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====Probe electrospray ionization==== {{Main|Probe electrospray ionization}} Probe electrospray ionization (PESI) is a modified version of electrospray, where the capillary for sample solution transferring is replaced by a sharp-tipped solid needle with periodic motion.<ref>{{cite journal |author1=Hiraoka K. |author2=Nishidate K. |author3=Mori K. |author4=Asakawa D. |author5=Suzuki S. | title = Development of probe electrospray using a solid needle | journal = [[Rapid Communications in Mass Spectrometry]] | date = 2007| volume = 21 | pages = 3139β3144 | doi = 10.1002/rcm.3201 | pmid = 17708527 | issue = 18| bibcode = 2007RCMS...21.3139H }}</ref>
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