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===Groups containing oxygen=== Compounds that contain C–O bonds each possess differing reactivity based upon the location and [[orbital hybridisation|hybridization]] of the C–O bond, owing to the electron-withdrawing effect of sp-hybridized oxygen (carbonyl groups) and the donating effects of sp<sup>2</sup>-hybridized oxygen (alcohol groups). {| class="wikitable" style="background: #ffffff; text-align: center;width:300px" |- ! [[Chemical class]] ! Group ! Formula ! Structural formula ! Prefix ! Suffix ! Example |- | [[Alcohol (chemistry)|Alcohol]] || [[Hydroxy]] | ROH | [[File:Hydroxy-group-bw.svg|60px|center|Hydroxyl]] | hydroxy- || '''-ol''' | [[File:Methanol-2D.svg|90px|methanol]]<br>[[Methanol]] |- | [[Ketone]] || [[Ketone]] | RCOR′ | [[File:Ketone-group-2D-skeletal.svg|Ketone|75px]] | -oyl- (-COR′)<br>or<br>oxo- (=O) || '''-one''' | [[File:Butanone-skeletal-structure.svg|75px|Butanone]]<br>[[Butanone]]<br>''(Methyl ethyl ketone)'' |- | [[Aldehyde]] || [[Aldehyde]] | RCHO | [[File:Skeletal formula of an aldehyde group.svg|75px|Aldehyde]] | formyl- (-COH)<br>or<br>oxo- (=O)|| '''-al''' | [[File:Acetaldehyde-skeletal.svg|75px|acetaldehyde]]<br>[[Acetaldehyde]]<br>''(Ethanal)'' |- | [[Acyl halide]] || Haloformyl | RCOX | [[File:Acyl-halide-skeletal2D.svg|75px|Acyl halide]] | carbonofluoridoyl-<br>carbonochloridoyl-<br>carbonobromidoyl-<br>carbonoiodidoyl- || -oyl '''fluoride'''<br> -oyl '''chloride'''<br> -oyl '''bromide'''<br> -oyl '''iodide''' | [[File:Acetyl-chloride.svg|75px|Acetyl chloride]]<br>[[Acetyl chloride]]<br>''(Ethanoyl chloride)'' |- |[[Carbonate ester|Carbonate]] | [[Carbonate ester]] | ROCOOR′ | [[File:Carbonate-group-skeletal.svg|75px|Carbonate]] | (alkoxycarbonyl)oxy- | alkyl '''carbonate''' | [[File:Triphosgen Strukturformel.svg|90px|triphosgene]]<br>[[Triphosgene]]<br>''(bis(trichloromethyl) carbonate)'' |- | [[Carboxylic acid|Carboxylate]] | [[Carboxylate]] || RCOO<sup>−</sup> | [[File:Carboxylate-resonance-hybrid.svg|60px|center|Carboxylate]]<br>[[File:Carboxylate-canonical-forms.svg|119x119px|Carboxylate]] | carboxylato- || -oate | [[File:Sodium-acetate-2D-skeletal.png|75px|Sodium acetate]]<br>[[Sodium acetate]]<br>''(Sodium ethanoate)'' |- | [[Carboxylic acid]] | [[Carboxyl]] || RCOOH | [[File:Carboxylic-acid-skeletal.svg|75px|Carboxylic acid]] | carboxy- || -oic '''acid''' | [[File:Acetic-acid-2D-skeletal.svg|75px|Acetic acid]]<br>[[Acetic acid]]<br>''(Ethanoic acid)'' |- | [[Ester]] || [[Ester|Carboalkoxy]] | RCOOR′ | [[File:Ester-skeletal.svg|Ester|75px]] | alkanoyloxy-<br>or<br>alkoxycarbonyl | alkyl alkan'''oate''' | [[File:Ethyl butyrate.png|75px|Ethyl butyrate]]<br>[[Ethyl butyrate]]<br>''(Ethyl butanoate)'' |- | [[Organic peroxide|Hydroperoxide]] | [[Organic peroxide|Hydroperoxy]] | ROOH | [[File:Hydroperoxide-group-2D.svg|75px|Hydroperoxy]] | hydroperoxy- | alkyl '''hydroperoxide''' | [[File:TBHP.png|75px|''tert''-Butyl hydroperoxide]]<br>[[tert-Butyl hydroperoxide|''tert''-Butyl hydroperoxide]] |- | [[Organic peroxide|Peroxide]] | [[Organic peroxide|Peroxy]] | ROOR′ | [[File:Peroxy-group.svg|75px|Peroxy]] | peroxy- | alkyl '''peroxide''' | [[File:Di-tert-butyl peroxide.svg|75px|Di-tert-butyl peroxide]]<br>[[Di-tert-butyl peroxide]] |- | [[Ether]] || [[Ether]] | ROR′ | [[File:Ether-(general).svg|60px|center|Ether]] | alkoxy- | alkyl '''ether''' | [[File:Diethyl ether chemical structure.svg|75px|Diethyl ether]]<br>[[Diethyl ether]]<br>''(Ethoxyethane)'' |- | [[Hemiacetal]] || [[Hemiacetal]] | R<sub>2</sub>CH(OR<sub>1</sub>)(OH) | [[File:Hemiacetal general.svg|75px|Hemiacetal]] | alkoxy -ol | -al alkyl '''hemiacetal''' | |- | [[Hemiketal]] || [[Hemiketal]] | RC(ORʺ)(OH)R′ | [[File:Hemiketal-2D-skeletal.png|75px|Hemiketal]] | alkoxy -ol | -one alkyl '''hemiketal''' | |- | [[Acetal]] || [[Acetal]] | RCH(OR′)(OR″) | [[File:Acetal-2D-skeletal.png|75px|Acetal]] | dialkoxy- | -al dialkyl '''acetal''' | |- | [[Ketal]] (or [[Acetal]]) || [[Ketal]] (or [[Acetal]]) | {{nowrap|RC(OR″)(OR‴)R′}} | [[File:Ketal-2D-skeletal.png|75px|Ketal]] | dialkoxy- | -one dialkyl '''ketal''' | |- | [[Orthoester]] || [[Orthoester]] | {{nowrap|RC(OR′)(OR″)(OR‴)}} | [[File:Orthoester general structure.svg|75px|Orthoester]] | trialkoxy- | | |- | [[Heterocycle]]<br> (if cyclic) || [[Methylenedioxy]] | {{nowrap|(–OCH<sub>2</sub>O–)}} | [[File:Methylenedioxy graphic (ChemDraw).png|50px|frameless]] | methylenedioxy- | -dioxole | [[File:Benzo(d)(1,3)dioxole 200.svg|75px]]<br>[[1,3-Benzodioxole|1,2-Methylenedioxybenzene]]<br>''(1,3-Benzodioxole)'' |- | [[Orthocarbonate ester]] || [[Orthocarbonate ester]] | {{nowrap|C(OR)(OR′)(OR″)(OR‴)}} | [[File:Orthocarbonate-ester.svg|75px|Orthocarbonate ester]] | tetralkoxy- | ''tetraalkyl'' '''orthocarbonate''' | [[File:Tetramethylorthocarbonat.svg]]<br>[[Tetramethoxymethane]] |- | [[Organic acid anhydride]] || [[Carboxylic anhydride]] | {{nowrap|R<sub>1</sub>(CO)O(CO)R<sub>2</sub>}} | [[File:FunktionelleGruppen Carbonsäureanhydrid.svg|75px|Carboxylic anhydride]] | | anhydride | [[File:Butyric anhydride.svg|75px|Butyric anhydride]]<br>[[Butyric anhydride]] |}
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