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Irreversible process
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== Examples of irreversible processes == In the physical realm, many irreversible processes are present to which the inability to achieve 100% efficiency in energy transfer can be attributed. The following is a list of spontaneous events which contribute to the irreversibility of processes.<ref>Moran, John (2008). "Fundamentals of Engineering Thermodynamics", p. 220. John Wiley & Sons, Inc., USA. {{ISBN|978-0-471-78735-8}}.</ref> * [[Ageing]] (this claim is disputed, as aging has been demonstrated to be reversed in mice.<ref>{{cite journal |last1=Ledford |first1=Heidi |title=Reversal of biological clock restores vision in old mice |journal=Nature |date=2 December 2020 |volume=588 |issue=7837 |pages=209 |doi=10.1038/d41586-020-03403-0 |pmid=33268879 |bibcode=2020Natur.588..209L |s2cid=227259860 }}</ref> [[Nicotinamide adenine dinucleotide|NAD+]]<ref>{{cite journal |last1=Yang |first1=Qingling |last2=Cong |first2=Luping |last3=Wang |first3=Yujiao |last4=Luo |first4=Xiaoyan |last5=Li |first5=Hui |last6=Wang |first6=Huan |last7=Zhu |first7=Jing |last8=Dai |first8=Shanjun |last9=Jin |first9=Haixia |last10=Yao |first10=Guidong |last11=Shi |first11=Senlin |last12=Hsueh |first12=Aaron J. |last13=Sun |first13=Yingpu |title=Increasing ovarian NAD+ levels improve mitochondrial functions and reverse ovarian aging |journal=Free Radical Biology and Medicine |date=20 August 2020 |volume=156 |pages=1β10 |doi=10.1016/j.freeradbiomed.2020.05.003 |pmid=32492457 |s2cid=219312914 }}</ref> and [[telomerase]]<ref>{{cite journal |last1=Tsoukalas |first1=Dimitris |last2=Buga |first2=Ana |last3=Docea |first3=Anca |last4=Sarandi |first4=Evangelia |last5=Mitrut |first5=Radu |last6=Renieri |first6=Elisavet |last7=Spandidos |first7=Demetrios |last8=Rogoveanu |first8=Ion |last9=Cercelaru |first9=Liliana |last10=Niculescu |first10=Mihaela |last11=Tsatsakis |first11=Aristidis |last12=Calina |first12=Daniela |title=Reversal of brain aging by targeting telomerase: A nutraceutical approach |journal=International Journal of Molecular Medicine |date=10 September 2021 |volume=48 |issue=5 |pages=199 |doi=10.3892/ijmm.2021.5032 |pmid=34515324 |pmc=8448543 }}</ref> have also been demonstrated to reverse ageing.) * [[Death]] * [[Time]] * [[Heat transfer]] through a finite temperature difference * [[Friction]] * [[Deformation (engineering)#Plastic deformation|Plastic deformation]] * Flow of electric current through a [[Resistance (electricity)|resistance]] * Magnetization or polarization with a hysteresis * Unrestrained [[Fluid mechanics|expansion of fluids]] * Spontaneous chemical reactions * Spontaneous mixing of matter of varying composition/states A [[Joule expansion]] is an example of classical thermodynamics, as it is easy to work out the resulting increase in entropy. It occurs where a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated; the partition between the two parts of the container is then opened, and the gas fills the whole container. The internal energy of the gas remains the same, while the volume increases. The original state cannot be recovered by simply compressing the gas to its original volume, since the internal energy will be increased by this compression. The original state can only be recovered by then cooling the re-compressed system, and thereby irreversibly heating the environment. The diagram to the right applies only if the first expansion is "free" (Joule expansion), i.e. there can be no atmospheric pressure outside the cylinder and no weight lifted.
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