Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Group 12 element
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
===Periodic trends=== All elements in this group are [[metal]]s. The similarity of the metallic radii of cadmium and mercury is an effect of the [[lanthanide contraction]]. So, the trend in this group is unlike the trend in group 2, the [[alkaline earth]]s, where metallic radius increases smoothly from top to bottom of the group. All three metals have relatively low melting and boiling points, indicating that the [[metallic bond]] is relatively weak, with relatively little overlap between the [[valence band]] and the [[conduction band]].<ref name = "chemyst">{{cite web |url=http://www.alchemyst.co.uk/alchemystry/pdf/Inorganic/descriptive_pblock.pdf |title= Descriptive P-block Notes|author=Moss, Alex |year=2003 |publisher=Alchemyst Online|access-date=June 2, 2011}}</ref> Thus, zinc is close to the boundary between metallic and [[metalloid]] elements, which is usually placed between [[gallium]] and [[germanium]], though gallium participates in [[semi-conductor]]s such as [[gallium arsenide]]. Zinc and cadmium are [[Electropositivity|electropositive]] while mercury is not.<ref name = "chemyst"/> As a result, zinc and cadmium metal are good reducing agents. The elements of group 12 have an oxidation state of +2 in which the ions have the rather stable d<sup>10</sup> electronic configuration, with a full [[electron shell|sub-shell]]. However, mercury can easily be reduced to the +1 oxidation state; usually, as in the ion {{chem|Hg|2|2+}}, two mercury(I) ions come together to form a metal-metal bond and a [[diamagnetic]] species.<ref>{{cite journal |last1=Lindberg |first1=S. E. |last2=Stratton |first2=W. J. |year=1998 |title=Atmospheric Mercury Speciation: Concentrations and Behavior of Reactive Gaseous Mercury in Ambient Air|journal=Environmental Science and Technology |volume=32 |issue=1 |doi=10.1021/es970546u |pages=49β57 |bibcode = 1998EnST...32...49L }}</ref> Cadmium can also form species such as [Cd<sub>2</sub>Cl<sub>6</sub>]<sup>4β</sup> in which the metal's oxidation state is +1. Just as with mercury, the formation of a metal-metal bond results in a diamagnetic compound in which there are no unpaired electrons; thus, making the species very reactive. Zinc(I) is known mostly in the gas phase, in such compounds as linear Zn<sub>2</sub>Cl<sub>2</sub>, analogous to [[calomel]]. In the solid phase, the rather exotic compound [[decamethyldizincocene]] (Cp*ZnβZnCp*) is known.
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)