Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Sharpless epoxidation
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==Kinetic resolution== The Sharpless epoxidation can also give [[kinetic resolution]] of a racemic mixture of secondary 2,3-epoxyalcohols. While the yield of a kinetic resolution process cannot be higher than 50%, the [[enantiomeric excess]] approaches 100% in some reactions.<ref>{{cite journal|author1=Kitano, Y. |author2=Matsumoto, T. |author3=Sato, F. |journal=[[Tetrahedron (journal)|Tetrahedron]]|year=1988|volume=44|pages= 4073β4086|doi=10.1016/S0040-4020(01)86657-6|title=A highly efficient kinetic resolution of Ξ³- and Ξ²- trimethylsilyl secondary allylic alcohols by the sharpless asymmetric epoxidation|issue=13}}</ref><ref>{{cite journal|author=Martin, V.|author2=Woodard, S.|author3=Katsuki, T.|author4=Yamada, Y.|author5=Ikeda, M.|author6=Sharpless, K. B.|author6-link=K. Barry Sharpless |journal=[[J. Am. Chem. Soc.]]|year=1981|volume=103|pages= 6237β6240| doi=10.1021/ja00410a053|title=Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity?|issue=20|bibcode=1981JAChS.103.6237M }}</ref> [[File:Kinetic resolution.png|center|Kinetic resolution]]
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)