Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Tunable diode laser absorption spectroscopy
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
=== Concentration measurement === The basic principle behind the TDLAS technique is simple. The focus here is on a single absorption line in the absorption spectrum of a particular species of interest. To start, the wavelength of a [[laser diode|diode laser]] is tuned over a particular absorption line of interest and the intensity of the transmitted radiation is measured. The transmitted intensity can be related to the concentration of the species present by the [[Beer-Lambert law]], which states that when a radiation of [[wavenumber]] <math> (\tilde{\nu}) </math> passes through an absorbing medium, the intensity variation along the path of the beam is given by,<ref>See Bernath, Peter F. (2005), C7Β§6 p.272β274.</ref> :<math>I(\tilde{\nu}) = I_{0}(\tilde{\nu}) \exp(-\alpha(\tilde{\nu})L) = I_{0}(\tilde{\nu}) \exp(-\sigma(\tilde{\nu})NL)</math> where, <!-- The \! is to keep the formula rendered as PNG instead of HTML. Please don't remove it.--> :<math> I(\tilde{\nu}) </math> is the transmitted intensity of the radiation after it has traversed a distance <math> L </math> through the medium, :<math> I_{0}(\tilde{\nu}) </math> is the initial intensity of the radiation, :<math> \alpha(\tilde{\nu}) = \sigma(\tilde{\nu})N = S(T)\phi(\tilde{\nu}- \tilde{\nu}_{0}) </math> is the absorbance of the medium, :<math> \sigma(\tilde{\nu}) </math> is the absorption cross-section of the absorbing species, :<math> N \!</math> is the [[number density]] of the absorbing species, :<math> S(T) \!</math> is the line strength (i.e. the total absorption per molecule) of the absorbing species at temperature <math> T </math>, :<math> \phi(\tilde{\nu}- \tilde{\nu}_{0}) </math> is the lineshape function for the particular absorption line. Sometimes also represented by <math> g(\tilde{\nu}- \tilde{\nu}_{0}) </math>, :<math>\tilde{\nu}_{0}</math> is the center frequency of the spectrum.
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)