Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Lead(II) iodide
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
== Applications == Lead iodide is a precursor material in the fabrication of highly efficient [[Perovskite solar cell]]. Typically, a solution of {{chem|Pb|I|2}} in an organic solvent, such as [[dimethylformamide]] or dimethylsulfoxide, is applied over a [[titanium dioxide]] layer by [[spin coating]]. The layer is then treated with a solution of [[methylammonium iodide]] {{chem|C|H|3|N|H|3|I}} and [[Annealing (metallurgy)|annealed]], turning it into the [[double salt]] [[methylammonium lead iodide]] {{chem|C|H|3|N|H|3|Pb|I|3}}, with a [[perovskite]] structure. The reaction changes the film's color from yellow to light brown.<ref name=Dhiaputra/> {{chem|Pb|I|2}} is also used as a high-energy photon detector for gamma-rays and X-rays, due to its wide band gap which ensures low noise operation.<ref name="patnaik" /><ref name=Shah/><ref name="forn" /> Lead iodide was formerly used as a paint pigment under the name "iodine yellow". It was described by [[Prosper Mérimée]] (1830) as "not yet much known in commerce, is as bright as [[orpiment]] or [[lead(II) chromate|chromate of lead]]. It is thought to be more permanent; but time only can prove its pretension to so essential a quality. It is prepared by precipitating a solution of acetate or nitrate of lead, with potassium iodide: the nitrate produces a more brilliant yellow color."<ref name=Eastaugh/> However, due to the toxicity and instability of the compound it is no longer used as such.<ref name=Eastaugh/> It may still be used in art for [[bronzing]] and in gold-like [[mosaic]] tiles.<ref name="patnaik" />
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)