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Electron affinity
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== Electron affinities of the elements == [[File:Electron affinity of the elements.svg|thumb|200px|Electron affinity (''E''<sub>ea</sub>) vs atomic number (''Z''). Note the sign convention explanation in the previous section.]] {{Main|Electron affinity (data page)}} Although ''E''<sub>ea</sub> varies greatly across the [[periodic table]], some patterns emerge. Generally, [[nonmetals]] have more positive ''E''<sub>ea</sub> than [[metal]]s. Atoms whose anions are more stable than neutral atoms have a greater ''E''<sub>ea</sub>. [[Chlorine]] most strongly attracts extra electrons; [[neon]] most weakly attracts an extra electron. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values. ''E''<sub>ea</sub> generally increases across a period (row) in the periodic table prior to reaching group 18. This is caused by the filling of the valence shell of the atom; a [[halogen|group 17]] atom releases more energy than a [[Group 1 element|group 1]] atom on gaining an electron because it obtains a filled [[electron shell|valence shell]] and therefore is more stable. In group 18, the valence shell is full, meaning that added electrons are unstable, tending to be ejected very quickly. Counterintuitively, ''E''<sub>ea</sub> does ''not'' decrease when progressing down most columns of the periodic table. For example, ''E''<sub>ea</sub> actually increases consistently on descending the column for the [[Group 2 element|group 2]] data. Thus, electron affinity follows the same "left-right" trend as electronegativity, but not the "up-down" trend. The following data are quoted in [[Joule per mole|kJ/mol]]. {| class="mw-collapsible {{#if:{{{state|collapsed}}}|collapsed|mw-collapsed}}" style="text-align: center; background: {{Element color|table background}}; border: 1px solid {{Element color|table border}}; width: 100%; max-width: 1300px; margin: 0 auto; padding: 2px; cellpadding: 0; cellspacing: 1;" |+ style="background: {{Element color|table title}}; padding: 2px 4px;" | [[Electron affinities]] in the [[periodic table]] |- style="background: {{Element color|table colheader}}" ! width="1.0%" | <small>[[Periodic table group|Group]] β</small> ! width="5.4%" | [[Alkali metal|1]] ! width="5.4%" | [[Alkaline earth metal|2]] ! width="1.8%" | ! width="5.4%" | [[Group 3 element|3]] ! width="5.4%" | [[Group 4 element|4]] ! width="5.4%" | [[Group 5 element|5]] ! width="5.4%" | [[Group 6 element|6]] ! width="5.4%" | [[Group 7 element|7]] ! width="5.4%" | [[Group 8 element|8]] ! width="5.4%" | [[Group 9 element|9]] ! width="5.4%" | [[Group 10 element|10]] ! width="5.4%" | [[Group 11 element|11]] ! width="5.4%" | [[Group 12 element|12]] ! width="5.4%" | [[Boron group|13]] ! width="5.4%" | [[Carbon group|14]] ! width="5.4%" | [[Pnictogen|15]] ! width="5.4%" | [[Chalcogen|16]] ! width="5.4%" | [[Halogen|17]] ! width="5.4%" | [[Noble gas|18]] |- ! <small>β [[Periodic table period|Period]]</small> | colspan="20"|<br /> |- ! [[Period 1 element|1]] | {{element cell property|H |hydrogen |73 |s-block|Primordial}} | colspan="17"|<br /> | {{element cell property|He|helium |(β50) |s-block|Primordial}} |- ! [[Period 2 element|2]] | {{element cell property|Li|lithium |60 |s-block|Primordial}} | {{element cell property|Be|beryllium |(β50)|s-block|Primordial}} | colspan="11"|<br /> | {{element cell property|B |boron |27 |p-block|Primordial}} | {{element cell property|C |carbon |122 |p-block|Primordial}} | {{element cell property|N |nitrogen |β7 |p-block|Primordial}} | {{element cell property|O |oxygen |141 |p-block|Primordial}} | {{element cell property|F |fluorine |328 |p-block|Primordial}} | {{element cell property|Ne|neon |(β120) |p-block|Primordial}} |- ! [[Period 3 element|3]] | {{element cell property|Na|sodium |53 |s-block|Primordial}} | {{element cell property|Mg|magnesium |(β40) |s-block|Primordial}} | colspan="11"|<br /> | {{element cell property|Al|aluminium |42 |p-block|Primordial}} | {{element cell property|Si|silicon |134 |p-block|Primordial}} | {{element cell property|P |phosphorus|72 |p-block|Primordial}} | {{element cell property|S |sulfur |200 |p-block|Primordial}} | {{element cell property|Cl|chlorine |349 |p-block|Primordial}} | {{element cell property|Ar|argon |(β96) |p-block|Primordial}} |- ! [[Period 4 element|4]] | {{element cell property|K |potassium |48 |s-block|Primordial}} | {{element cell property|Ca|calcium |2 |s-block|Primordial}} | | {{element cell property|Sc|scandium |18|d-block|Primordial}} | {{element cell property|Ti|titanium |7 |d-block|Primordial}} | {{element cell property|V |vanadium |51 |d-block|Primordial}} | {{element cell property|Cr|chromium |65 |d-block|Primordial}} | {{element cell property|Mn|manganese |(β50) |d-block|Primordial}} | {{element cell property|Fe|iron |15 |d-block|Primordial}} | {{element cell property|Co|cobalt |64 |d-block|Primordial}} | {{element cell property|Ni|nickel |112 |d-block|Primordial}} | {{element cell property|Cu|copper |119 |d-block|Primordial}} | {{element cell property|Zn|zinc |(β60) |d-block|Primordial}} | {{element cell property|Ga|gallium |29 |p-block|Primordial}} | {{element cell property|Ge|germanium |119 |p-block|Primordial}} | {{element cell property|As|arsenic |78 |p-block|Primordial}} | {{element cell property|Se|selenium |195 |p-block|Primordial}} | {{element cell property|Br|bromine |325 |p-block|Primordial}} | {{element cell property|Kr|krypton |(β96) |p-block|Primordial}} |- ! [[Period 5 element|5]] | {{element cell property|Rb|rubidium |47 |s-block|Primordial}} | {{element cell property|Sr|strontium |5 |s-block|Primordial}} | | {{element cell property|Y |yttrium |30 |d-block|Primordial}} | {{element cell property|Zr|zirconium |42 |d-block|Primordial}} | {{element cell property|Nb|niobium |89 |d-block|Primordial}} | {{element cell property|Mo|molybdenum|72 |d-block|Primordial}} | {{element cell property|Tc|technetium|(53) |d-block|from decay}} | {{element cell property|Ru|ruthenium |(101)|d-block|Primordial}} | {{element cell property|Rh|rhodium |110|d-block|Primordial}} | {{element cell property|Pd|palladium |54|d-block|Primordial}} | {{element cell property|Ag|silver |126|d-block|Primordial}} | {{element cell property|Cd|cadmium |(β70)|d-block|Primordial}} | {{element cell property|In|indium |37|p-block|Primordial}} | {{element cell property|Sn|tin |107|p-block|Primordial}} | {{element cell property|Sb|antimony |101|p-block|Primordial}} | {{element cell property|Te|tellurium |190|p-block|Primordial}} | {{element cell property|I |iodine |295|p-block|Primordial}} | {{element cell property|Xe|xenon |(β80)|p-block|Primordial}} |- ! [[Period 6 element|6]] | {{element cell property|Cs|caesium |46|s-block|Primordial}} | {{element cell property|Ba|barium |14|s-block|Primordial}} | {{element cell-asterisk|1}} | {{element cell property|Lu|lutetium |23|d-block|Primordial}} | {{element cell property|Hf|hafnium |17|d-block|Primordial}} | {{element cell property|Ta|tantalum |31|d-block|Primordial}} | {{element cell property|W |tungsten |79|d-block|Primordial}} | {{element cell property|Re|rhenium |6|d-block|Primordial}} | {{element cell property|Os|osmium |104|d-block|Primordial}} | {{element cell property|Ir|iridium |151|d-block|Primordial}} | {{element cell property|Pt|platinum |205|d-block|Primordial}} | {{element cell property|Au|gold |223|d-block|Primordial}} | {{element cell property|Hg|mercury |(β50)|d-block|Primordial|mercury (element)}} | {{element cell property|Tl|thallium |31|p-block|Primordial}} | {{element cell property|Pb|lead |34|p-block|Primordial}} | {{element cell property|Bi|bismuth |91|p-block|Primordial}} | {{element