process: An 808 nm pump diode is used to generate 1,064 nm and 1,342 nm light, which are summed in parallel to become 593.5 nm. Due to their complexity, most yellow DPSSLs are only around 1% efficient, and usually more expensive per unit of power. Another method is to generate 1,064 and 1,319 nm light, which are summed to 589 nm.<ref name=aip75>{{Cite web |url=http://jap.aip.org/resource/1/japiau/v75/i12/p8240_s1?isAuthorized=no |title=589 nm light generation by intracavity mixing in a Nd:YAG laser | Browse Journal - Journal of Applied Physics |access-date=2010-11-17 |archive-url=https://web.archive.org/web/20110722192236/http://jap.aip.org/resource/1/japiau/v75/i12/p8240_s1?isAuthorized=no |archive-date=2011-07-22 |url-status=dead }}</ref> This process is more efficient, with about 3% of the pump diode's power being converted to yellow light.<ref>Yellow lasers with 2.5 W pump diodes have reached up to around 80 mW</ref>
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