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Nitronium ion
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==Related species== The compounds [[nitryl fluoride]], {{chem2|NO2F}}, and [[nitryl chloride]], {{chem2|NO2Cl}}, are not nitronium salts but molecular compounds, as shown by their low boiling points (−72 °C and −6 °C respectively) and short nitrogen–halogen bond lengths (N–F 135 pm, N–Cl 184 pm).<ref>[[F. Albert Cotton|F. A. Cotton]] and G.Wilkinson, Advanced Inorganic Chemistry, 5th edition (1988), Wiley, p.333</ref> Addition of one electron forms the neutral [[nitryl]] [[radical (chemistry)|radical]], {{chem2|NO2•}}; in fact, this is fairly stable and known as the compound [[nitrogen dioxide]]. The related negatively charged species is {{chem2|NO2(−)}}, the [[nitrite]] ion.
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