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Freezing-point depression
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=== Due to concentration and entropy === In the liquid solution, the solvent is diluted by the addition of a solute, so that fewer molecules are available to freeze (a lower concentration of solvent exists in a solution versus pure solvent). Re-establishment of equilibrium is achieved at a lower temperature at which the rate of freezing becomes equal to the rate of liquefying. The solute is not occluding or preventing the solvent from solidifying, it is simply diluting it so there is a reduced probability of a solvent making an attempt at freezing in any given moment. At the lower freezing point, the vapor pressure of the liquid is equal to the vapor pressure of the corresponding solid, and the chemical potentials of the two phases are equal as well.
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