Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Lithium
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
=== Organic and polymer chemistry === [[Organolithium compound]]s are widely used in the production of polymer and fine-chemicals. In the polymer industry, which is the dominant consumer of these reagents, alkyl lithium compounds are [[catalyst]]s/[[radical initiator|initiators]]<ref>{{cite web |url=http://chemical.ihs.com/CEH/Public/Reports/681.7000/ |title=Organometallics |work=IHS Chemicals |date=February 2012 |access-date=2 January 2012 |archive-url=https://archive.today/20120707175638/http://chemical.ihs.com/CEH/Public/Reports/681.7000/ |archive-date=7 July 2012 |url-status=live}}</ref> in [[Anionic addition polymerization|anionic polymerization]] of [[functional group|unfunctionalized]] [[olefin]]s.<ref>{{Cite journal |title=Polymerization of 1,2-dimethylenecyclobutane by organolithium initiators |journal=Russian Chemical Bulletin |volume=37 |date=2005 |doi=10.1007/BF00962487 |pages=1782β1784 |author=Yurkovetskii, A. V. |first2=V. L. |first3=K. L. |last2=Kofman |last3=Makovetskii |issue=9 |s2cid=94017312}}</ref><ref>{{Cite journal |doi=10.1021/ma00159a001 |title=Functionalization of polymeric organolithium compounds. Amination of poly(styryl)lithium |date=1986 |author=Quirk, Roderic P. |journal=Macromolecules |volume=19 |pages=1291β1294 |first2=Pao Luo |last2=Cheng |bibcode=1986MaMol..19.1291Q |issue=5}}</ref><ref>{{Cite book |title=Advances in organometallic chemistry |author=Stone, F. G. A. |author2=West, Robert |publisher=Academic Press |date=1980 |isbn=978-0-12-031118-7 |page=55 |url={{google books |plainurl=y |id=_gai4kRfcMUC}} |access-date=6 November 2020 |archive-date=13 March 2021 |archive-url=https://web.archive.org/web/20210313170549/https://books.google.com/books?id=_gai4kRfcMUC |url-status=live}}</ref> For the production of fine chemicals, organolithium compounds function as strong bases and as reagents for the formation of [[carbon-carbon bond]]s. Organolithium compounds are prepared from lithium metal and [[alkyl halide]]s.<ref>{{Cite book |url={{google books |plainurl=y |id=_SJ2upYN6DwC |page=192}} |page=192 |title=Synthetic approaches in organic chemistry |author=Bansal, Raj K. |date=1996 |publisher=Jones & Bartlett Learning |isbn=978-0-7637-0665-4 |url-status=live |archive-url=https://web.archive.org/web/20160618033923/https://books.google.com/books?id=_SJ2upYN6DwC&pg=PA192 |archive-date=18 June 2016}}</ref> Many other lithium compounds are used as reagents to prepare organic compounds. Some popular compounds include [[lithium aluminium hydride]] (LiAlH<sub>4</sub>), [[lithium triethylborohydride]], [[N-Butyllithium|''n''-butyllithium]] and [[Tert-Butyllithium|''tert''-butyllithium]]. [[File:US Navy 040626-N-5319A-006 An Anti-Submarine Warfare (ASW) MK-50 Torpedo is launched from guided missile destroyer USS Bulkeley (DDG 84).jpg|thumb|The launch of a torpedo using lithium as fuel]]
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)