cell property|Po|polonium |(136)|p-block|from decay}} | {{element cell property|At|astatine |233|p-block|from decay}} | {{element cell property|Rn|radon |(β70)|p-block|from decay}} |- ! [[Period 7 element|7]] | {{element cell property|Fr|francium |(47)|s-block|from decay}} | {{element cell property|Ra|radium |(10)|s-block|from decay}} | {{element cell-asterisk|2vert}} | {{element cell property|Lr|lawrencium |(β30)|d-block|Synthetic}} | {{element cell property|Rf|rutherfordium| |d-block|Synthetic}} | {{element cell property|Db|dubnium | |d-block|Synthetic}} | {{element cell property|Sg|seaborgium | |d-block|Synthetic}} | {{element cell property|Bh|bohrium | |d-block|Synthetic}} | {{element cell property|Hs|hassium | |d-block|Synthetic}} | {{element cell property|Mt|meitnerium | |d-block|Synthetic}} | {{element cell property|Ds|darmstadtium | |d-block|Synthetic}} | {{element cell property|Rg|roentgenium |(151)|d-block|Synthetic}} | {{element cell property|Cn|copernicium |(<0)|d-block|Synthetic}} | {{element cell property|Nh|nihonium |(67)|p-block|Synthetic}} | {{element cell property|Fl|flerovium |(<0)|p-block|Synthetic}} | {{element cell property|Mc|moscovium |(35)|p-block|Synthetic}} | {{element cell property|Lv|livermorium |(75)|p-block|Synthetic}} | {{element cell property|Ts|tennessine |(166)|p-block|Synthetic}} | {{element cell property|Og|oganesson |(8)|p-block|Synthetic}} |- | colspan="22"|<br /> |- | colspan="4" {{element cell-asterisk|1|align=right}} | {{element cell property|La|lanthanum |54|f-block|Primordial}} | {{element cell property|Ce|cerium |55|f-block|Primordial}} | {{element cell property|Pr|praseodymium|11|f-block|Primordial}} | {{element cell property|Nd|neodymium |9|f-block|Primordial}} | {{element cell property|Pm|promethium |(12)|f-block|from decay}} | {{element cell property|Sm|samarium |(16)|f-block|Primordial}} | {{element cell property|Eu|europium |11|f-block|Primordial}} | {{element cell property|Gd|gadolinium |(13)|f-block|Primordial}} | {{element cell property|Tb|terbium |13|f-block|Primordial}} | {{element cell property|Dy|dysprosium |1|f-block|Primordial}} | {{element cell property|Ho|holmium |(33)|f-block|Primordial}} | {{element cell property|Er|erbium |(30)|f-block|Primordial}} | {{element cell property|Tm|thulium |99|f-block|Primordial}} | {{element cell property|Yb|ytterbium |(β2)|f-block|Primordial}} |- | colspan="4" {{element cell-asterisk|2vert|align=right}} | {{element cell property|Ac|actinium |(34)|f-block|from decay}} | {{element cell property|Th|thorium |(113)|f-block|Primordial}} | {{element cell property|Pa|protactinium|(53)|f-block|from decay}} | {{element cell property|U |uranium |(51)|f-block|Primordial}} | {{element cell property|Np|neptunium |(46)|f-block|from decay}} | {{element cell property|Pu|plutonium |(β48)|f-block|from decay}} | {{element cell property|Am|americium |(10)|f-block|Synthetic}} | {{element cell property|Cm|curium |(27)|f-block|Synthetic}} | {{element cell property|Bk|berkelium |(β165)|f-block|Synthetic}} | {{element cell property|Cf|californium |(β97)|f-block|Synthetic}} | {{element cell property|Es|einsteinium |(β29)|f-block|Synthetic}} | {{element cell property|Fm|fermium |(34)|f-block|Synthetic}} | {{element cell property|Md|mendelevium |(94)|f-block|Synthetic}} | {{element cell property|No|nobelium |(β223)|f-block|Synthetic}} |- | colspan=19 style="text-align:left;" | '''Legend''' |- | colspan=19 style="text-align:left;" |Values are in [[Joule per mole|kJ/mol]], rounded |- | colspan=19 style="text-align:left;" | For the equivalent in eV, see: [[Electron affinity (data page)]] |- | colspan=19 style="text-align:left;" | [[Bracket|Parentheses or Round brackets()]] denote predictions |- | colspan=19 | {{periodic table legend |theme1=Occurrence |theme2=Block|unknown2=no}} |}
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