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Electron counting
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==Electrons donated by common fragments== {| class="wikitable" |- ! Ligand !! Electrons contributed<br/>(neutral counting) !! Electrons contributed<br/>(ionic counting) !! Ionic equivalent |- | [[Halide|X]] || 1 || 2 ||X<sup>β</sup>; X = F, Cl, Br, I |- | [[Hydride|H]] || 1 || 2 ||H<sup>β</sup> |- | [[Hydrogen|H]] || 1 || 0 ||H<sup>+</sup> |- | [[Oxide|O]] || 2 || 4 ||O<sup>2β</sup> |- | [[Nitride|N]] || 3 || 6 ||N<sup>3β</sup> |- |[[Carbonyl ligand|CO]] |2 |2 |CO |- | [[Amine|NR<sub>3</sub>]] || 2 || 2 ||NR<sub>3</sub>; R = H, alkyl, aryl |- | [[Alkylidene|CR<sub>2</sub>]] || 2 || 4 ||{{chem2|CR2(2β)}} |- | [[Ethylene]] || 2 || 2 ||C<sub>2</sub>H<sub>4</sub> |- | [[Cyclopentadienyl complex|cyclopentadienyl]] || 5 || 6 ||{{chem2|C5H5-}} |- | [[benzene]] || 6 || 6 ||C<sub>6</sub>H<sub>6</sub> |} ==="Special cases"=== The numbers of electrons "donated" by some ligands depends on the geometry of the metal-ligand ensemble. An example of this complication is the Mβ[[Nitrosyl|NO]] entity. When this grouping is linear, the NO ligand is considered to be a three-electron ligand. When the MβNO subunit is strongly bent at N, the NO is treated as a pseudohalide and is thus a one electron (in the neutral counting approach). The situation is not very different from the ''Ξ·''<sup>3</sup> versus the ''Ξ·''<sup>1</sup> allyl. Another unusual ligand from the electron counting perspective is [[sulfur dioxide]]. <!-- -SCN vs. -NCS? -->
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