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Cobalt(II) chloride
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===Hydrates=== The crystal unit of the solid hexahydrate {{chem|CoCl|2}}β’6{{chem|H|2|O}} contains the neutral molecule ''trans''-{{chem|CoCl|2|(|H|2|O|)|4}} and two molecules of [[water of crystallization]].<ref>{{Wells5th}}</ref> This species dissolves readily in water and [[ethanol|alcohol]]. The anhydrous salt is [[hygroscopic]] and the hexahydrate is [[deliquescent]].{{citation needed|date=February 2019}} The dihydrate, CoCl<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>, is a [[coordination polymer]]. Each Co center is coordinated to four doubly [[bridging chloride ligand]]s. The octahedron is completed by a pair of mutually trans [[aquo ligand]]s.<ref>{{cite journal |title=Crystal structures of manganese(II) and iron(II) chloride dihydrate |author1=Morosin, B. |author2=Graeber, E. J. |journal=Journal of Chemical Physics |year=1965 |volume=42 |issue=3 |pages=898β901 |doi=10.1063/1.1696078 |bibcode=1965JChPh..42..898M}}</ref> {{multiple image | align = center | width = 200 | footer = Structures of the forms of cobalt(II) chloride | image1 = Cobalt(II)-chloride-3D-balls.png | alt1 = | caption1 = Anhydrous | image2 = MX2(H2O)2.png | alt2 = | caption2 = Dihydrate | image3 = MCl2(aq)6forFeCoNi.png | alt3 = | caption3 = Hexahydrate}}
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